摘要:
A hydrogen generator (100) of the present invention includes: a raw material supplying device (4) configured to supply a raw material containing a sulfur constituent; a hydrogen supplying device (7) configured to generate hydrogen by electrolysis of water; a hydro-desulfurizer (5) configured to remove the sulfur constituent of the raw material by using the hydrogen generated by the hydrogen supplying device (7), the raw material being supplied from the raw material supplying device (4); and a reformer (1) configured to generate a hydrogen-containing gas by a reforming reaction of the raw material from which the sulfur constituent is removed by the hydro-desulfurizer (5).
摘要:
A method for operating a fuel cell system having a fuel cell equipped with an anode and a cathode includes the steps of generating electric power by allowing hydrogen gas supplied to the anode and oxygen gas supplied to the cathode to react electrochemically with each other, recovering water from water vapor discharged from at least one of the anode and cathode, storing recovered water in a water storing portion equipped with a tank having a closable drain opening, through which opening water stored in the tank is dischargeable to outside the fuel cell system, supplying water stored in the tank to a water utilizing means by a water supply portion, and making a decision whether or not to discharge the stored water to outside the fuel cell system through the drain opening in view of an increase in an amount of undesirable germs contained in water stored in the water storing portion.
摘要:
A fuel cell system of the present invention comprises a reformer (1) configured to generate a hydrogen-rich gas, a shift converter (2) configured to generate hydrogen and carbon dioxide from carbon monoxide in the hydrogen-rich gas and water, a hydrogen generator (20) including a carbon monoxide removing portion (3) configured to reduce the carbon monoxide in the hydrogen-rich gas which has not been removed in said shift converter (2), a fuel cell (4) configured to generate power using the hydrogen-rich gas supplied from the hydrogen generator (20) and an oxidizing gas, an air supply portion (6, 9) configured to supply air to at least one of a position upstream of said reformer (1) and a position between said carbon monoxide removing portion (3) and said fuel cell (4) in a flow of the fuel gas; and an impurity removing means (12, 13) configured to remove an impurity gas from the air.
摘要:
A hydrogen generating apparatus or the like is able to detect an excess water state or an excess steam state in the interior of a shift converter or a selective oxidation device. The hydrogen generating apparatus (120) comprise a hydrogen generator (118) including a reformer (100) configured to generate a reformed gas from a material and steam; a shift converter (103) configured to cause the reformed gas supplied from the reformer (100) to be subjected to a shift reaction; and a selective oxidation device (105) configured to decrease a concentration of carbon monoxide in the reformed gas after the shift reaction to a predetermined concentration or less; a temperature sensor (116, 117) configured to detect one of a temperature of the shift converter (103) and a temperature of the selective oxidation device (105); and a controller (205) configured to determine that excess water or excess steam exists in an interior of the hydrogen generator (118) when an increasing rate of the temperature detected by the temperature sensor is less than a predetermined threshold.
摘要:
A hydrogen generation system comprises a reformer 1 that contains a reforming catalyst, an evaporator 4 that supplies steam to the reformer 1, a heater 3 that heats the reformer 1 and the evaporator 4, a material feed portion 5 that feeds a feed material containing hydrocarbon compound to the reformer 1 through the evaporator 4, and a water supply portion 6 that has a flow rate switch 6a and supplies water to the reformer 1 and the evaporator 4.
摘要:
The present invention is a method for recovering a catalyst from a catalyst body comprising a carrier having a catalyst layer formed on at least a part of the surface thereof, which comprises (a) a step of forming an overcoat layer on the surface of the catalyst layer, and (b) a step of allowing the catalyst body having the overcoat layer formed thereon to stand under the condition to result in a difference in expansibility or contractility exhibited by the overcoat layer from that exhibited by the carrier, wherein exfoliation of the catalyst layer from the carrier is permitted by means of the resulting difference in expansibility or contractility under the condition.
摘要:
The present invention provides a fuel cell system comprising a hydrogen generator (1) which generates hydrogen gas by allowing a source material to undergo a reforming reaction and a fuel cell (3) which is equipped with a anode and an cathode and which generates electric power by allowing the hydrogen gas supplied to the anode and oxygen gas supplied to the cathode to react electrochemically with each other. The fuel cell system further comprises a water recovering portion (5) configured to recover water from water vapor discharged from at least one of the fuel and cathodes, a water storing portion (6) which is equipped with a tank (6a) for storing water recovered by the water recovering portion (5), and a water supply portion (10) configured to supply water stored in the tank (6a) to the hydrogen generator (1), wherein the tank (6a) is configured, in order to prevent water stored in the tank (6a) from decaying, such that the stored water is dischargable to the outside, and wherein the fuel cell system is so configured as to make a decision on whether or not to discharge the stored water to the outside for the prevention of water decay.
摘要:
A hydrogen generator of the present invention is provided with: a reformer for generating a reformed gas containing hydrogen from a feed material containing an organic compound at least containing carbon and hydrogen and water; a heater for heating the reformer to a temperature required for generating the reformed gas; a carbon monoxide reducing unit having a carbon monoxide reducing catalyst for reducing carbon monoxide contained in the reformed gas generated in the reformer; and a temperature detector for detecting at least one of a temperature of the reformed gas in the carbon monoxide reducing unit and a temperature of the carbon monoxide reducing catalyst, wherein an amount of the feed material to be supplied to the reformer is controlled based on a comparison between a detected temperature detected by the temperature detector and a reference temperature set in accordance with the amount of the feed material.
摘要:
A hydrogen generation apparatus has a reformer of generating a reformed gas containing at least hydrogen and carbon monoxide by making a material containing an organic compound react with water; carbon-monoxide-removing means of including at least a shifter of reducing the carbon monoxide contained in the reformed gas generated by the reformer in accordance with a shift reaction; and material-humidifying means of humidifying the material by directly or indirectly using moisture contained in the reformed gas.
摘要:
A hydrogen producing apparatus comprising: a reforming section having a reforming catalyst which causes a reaction between a carbon-containing organic compound as a feedstock and water; a feedstock supply section for supplying the feedstock to the reforming section; a water supply section for supplying water to the reforming section; a heating section for heating the reforming catalyst; a shifting section having a shift catalyst which causes a shift reaction between carbon monoxide and water contained in a reformed gas supplied from the reforming section; and a purifying section having a purifying catalyst which causes oxidation or methanation of carbon monoxide contained in a gas supplied from the shifting section, wherein the shift catalyst comprises a platinum group metal and a metal oxide.