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23 条记录 (耗时 0.027 秒)

    1,3/1,4-CYCLOHEXANE DIMETHANOL BASED MONOMERS AND POLYMERS
    1.
    发明申请
    1,3/1,4-CYCLOHEXANE DIMETHANOL BASED MONOMERS AND POLYMERS 有权
    1,3 / 1,4-环己烷基二甲基甲硅烷基单体和聚合物

    公开(公告)号：US20090198014A1

    公开(公告)日：2009-08-06

    申请号：US12160001

    申请日：2006-12-07

    申请人： Kiran K. Baikerikar ,  Michael L. Tulchinsky ,  John N. Argyropoulos

    发明人： Kiran K. Baikerikar ,  Michael L. Tulchinsky ,  John N. Argyropoulos

    IPC分类号： C08F2/44 ,  C08F16/36 ,  C07C35/08 ,  C07C43/10 ,  C07C69/54 ,  C07C67/20

    CPC分类号： C08G63/47 ,  C07C29/80 ,  C07C2601/14 ,  C08G63/199 ,  C08G64/42 ,  C09D175/16 ,  C07C31/276

    摘要： A mixture of compounds useful to make a polymer or a prepolymer, the mixture of compounds including compounds having the formula I; wherein R1 is H, acryloyl, methacryloyl or vinyl, wherein R2 is acryloyl, methacryloyl or vinyl, wherein compounds having the formula I consist of a mixture of cis and trans-1,3- and 1,4-substituted cyclohexane and wherein the trans-1,4-substituted cyclohexane content of the compounds having the formula I is less than forty mole percent. A process for producing a mixture of compounds including compounds having the formula II: wherein compounds having the formula II consist of a mixture of cis and trans-1,3- and 1,4-methanol substituted cyclohexane and wherein the trans-1,4-methanol substituted cyclohexane content of the compounds having the formula II is less than twenty five mole percent.

    摘要翻译： 可用于制备聚合物或预聚物的化合物的混合物，化合物的混合物包括具有式I的化合物; 其中R 1是H，丙烯酰基，甲基丙烯酰基或乙烯基，其中R 2是丙烯酰基，甲基丙烯酰基或乙烯基，其中具有式I的化合物由顺式和反式-1,3-和1,4-取代的环己烷的混合物组成， 具有式I的化合物的-1,4-取代的环己烷含量小于40摩尔％。 一种制备包括具有式II化合物的化合物的混合物的方法：其中具有式II的化合物由顺式和反式-1,3-和1,4-甲醇取代的环己烷的混合物组成，其中反式-1,4 具有式II的化合物的甲醇取代的环己烷含量小于25摩尔％。

    1,3/1,4-cyclohexane dimethanol based monomers and polymers
    2.
    发明授权
    1,3/1,4-cyclohexane dimethanol based monomers and polymers 有权
    1,3 / 1,4-环己烷二甲醇基单体和聚合物

    公开(公告)号：US07943725B2

    公开(公告)日：2011-05-17

    申请号：US12160001

    申请日：2006-12-07

    申请人： Kiran K. Baikerikar ,  Michael L. Tulchinsky ,  John N. Argyropoulos

    发明人： Kiran K. Baikerikar ,  Michael L. Tulchinsky ,  John N. Argyropoulos

    IPC分类号： C08G63/00 ,  C07C31/13

    CPC分类号： C08G63/47 ,  C07C29/80 ,  C07C2601/14 ,  C08G63/199 ,  C08G64/42 ,  C09D175/16 ,  C07C31/276

    摘要： A mixture of compounds useful to make a polymer or a prepolymer, the mixture of compounds including compounds having the formula I; wherein R1 is H, acryloyl, methacryloyl or vinyl, wherein R2 is acryloyl, methacryloyl or vinyl, wherein compounds having the formula I consist of a mixture of cis and trans-1,3- and 1,4-substituted cyclohexane and wherein the trans-1,4-substituted cyclohexane content of the compounds having the formula I is less than forty mole percent. A process for producing a mixture of compounds including compounds having the formula II: wherein compounds having the formula II consist of a mixture of cis and trans-1,3- and 1,4-methanol substituted cyclohexane and wherein the trans-1,4-methanol substituted cyclohexane content of the compounds having the formula II is less than twenty five mole percent.

