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公开(公告)号：US3953409A
公开(公告)日：1976-04-27
申请号：US39569
申请日：1970-05-21
IPC分类号： C08F36/04 , C08F236/16 , C08F236/18
CPC分类号： C08F36/04
摘要： Conjugated diolefinic polymers having a molecular weight of less than 1,000,000 can be produced at high polymerization rates and in high yields by polymerizing a conjugated diolefin or copolymerizing a conjugated diolefin with a vinyl aromatic hydrocarbon in the presence of an alfin catalyst, in which as a molecular weight regulator is used a halogenated unsaturated hydrocarbon represented by the formula, ##EQU1## wherein R is an alkyl group having 1 to 7 carbon atoms, a vinyl group, a phenyl group, an alkyl-substituted phenyl group, a halogen atom or a hydrogen atom, and X, Y and Z which may be same or different are individually a hydrogen atom, a halogen atom or an alkyl group having 1 to 4 carbon atoms, at least one of the R, X, Y and Z being a halogen atom. The above-mentioned molecular weight regulator not only displays a prominent molecular weight-regulating effect, even when used in a small amount, but also is easily commercially obtainable and inexpensive, so that marked commercial advantages can be attained according to the above-mentioned process.
摘要翻译： 分子量小于1,000,000的共轭二烯烃聚合物可以在高聚合速率下以高收率产生，通过聚合共轭二烯烃或共轭二烯烃与乙烯基芳族烃在烯属催化剂存在下共聚，其中作为分子 使用由式RY ANGLE C = C ANGLE XZ表示的卤代不饱和烃，其中R是具有1至7个碳原子的烷基，乙烯基，苯基，烷基取代的苯基，卤素 原子或氢原子，X，Y和Z可以相同或不同，分别为氢原子，卤素原子或碳原子数1〜4的烷基，R，X，Y和Z中的至少一个 是卤素原子。 上述分子量调节剂即使在少量使用的情况下也显示出突出的分子量调节作用，而且容易商业上可获得并且价廉，因此可以根据上述方法获得显着的商业优点 。
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2.发明授权
公开(公告)号：US4083834A
公开(公告)日：1978-04-11
申请号：US605699
申请日：1975-08-18
摘要： A process for producing a polymer having functional groups at its chain terminals, which comprises reacting a polymer having alkali metal atoms at its chain terminals with an alkylene oxide or sulfide in a hydrocarbon medium having a solubility parameter of 7.2 or less at 25.degree. C. This process makes it possible to produce the said polymer in a short period of time without necessitating a large power for agitation. According to this process, there can be produced a polymer having a functionality near the theoretical functionality in a short period of time.
摘要翻译： 一种制备在其末端具有官能团的聚合物的方法，其包括使其末端具有碱金属原子的聚合物与环氧烷或硫化物在溶解度参数为7.2以下的烃介质中在25℃下反应。 该方法使得可以在短时间内生产所述聚合物，而不需要大的搅拌功率。 根据该方法，可以在短时间内产生具有接近理论官能度的官能团的聚合物。
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3.发明授权Photosensitive composition using maleic anhydride adduct of a 1,2 polybutadiene 失效使用1,2聚丁二烯的马来酐加合物的感光组合物
公开(公告)号：US4023973A
公开(公告)日：1977-05-17
申请号：US569145
申请日：1975-04-17
申请人： Fumitake Imaizumi , Isao Nagaoka , Mitsuo Kurokawa , Koei Komatsu , Yasuyuki Takimoto , Hidefumi Kusuda
发明人： Fumitake Imaizumi , Isao Nagaoka , Mitsuo Kurokawa , Koei Komatsu , Yasuyuki Takimoto , Hidefumi Kusuda
CPC分类号： G03F7/0388 , G03F7/038 , Y10S430/111 , Y10S430/118 , Y10S430/124 , Y10S430/128
摘要： A photosensitive composition comprising (1) a maleic anhydride adduct of 1,2-polybutadiene having a molecular weight of 10,000 or higher, (2) at least one photosensitizer and/or at least one photosensitive crosslinking agent, and, if necessary, (3) at least one acrylic monomer. This composition can be developed with water or a polar solvent such as an alcohol, and its layer formed on a support provides a printing plate. When the acrylic monomer is contained, the composition is suitable for use in flexographic printing.
