Laddery lower alkylpolysilsesquioxane having heat-resistant thin
film-formability and process for preparing same
    2.
    发明授权
    Laddery lower alkylpolysilsesquioxane having heat-resistant thin film-formability and process for preparing same 失效
    具有耐热薄膜成形性的梯形低级烷基聚硅倍半氧烷及其制备方法

    公开(公告)号:US4399266A

    公开(公告)日:1983-08-16

    申请号:US353811

    申请日:1982-03-02

    CPC分类号: C08G77/04 C08G77/06 C08G77/32

    摘要: A laddery lower alkylpolysilsesquioxane represented by the formula: ##STR1## wherein R and R' represent same or different lower alkyl groups, and n represents an average degree of polymerization, said laddery lower alkylpolysilsesquioxane having a heat-resistant thin film-formability, characterized in that 15 to 30% by weight of the lower alkylpolysilsesquioxane is occupied by the portion having a standard polystyrene-reduced molecular weight of 20,000 or less as measured by gel permeation chromatography. Said silicone resin in which R and R' are methyl is prepared by dissolving CH.sub.3 SiCl.sub.3 in a ketone or an ether, adding water to this solution with stirring to hydrolyze CH.sub.3 SiCl.sub.3, condensing the hydrolyzate and, if necessary, subjecting the resulting condensate to a treatment for adjusting the proportion of the low molecular weight portion in the product.

    摘要翻译: 由下式表示的梯状低级烷基聚硅倍半氧烷:其中R和R'表示相同或不同的低级烷基,n表示平均聚合度,所述梯状低级烷基聚硅倍半氧烷具有耐热薄膜可成形性,其特征在于 通过凝胶渗透色谱法测定,低分子量聚硅氧烷的15〜30重量%被标准聚苯乙烯缩小分子量为20,000以下的部分占据。 其中R和R'为甲基的所述有机硅树脂通过将CH 3 SiCl 3溶解在酮或醚中制备,在搅拌下向该溶液中加入水以水解CH 3 SiCl 3,冷凝水解产物,如果需要,将所得缩合物进行处理 调节产品中低分子量部分的比例。