MONOMER BEADS FOR PRODUCING A PROTON-CONDUCTING MEMBRANE
    7.
    发明申请
    MONOMER BEADS FOR PRODUCING A PROTON-CONDUCTING MEMBRANE 审中-公开
    用于制造导电膜的单体珠

    公开(公告)号:US20150197604A1

    公开(公告)日:2015-07-16

    申请号:US14667946

    申请日:2015-03-25

    IPC分类号: C08G73/18 H01M8/10

    摘要: Monomer beads which can be obtained according to a process in which i. one or more aromatic tetraamino compounds are mixed with one or more aromatic carboxylic acids comprising at least two acid groups per carboxylic acid monomer in an extruder and melted at 190° C.-270° C.; ii. the melt is dropletized at 190° C.-270° C. by means of a die located at the extruder outlet; iii. the liquid droplets are collected, cooled and allowed to solidify. The monomer beads are particularly suited to the production of a proton-conducting polymer membrane based on polyazoles.

    摘要翻译: 可以根据以下步骤获得的单体珠粒,其中i。 在挤出机中将一种或多种芳族四氨基化合物与一种或多种包含每个羧酸单体的至少两个酸基团的芳族羧酸混合,并在190℃-270℃下熔融。 ii。 熔体通过位于挤出机出口处的模具在190℃-270℃下液滴化; iii。 收集液滴,冷却并使其固化。 单体珠特别适合于制备基于多唑的质子传导性聚合物膜。

    METHOD FOR THE PRODUCTION OF A HIGH-MOLECULAR POLYAZOL
    8.
    发明申请
    METHOD FOR THE PRODUCTION OF A HIGH-MOLECULAR POLYAZOL 有权
    生产高分子聚氨酯的方法

    公开(公告)号:US20120101173A1

    公开(公告)日:2012-04-26

    申请号:US13377346

    申请日:2010-06-17

    IPC分类号: C08J5/22 C08K3/32

    摘要: A process for preparing a polyazole with an inherent viscosity, measured in at least 96% sulfuric acid at 25° C., greater than 2.9 dl/g, comprising the steps of i) mixing one or more aromatic tetraamino compounds with one or more aromatic carboxylic acids or esters thereof which comprise at least two acid groups per carboxylic acid monomer, or mixing one or more aromatic and/or heteroaromatic diaminocarboxylic acids, in polyphosphoric acid to form a solution and/or dispersion ii) heating the mixture from step i) under inert gas to temperatures in the range from 120° C. to 350° C. to form the polyazole, wherein in step ii), a mixture having a concentration of polyphosphoric acid, calculated as P2O5 (by acidimetric means), based on the total amount of H3PO4, polyphosphoric acid and water in the mixture, greater than 78.22%, is heated, the amounts of the components are selected in step i) such that the proportion by weight of the tetraamino compounds and of the aromatic carboxylic acids or esters thereof which comprise at least two acid groups per carboxylic acid monomer, or of the diaminocarboxylic acids of the mixture in step ii), based on the total weight of the mixture, is less than 11.0% by weight, the reaction mixture is heated in step ii) to greater than 220° C.

    摘要翻译: 制备具有特性粘度的聚唑的方法,其在25℃下的至少96%硫酸中测量,大于2.9dl / g,包括以下步骤:i)将一种或多种芳族四氨基化合物与一种或多种芳族化合物 每个羧酸单体包含至少两个酸基团,或在多磷酸中混合一种或多种芳族和/或杂芳族二氨基羧酸以形成溶液和/或分散体的羧酸或其酯ii)加热来自步骤i)的混合物, 在惰性气体下,在120℃至350℃的温度范围内,形成聚唑,其中在步骤ii)中,以P 2 O 5(通过酸度法)计算的具有多磷酸浓度的混合物 混合物中的H 3 PO 4,多磷酸和水的总量大于78.22%,在步骤i)中选择组分的量,使得四氨基化合物和芳族羧酸的重量比 或其在每个羧酸单体中包含至少两个酸基团的酯或其酯,或者基于混合物的总重量,步骤ii)中的混合物的二氨基羧酸的含量小于11.0重量%,反应混合物为 在步骤ii)中加热到大于220℃

    MONOMER BEADS FOR PRODUCING A PROTON-CONDUCTING MEMBRANE
    9.
    发明申请
    MONOMER BEADS FOR PRODUCING A PROTON-CONDUCTING MEMBRANE 有权
    用于制造导电膜的单体珠

    公开(公告)号:US20120007263A1

    公开(公告)日:2012-01-12

    申请号:US13144207

    申请日:2010-01-14

    IPC分类号: B29B9/00 C08G73/18 C08J5/22

    摘要: Monomer beads which can be obtained according to a process in which i. one or more aromatic tetraamino compounds are mixed with one or more aromatic carboxylic acids comprising at least two acid groups per carboxylic acid monomer in an extruder and melted at 190° C.-270° C.; ii. the melt is dropletized at 190° C.-270° C. by means of a die located at the extruder outlet; iii. the liquid droplets are collected, cooled and allowed to solidify. The monomer beads are particularly suited to the production of a proton-conducting polymer membrane based on polyazoles.

    摘要翻译: 可以根据以下步骤获得的单体珠粒,其中i。 在挤出机中将一种或多种芳族四氨基化合物与一种或多种包含每个羧酸单体的至少两个酸基团的芳族羧酸混合,并在190℃-270℃下熔融。 ii。 熔体通过位于挤出机出口处的模具在190℃-270℃下液滴化; iii。 收集液滴,冷却并使其固化。 单体珠特别适合于制备基于多唑的质子传导性聚合物膜。

    Thiazole compounds as additives in electrolyte solutions in electrochemical cells and batteries
    10.
    发明授权
    Thiazole compounds as additives in electrolyte solutions in electrochemical cells and batteries 有权
    噻唑化合物作为电解质溶液中电解质电池和电池中的添加剂

    公开(公告)号:US08940433B2

    公开(公告)日:2015-01-27

    申请号:US12966510

    申请日:2010-12-13

    摘要: The present invention relates to an electrolyte solution comprising at least one solvent as component A, at least one electrolyte as component B and from 0.1 to 20% by weight, based on the total electrolyte solution, of at least one heteroaromatic compound of the general formula (I) as component C, the use of such a compound in electrolyte solutions, the use of such an electrolyte solution in an electrochemical cell or for metal plating, and also electrochemical cells comprising a corresponding electrolyte solution.

    摘要翻译: 本发明涉及一种电解质溶液,其包含至少一种溶剂作为组分A,至少一种作为组分B的电解质和0.1至20重量%,基于总电解液,至少一种通式为的杂芳族化合物 (I)作为组分C,在电解质溶液中使用这种化合物,在电化学电池中使用这种电解质溶液或用于金属电镀,以及包含相应的电解质溶液的电化学电池。