摘要翻译： 一种光敏组合物，其包含（1）分子量为10,000以上的1,2-聚丁二烯的马来酸酐加合物，（2）至少一种光敏剂和/或至少一种光敏交联剂，以及如果需要，（3 ）至少一种丙烯酸类单体。 该组合物可以用水或极性溶剂如醇显影，并且其形成在载体上的层提供印刷版。 当含有丙烯酸单体时，该组合物适用于柔性版印刷。
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公开(公告)号：US4021259A
公开(公告)日：1977-05-03
申请号：US598598
申请日：1975-07-24
申请人： Koei Komatsu , Kunihiro Harada , Seiji Aotani , Akio Itabashi
发明人： Koei Komatsu , Kunihiro Harada , Seiji Aotani , Akio Itabashi
摘要： A gypsum composition obtained by molding and drying an aqueous slurry comprising calcined gypsum, polyvinyl alcohol, and at least one metal compound. The composition has high surface hardness and high water resistance.
摘要翻译： 通过将包含煅烧石膏，聚乙烯醇和至少一种金属化合物的含水浆料模制和干燥获得的石膏组合物。 该组合物具有高表面硬度和高耐水性。
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公开(公告)号：US4217299A
公开(公告)日：1980-08-12
申请号：US658749
申请日：1976-02-17
IPC分类号： C07C1/213 , C07F7/18 , C07C121/30 , C07C120/00 , C07C121/48 , C07C121/70
CPC分类号： C07C1/213 , C07C255/00 , C07C45/68 , C07C67/00 , C07C67/475 , C07F7/1804 , C07C2527/10 , C07C2527/132 , C07C2531/02 , C07C2531/14 , C07C2531/20
摘要： A method for the conversion of an unsaturated compound having a functional group, characterized by contacting [1] at least one compound selected from the group consisting of carboxylic acid esters, nitriles, ketones, amides, and ethers and having a carbon-to-carbon double bond and no unsaturation at the position conjugate to said double bond, or a mixture of said compound [1] and [2] at least one compound selected from the group consisting of ethylenically unsaturated compounds having a carbon-to-carbon double bond and neither unsaturation at the position conjugate to said double bond nor a functional group, with a catalyst system consisting essentially of a combination of (A) at least one member selected from the group consisting of tungsten compounds, molybdenum compounds, and rhenium compounds, with (B) at least one organoaluminum compound having at least one carbon-to-aluminum bond.
摘要翻译： 用于转化具有官能团的不饱和化合物的方法，其特征在于使[1]选自羧酸酯，腈，酮，酰胺和醚中的至少一种化合物与碳 - 碳 双键并且在与所述双键结合的位置上没有不饱和键，或所述化合物[1]和[2]的混合物中的至少一种选自具有碳 - 碳双键的烯键式不饱和化合物和 催化剂体系基本上由（A）至少一种选自钨化合物，钼化合物和铼化合物的组分与（A）组合组成的催化剂体系与（A） B）至少一种具有至少一个碳 - 铝键的有机铝化合物。
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公开(公告)号：US4182813A
公开(公告)日：1980-01-08
申请号：US905951
申请日：1978-05-15
申请人： Kenya Makino , Koei Komatsu , Yasumasa Takeuchi , Masayuki Endo
发明人： Kenya Makino , Koei Komatsu , Yasumasa Takeuchi , Masayuki Endo
CPC分类号： C08F136/06
摘要： A process for preparing crystalline 1,2-polybutadiene by contacting 1,3-butadiene with a catalyst consisting of (A) a cobalt compound, (B) an organoaluminum compound, (C) water in an amount of 0.25 to 1.5 mole per mol of said organoaluminum compound, and (D) an organic phosphorus compound in a halogenated hydrocarbon solvent to polymerize the butadiene, characterized in that as said organic phosphorus compound there is used a compound represented by the formula: ##STR1## wherein R.sup.1 is an alkyl or aryl group, and R.sup.2 and R.sup.3 represent independently hydrogen, or alkyl or aryl groups. This process can produce 1,2-polybutadiene having a degree of crystallization of 25 to 50% in a high yield at a temperature of from 0.degree. to 30.degree. C.