    摘要翻译： 可用于制备聚合物或预聚物的化合物的混合物，化合物的混合物包括具有式I的化合物; 其中R 1是H，丙烯酰基，甲基丙烯酰基或乙烯基，其中R 2是丙烯酰基，甲基丙烯酰基或乙烯基，其中具有式I的化合物由顺式和反式-1,3-和1,4-取代的环己烷的混合物组成， 具有式I的化合物的-1,4-取代的环己烷含量小于40摩尔％。 一种制备包括具有式II化合物的化合物的混合物的方法：其中具有式II的化合物由顺式和反式-1,3-和1,4-甲醇取代的环己烷的混合物组成，其中反式-1,4 具有式II的化合物的甲醇取代的环己烷含量小于25摩尔％。

    Sulfonated organophosphine compounds and use in hydroformylation processes
    6.
    发明授权
    Sulfonated organophosphine compounds and use in hydroformylation processes 有权
    磺化有机膦化合物并用于加氢甲酰化过程

    公开(公告)号：US08466306B2

    公开(公告)日：2013-06-18

    申请号：US12812978

    申请日：2009-01-09

    申请人： Michael L. Tulchinsky ,  Ronald R. Peterson

    发明人： Michael L. Tulchinsky ,  Ronald R. Peterson

    IPC分类号： C07F9/02

    CPC分类号： C07F9/5018

    摘要： A compound comprising a sulfonated dihydrocarbyl(arylalkyl)phosphine of formula R1R2PR3—(SO3M)n, wherein the R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups, and R3 is a divalent or polyvalent arylalkylene radical such that the alkyl moiety is bonded to the phosphorus atom and the aryl moiety is bonded to the alkyl and is also substituted with one or more sulfonate groups; M is a monovalent cation, and n ranges from 1 to 3. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alkyl-aryl exchange, thereby leading to reduced ligand usage and improved ligand and transition metal, e.g., rhodium, recovery and recycling.

    摘要翻译： 包含式R 1 R 2 PR 3 - （SO 3 M）n的磺化二烃基（芳烷基）膦的化合物，其中R 1和R 2分别选自烷基，芳烷基和脂环基，R 3是二价或多价芳基亚烷基，使得烷基部分 键合到磷原子上，芳基部分键合到烷基上并且也被一个或多个磺酸基团取代; M是一价阳离子，n在1至3的范围内。该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的加氢甲酰化形成一个或多个 更多相应的醛产品。 配体不能进行烷基 - 芳基交换，从而导致配体使用减少，改进配体和过渡金属，例如铑，回收和回收。

    Sulfonated organophosphine compounds and use thereof in hydroformylation processes
    7.
    发明授权
    Sulfonated organophosphine compounds and use thereof in hydroformylation processes 有权
    磺化有机膦化合物及其在加氢甲酰化方法中的应用

    公开(公告)号：US08461366B2

    公开(公告)日：2013-06-11

    申请号：US12812981

    申请日：2009-01-09

    申请人： Michael L. Tulchinsky ,  Robert E. Hefner, Jr.

    发明人： Michael L. Tulchinsky ,  Robert E. Hefner, Jr.

