Process for isomerization of a C7 fraction with opening of naphthene rings
    5.
    发明申请
    Process for isomerization of a C7 fraction with opening of naphthene rings 有权
    C7馏分与环烷烃环开环异构化的方法

    公开(公告)号:US20050043576A1

    公开(公告)日:2005-02-24

    申请号:US10887223

    申请日:2004-07-09

    摘要: A process for the production of an isomerate with a RON that is at least equal to 80 and that contains less than 1% by weight of aromatic compounds, starting with a fraction consisting mostly of hydrocarbons with 7 carbon atoms, and containing paraffins, naphthenes, and aromatic compounds in any proportion is described. Said process uses at least one isomerization unit, at least one unit for opening naphthene rings, and at least one separation unit; these units are combined in such a way as to recycle, to exhaustion, methyl cyclohexane, toluene, and normal paraffins and monobranched paraffins.

    摘要翻译: 一种生产异构体的方法,RON至少等于80,含有少于1重量%的芳族化合物,起始于主要由具有7个碳原子的烃组成的馏分,并含有链烷烃,环烷烃, 并描述任何比例的芳族化合物。 所述方法使用至少一种异构化单元,至少一个用于打开环烷环的单元和至少一个分离单元; 这些单元以循环,耗尽,甲基环己烷,甲苯和正链烷烃和单支链烷烃的方式组合。

    Aliphatic alkylation utilizing a liquid catalyst
    6.
    发明授权
    Aliphatic alkylation utilizing a liquid catalyst 失效
    使用液体催化剂的脂肪族烷基化

    公开(公告)号:US6096939A

    公开(公告)日:2000-08-01

    申请号:US115546

    申请日:1998-07-15

    摘要: The invention concerns the catalytic alkylation of at least one isoparaffin selected from the group formed by isobutane and isopentane in the presence of at least one olefin containing 3 to 6 carbon atoms per molecule, using a catalyst comprising 40% to 99% by weight of an acid selected from acids with formula R--SO.sub.3 H where R is fluorine or an alkyl group or a fluorinated alkyl group, R preferably being F or CF.sub.3, and more preferably CF.sub.3, and 1% to 60% by weight of a solvent selected from the group formed by sulpholane, dimethylsulphoxide and dioxanes, preferably sulpholane.

    摘要翻译: 本发明涉及至少一种选自异丁烷和异戊烷的异构烷烃在至少一种含有3至6个碳原子的烯烃存在下,每分子的催化烷基化,使用包含40-99%(重量) 选自具有式R-SO 3 H的酸的酸,其中R是氟或烷基或氟化烷基,R优选为F或CF 3,更优选为CF 3,和1至60重量%的选自以下的溶剂: 由环丁烷,二甲基亚砜和二恶烷形成,优选为环丁烷。

    Method of producing liquid hydrocarbons from natural gas, in the
presence of a catalyst based on zeolite and gallium
    10.
    发明授权
    Method of producing liquid hydrocarbons from natural gas, in the presence of a catalyst based on zeolite and gallium 失效
    在基于沸石和镓的催化剂存在下,从天然气生产液态烃的方法

    公开(公告)号:US5288935A

    公开(公告)日:1994-02-22

    申请号:US886226

    申请日:1992-05-21

    摘要: The invention concerns a method of producing liquid hydrocarbons from natural gas, characterized in that:a) the natural gas is separated in (2) into at least two fractions, a first fraction of gas enriched with methane and a second fraction enriched with C2+ alkanesb) the methane is selectively oxidised in (7a) by molecular oxygen in the presence of a catalyst for oxidizing linkage of methanec) the fraction enriched with C2+ alkanes is at least partly mixed with the effluent from selective oxidation, when at least 80% of the molecular oxygen introduced at stage (b) has already been consumed at stage (b)d) the mixture resulting from stage (c) is pyrolysed in (7b)e) when the temperature of the mixture from stage (d) has been brought to a temperature from 300.degree. to 750.degree. C. and more particularly from 420.degree. to 550.degree. C., at least part of the olefins is converted to aromatics in (11c), in the presence of a special catalyst containing a zeolite, gallium, one or more Group VIII metals and/or rhenium, one or more additional metals selected from tin, lead, indium, germanium and thallium, possibly an alkali metal or alkaline earth metal and possibly a matrix.

    摘要翻译: 本发明涉及从天然气生产液体烃的方法,其特征在于:a)将天然气在(2)中分离成至少两个馏分,富含甲烷的第一部分气体和富含C2 +烷烃的第二馏分 b)在用于氧化甲烷连接的催化剂的存在下,通过分子氧在(7a)中甲烷被选择性氧化c)富含C 2 +烷烃的级分至少部分地与来自选择性氧化的流出物混合,当至少80% 在步骤(b)中引入的分子氧已经在阶​​段(b)d被消耗)d)当从步骤(d)得到的混合物的温度已经 使温度从300摄氏度到750摄氏度,更特别是从420摄氏度到550摄氏度,在含有沸石的特殊催化剂的存在下,至少部分烯烃转化为(11c)中的芳族化合物, 镓,一种或一种 Ⅷ族金属和/或铼,选自锡,铅,铟,锗和铊中的一种或多种另外的金属,可能是碱金属或碱土金属以及可能的基质。