公开(公告)号：US4013817A

公开(公告)日：1977-03-22

申请号：US592702

申请日：1975-07-02

申请人： Kinji Masuda ,  Hideaki Saigo ,  Kazuo Naito ,  Tadashi Utsunomiya ,  Sakae Inoue

发明人： Kinji Masuda ,  Hideaki Saigo ,  Kazuo Naito ,  Tadashi Utsunomiya ,  Sakae Inoue

IPC分类号： B29C70/00 ,  B29C35/00 ,  B29C55/00 ,  B29C65/00 ,  B29C65/70 ,  B32B15/06 ,  C08J5/04 ,  C08J5/10 ,  C08K3/18 ,  C08K5/00 ,  C08K5/03 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  B05D7/14 ,  B05D3/00 ,  B32B15/08

CPC分类号： C08J5/10 ,  C08K3/22 ,  C08K3/26 ,  C08K3/30 ,  C08K5/03 ,  C08J2309/02 ,  Y10T428/31529 ,  Y10T428/31696

摘要： A butadiene-acrylonitrile copolymer rubber (NBR) composition can be strongly adhered to a metal material by compounding (A) a halogenated aromatic hydrocarbon having the general formulaR.sub.n.sub.' --(Ar)--CX.sub.m H.sub. 3-m).sub.nOr ##STR1## WHEREIN Ar is benzene nucleus residue or naphthalene nucleus residue, R is a hydrocarbon residue having 1-6 carbon atoms, hydrogen atom or halogen atom, X is halogen atom, m is 1-3, n" is 1-3, when Ar is benzene nucleus residue, n is 1-6 and n' is 0-5 (provided that n+n'.ltoreq.6) and when Ar is naphthalene nucleus residue, n is 1-8 and n' is 0-7 (provided that n+n'.ltoreq.8), and (B) at least one compound selected from the oxides, carbonates, sulfides and hydroxides of metals of groups I, II, IV, V and VIII in the Periodic Table and aluminum hydroxide, to the NBR composition, contacting the resulting rubber composition to the metal material, and vulcanizing the rubber composition to adhere the composition to the metal material.

公开(公告)号：US3984383A

公开(公告)日：1976-10-05

申请号：US356168

申请日：1973-05-01

申请人： Tsuneharu Akiyama ,  Sakae Inoue ,  Kinji Masuda ,  Suminobu Kurahashi

发明人： Tsuneharu Akiyama ,  Sakae Inoue ,  Kinji Masuda ,  Suminobu Kurahashi

IPC分类号： C08L23/00 ,  C08K5/43 ,  C08L7/00 ,  C08L21/00 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C08C11/60 ,  C08C11/54

CPC分类号： C08K5/43

摘要： A vulcanizable rubber composition suitable for the production of rubber materials having improved scorching stability and heat aging resistance can be obtained by compounding raw material rubber with a sulfenamide compound having the following general formula ##EQU1## wherein X represents a residue selected from the group consisting of residues of hydrocarbon, alkyl ether and secondary alcohol having 2-20 carbon atoms, and residues represented by the general formulae ##EQU2## (wherein R' represents a residue of hydrocarbon or alkyl ether having 0-20 carbon atoms, and R" represents a hydrocarbon residue having 1-10 carbon atoms), and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are same or different and are selected from hydrocarbon residues having 2-10 carbon atoms, and hydrogen atom, or R.sub.1 is ringed with R.sub.2 and/or R.sub.3 is ringed with R.sub.4, through the nitrogen atom of the general formula (1), to form heterocyclic rings of 5-7 members.

摘要翻译： 通过将原料橡胶与具有以下通式的次磺酰胺化合物R1R3 ANGLE NSXSN ANGLE（1）R2R4混合，可以获得适合于生产具有改善的焦烧稳定性和耐热老化性的橡胶材料的可硫化橡胶组合物，其中X表示选定的残基 由具有2-20个碳原子的烃，烷基醚和仲醇的残基组成的组以及由通式-R“-CO-R'-OC-R” - ，-R“ - OC-R'-CO-R“ - ，并行平行平行平行OO -OR” - CN-R'-NC-R“ - 和-R”'-NC-R'-CN-R“ - 并联| PARALLEL | PARALLEL PARALLEL | OHHO HOOH（其中R'表示具有0-20个碳原子的烃或烷基醚的残基，R“表示具有1-10个碳原子的烃基），R1，R2 ，R3和R4相同或不同，选自具有2-10个碳原子的烃基，氢原子或R1被R 2环化 和/或R 3通过通式（1）的氮原子与R4环，形成5-7个成员的杂环。

公开(公告)号：US3976624A

公开(公告)日：1976-08-24

申请号：US447048

申请日：1974-02-28

申请人： Sakae Inouye ,  Suminobu Kurahashi ,  Norio Wada ,  Motokazu Kikuchi ,  Kinji Masuda ,  Tsuneharu Akiyama ,  Toshiyuki Osaki

发明人： Sakae Inouye ,  Suminobu Kurahashi ,  Norio Wada ,  Motokazu Kikuchi ,  Kinji Masuda ,  Tsuneharu Akiyama ,  Toshiyuki Osaki

IPC分类号： B32B15/08 ,  C08J5/12 ,  C08K3/38 ,  C08C19/20 ,  C08F8/34

CPC分类号： C08J5/12 ,  B32B15/08 ,  C08K3/38 ,  Y10S524/925 ,  Y10T428/31696 ,  Y10T428/31707

摘要： This invention relates to an improvement of the adhesion of a metallic material such as copper, copper alloys and other metals coated therewith with a vulcanizable rubber composition. It is realized by previously adding orthoboric acid or a metal borate to the rubber composition in order to proceed with metal-rubber bonding reaction and vulcanization reaction in good balance, and vulcanizing an assembly of the metallic material and the boric compound containing rubber composition closely contacted therewith.

摘要翻译： 本发明涉及一种金属材料如铜，铜合金和其它涂覆有可硫化橡胶组合物的金属的粘附性的改进。 通过预先向橡胶组合物中加入原硼酸或金属硼酸盐，以平衡地进行金属 - 橡胶粘合反应和硫化反应，并将金属材料和含硼化合物的橡胶组合物的组合物紧密接触 随之而来。

公开(公告)号：US5558704A

公开(公告)日：1996-09-24

申请号：US502157

申请日：1995-07-13

申请人： Kinji Masuda ,  Minoru Kuriki ,  Kozo Hokari

发明人： Kinji Masuda ,  Minoru Kuriki ,  Kozo Hokari

IPC分类号： C08K3/00 ,  C08L95/00 ,  E01C7/18 ,  E01C7/26 ,  C08L9/00

CPC分类号： E01C7/265 ,  C08L95/00

摘要： A paving asphalt concrete composition consists essentially of an oil-impregnated vulcanized rubber crumb and an asphalt-aggregate mixture, in which the oil-impregnated vulcanized rubber crumb consist of 99-60% by weight of vulcanized rubber crumb and 1-40% by weight of an extending oil. This paving asphalt concrete composition is suitable for pavement of motorways, sidewalks, runways, taxiways, parking lots and the like.

摘要翻译： 铺路沥青混凝土组合物基本上由油浸硫化橡胶屑和沥青骨料混合物组成，其中油浸硫化橡胶屑由99-60重量％的硫化橡胶屑和1-40重量％ 的延伸油。 这种铺路沥青混凝土组合物适用于高速公路，人行道，跑道，滑行道，停车场等的铺路。