摘要翻译： 通过使1,3-丁二烯与（A）钴化合物，（B）有机铝化合物，（C）每摩尔0.25至1.5摩尔的量的水组成的催化剂接触来制备结晶1,2-聚丁二烯的方法 的所述有机铝化合物，和（D）在卤代烃溶剂中的有机磷化合物以使所述丁二烯聚合，其特征在于，作为所述有机磷化合物，使用由下式表示的化合物：其中R 1是烷基或 芳基，R2和R3独立地表示氢或烷基或芳基。 该方法可以在0〜30℃的温度下以高收率生产结晶度为25〜50％的1,2-聚丁二烯。
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7.发明授权Process for the production of 1,2-polybutadiene with regulated molecular weight 失效生产具有规定分子量的1,2-聚丁二烯的方法
公开(公告)号：US4176219A
公开(公告)日：1979-11-27
申请号：US910429
申请日：1978-05-30
申请人： Kenya Makino , Tsunezo Ishikawa , Koei Komatsu
发明人： Kenya Makino , Tsunezo Ishikawa , Koei Komatsu
CPC分类号： C08F136/06
摘要： In the production of 1,2-polybutadiene by contacting 1,3-butadiene with a catalyst composed of (A) a cobalt compound, (B) an organic phosphine compound, (C) trialkylaluminum and (D) water in an amount of 0.25 to 1.5 moles per mole of said trialkylaluminum, the addition of (E) at least one compound selected from the group consisting of allyl halides, alkyl-substituted allyl halides, benzyl halides, alkyl-substituted benzyl halides, and tertiary aliphatic halides to the reaction system enables the molecular weight of the objective 1,2-polybutadiene to be regulated to any desired value without causing any change in microstructure and degree of crystallization of the product and also without deteriorating so much the polymerization activity.
摘要翻译： 通过使1,3-丁二烯与由（A）钴化合物，（B）有机膦化合物，（C）三烷基铝和（D）水组成的催化剂的量生成1,2-聚丁二烯的量为0.25 至每摩尔所述三烷基铝为1.5摩尔，向所述反应中加入（E）至少一种选自烯丙基卤化物，烷基取代的烯丙基卤化物，苄基卤化物，烷基取代的苄基卤化物和叔脂族卤化物的化合物 系统使得将目的1,2-聚丁二烯的分子量调节到任何所需值，而不引起产物的显微结构和结晶度的任何变化，并且也不会使聚合活性变差。
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公开(公告)号：US4039491A
公开(公告)日：1977-08-02
申请号：US583177
申请日：1975-06-02
申请人： Hiroharu Ikeda , Shuichi Matsumoto , Hiroji Enyo , Noboru Oshima , Koei Komatsu
发明人： Hiroharu Ikeda , Shuichi Matsumoto , Hiroji Enyo , Noboru Oshima , Koei Komatsu
IPC分类号： C08G61/00 , C08C19/28 , C08G61/06 , C08G61/08 , C08F253/00 , C08F255/06 , C08F257/02 , C08F279/02
摘要： A novel copolymer is obtained by reacting [A] at least one norbornene derivative having at least one polar group or polar-group-containing substituent with [B] at least one unsaturated polymer having carbon-to-carbon double bonds in the presence of a metathesis catalyst. This copolymer is excellent in chemical and mechanical properties. Particularly, when 50% by weight or more of the component [A] is contained, the resin is distinguished for its high impact strength.