    IPC分类号： C07C303/00 ,  C07F17/02 ,  C07F15/00

    CPC分类号： B01J31/2404 ,  B01J31/2447 ,  B01J31/4046 ,  B01J31/4053 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/845 ,  B01J2531/96 ,  B01J2540/32 ,  B01J2540/64 ,  C07F9/5004 ,  C07F9/5018 ,  Y02P20/584

    摘要： A compound comprising a class of sulfonated triorganophosphine compounds of formula R1R2P—R3[—O—(CH2)n—(SO3M)]m, wherein the R1 and R2 are selected individually from alkyl, aralkyl, and alicyclic groups, wherein R3 represents a divalent or polyvalent alkylene or alicyclic radical that is bonded to the phosphorus atom and to one or more sulfonate substituents via an alkylether link, and further wherein R3 does not contain any aryl moieties; n is an integer reflecting a number of methylene groups in the alkylether link; M represents a monovalent cation; and m is an integer representing a total number of sulfonated alkylether substituents. The compound is useful as a ligand in transition metal-ligand complex catalysts that are capable of catalyzing the hydroformylation of an olefinically-unsaturated compound with carbon monoxide and hydrogen to form one or more corresponding aldehyde products. The ligand is incapable of alky-aryl exchange, thereby leading to reduced ligand usage and improving ligand and rhodium recovery and recycling.

    摘要翻译： 包含一类式R1R2P-R3 [-O-（CH2）n-（SO3M）] m的磺化三有机膦化合物的化合物，其中R1和R2分别选自烷基，芳烷基和脂环族基团，其中R3表示 通过烷基醚连接键合到磷原子和一个或多个磺酸酯取代基的二价或多价亚烷基或脂环族基团，其中R3不含任何芳基部分; n是反映烷基链接中亚甲基数的整数; M表示一价阳离子; m为代表磺化烷基醚取代基总数的整数。 该化合物可用作过渡金属 - 配体配合物催化剂中的配体，其能够催化烯属不饱和化合物与一氧化碳和氢气的羰基化形成一种或多种相应的醛产物。 配体不能进行烷基 - 芳基交换，从而导致配体使用减少并改善配体和铑的回收和再循环。

    POLYCYCLOPENTADIENE COMPOUNDS
    9.
    发明申请
    POLYCYCLOPENTADIENE COMPOUNDS 失效
    聚环氧乙烷化合物

    公开(公告)号：US20130046065A1

    公开(公告)日：2013-02-21

    申请号：US13643321

    申请日：2011-04-21

    申请人： Robert E. Hefner, JR. ,  Michael J. Mullins ,  Michael L. Tulchinsky ,  Ernesto Occhiello

    发明人： Robert E. Hefner, JR. ,  Michael J. Mullins ,  Michael L. Tulchinsky ,  Ernesto Occhiello

    IPC分类号： C07C47/445 ,  C08G8/32 ,  C08G8/04

    CPC分类号： C07C261/02 ,  C07C39/17 ,  C07C2603/68 ,  C07C2603/91

    摘要： Embodiments of the present disclosure include polycyclopentadiene compounds represented by Formula (I): in which each X is either a hydrogen or a cyano group (N≡C—), n has an average value from zero to 20; each m independently has a value of zero to 3; p has a value of zero to 20; each R is independently a halogen, a nitrile group, a nitro group, an alkyl group, an alkoxy group, an alkenyl group, or an alkenyloxy group, where the alkyl group, the alkoxy group, the alkenyl group, and the alkenyloxy group each independently contain 1 to 6 carbon atoms; and each Q is independently hydrogen or an alkyl group containing 1 to 6 carbon atoms. Embodiments of the present disclosure also include a curable composition that includes the polycyclopentadiene compound(s) of Formula (I) and a curing amount of a resin or a catalyst amount of a catalyst and/or a cure accelerating amount of an accelerating agent.

    摘要翻译： 本公开的实施方案包括由式（I）表示的聚环戊二烯化合物：其中每个X为氢或氰基（N≡C-），n的平均值为0至20; 每个m独立地具有零到3的值; p的值为零到20; 每个R独立地是卤素，腈基，硝基，烷基，烷氧基，烯基或烯氧基，其中烷基，烷氧基，烯基和烯氧基各自 独立地含有1至6个碳原子; 并且每个Q独立地是氢或含有1至6个碳原子的烷基。 本公开的实施方案还包括包含式（I）的聚环戊二烯化合物和树脂的固化量或催化剂的催化剂量和/或加速剂的固化促进量的可固化组合物。