摘要翻译： 通过使[A]至少一种具有至少一个极性基团或含极性基团的取代基的降冰片烯衍生物与[B]至少一种具有碳 - 碳双键的不饱和聚合物在存在下进行反应来获得， 复分解催化剂。 该共聚物的化学和机械性能优异。 特别是当含有50重量％以上的成分[A]时，树脂的冲击强度高。
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公开(公告)号：US4097661A
公开(公告)日：1978-06-27
申请号：US788351
申请日：1977-04-18
申请人： Koei Komatsu , Kenji Itoyama , Jun Hirota , Akio Nishijima
发明人： Koei Komatsu , Kenji Itoyama , Jun Hirota , Akio Nishijima
CPC分类号： C08F36/04
摘要： A process for producing a conjugated diolefinic polymer by polymerizing at least one conjugated diolefin or copolymerizing at least one conjugated diolefin with at least one vinyl aromatic hydrocarbon in a hydrocarbon solvent in the presence of an alfin catalyst and at least one molecular weight regulator selected from the group consisting of (A) unsaturated halohydrocarbons represented by the general formula, RCX .dbd. CYZ, wherein R represents hydrogen, an alkyl group having 1 to 7 carbon atoms, a vinyl group, a phenyl group, a substituted phenyl group, or a halogen atom and X, Y and Z represent independently a hydrogen or halogen atom, at least one of said R, X, Y and Z being a halogen atom, (B) halogenated aromatic hydrocarbons, (C) ethers, polyethers, and acetals and (D) tertiary amines and, if necessary, a dihydro aromatic hydrocarbon, characterized in that said polymerization or copolymerization is effected in the presence of 0.03 to 0.9 mole of water and/or an alcohol per mole of organosodium contained in said alfin catalyst. According to this invention, there is obtained a polymer or copolymer excellent in green strength and processability of the unvulcanized compound and in physical properties of the vulcanizate.
摘要翻译： 一种制备共轭二烯烃聚合物的方法，其通过在烯烃催化剂和至少一种分子量调节剂的存在下，在烃溶剂中聚合至少一种共轭二烯烃或共聚至少一种共轭二烯烃与至少一种乙烯基芳烃， 由以下通式表示的（A）不饱和卤代烃：RCX = CYZ，其中R表示氢，具有1至7个碳原子的烷基，乙烯基，苯基，取代的苯基或卤素原子 并且X，Y和Z分别独立地表示氢原子或卤素原子，所述R，X，Y和Z中的至少一个为卤素原子，（B）卤代芳香烃，（C）醚，聚醚和缩醛和（D ）叔胺和如果需要的二氢芳族烃，其特征在于所述聚合或共聚在每摩尔o的0.03至0.9摩尔的水和/或醇的存在下进行 所述烯烃催化剂中含有的果糖钠。 根据本发明，获得了未硫化化合物的生坯强度和加工性能以及硫化橡胶的物理性能优异的聚合物或共聚物。
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10.发明授权Process for producing maleic anhydride adduct of high molecular weight 1,2-polybutadiene 失效生产高分子量1,2-聚丁二烯的马来酸酐的方法
公开(公告)号：US4082817A
公开(公告)日：1978-04-04
申请号：US671147
申请日：1976-03-29
申请人： Fumitake Imaizumi , Isao Nagaoka , Mitsuo Kurokawa , Koei Komatsu
发明人： Fumitake Imaizumi , Isao Nagaoka , Mitsuo Kurokawa , Koei Komatsu
CPC分类号： C08C19/28 , Y10S525/914
摘要： A process for producing a maleic anhydride adduct of high molecular weight 1,2-polybutadiene by contacting with heat maleic anhydride with high molecular weight 1,2-polybutadiene in the absence of a radical initiator in a halogenated aromatic hydrocarbon solvent. The adduct obtained by this process has a high molecular weight of more than 10,000 and is quite free from gel. Said process enables the addition of maleic anhydride in any desired proportion.
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