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    Formation of Ziegler-Natta Catalyst Using Non-blended Components
    1.
    发明申请
    Formation of Ziegler-Natta Catalyst Using Non-blended Components 审中-公开
    使用非混合组分形成齐格勒 - 纳塔催化剂

    公开(公告)号：US20110263802A1

    公开(公告)日：2011-10-27

    申请号：US12765454

    申请日：2010-04-22

    申请人： Lei Zhang ,  William Gauthier

    发明人： Lei Zhang ,  William Gauthier

    IPC分类号： C08F4/44 ,  C08F110/02 ,  C08F4/76

    CPC分类号： C08F10/00 ,  B01J37/00 ,  B01J37/04 ,  C08F110/02 ,  C08F4/6548 ,  C08F4/6557 ,  C08F2500/18 ,  C08F4/6546

    摘要： Methods of forming a catalyst, catalysts, polymerization processes and polymers formed therefrom are described herein. The method of forming a catalyst generally includes contacting an alkyl magnesium compound with an alcohol to form a magnesium alkoxide compound; contacting the magnesium alkoxide compound with a first titanium alkoxide and a first agent to form a reaction product “A”, wherein the titanium alkoxide and the first agent are nonblended individual components prior to contacting the magnesium alkoxide; and sequentially contacting the reaction product “A” with a second agent, followed by a third agent, and subsequently a first reducing agent to form a catalyst component.

    摘要翻译： 本文描述了形成催化剂，催化剂，聚合方法和由其形成的聚合物的方法。 形成催化剂的方法通常包括使烷基镁化合物与醇接触以形成烷氧基镁化合物; 使烷氧基镁化合物与第一钛醇盐和第一试剂接触以形成反应产物“A”，其中钛醇盐和第一试剂是在与烷氧基镁接触之前是非共混的单独组分; 并依次使反应产物“A”与第二试剂接触，随后与第三试剂接触，随后使第一还原剂接触以形成催化剂组分。

    Formation of Ziegler-Natta catalyst using non-blended components
    2.
    发明授权
    Formation of Ziegler-Natta catalyst using non-blended components 有权

    公开(公告)号：US10351640B2

    公开(公告)日：2019-07-16

    申请号：US12765454

    申请日：2010-04-22

    申请人： Lei Zhang ,  William Gauthier

    发明人： Lei Zhang ,  William Gauthier

    IPC分类号： C08F4/64 ,  B01J37/00 ,  C08F10/00 ,  B01J37/04 ,  C08F110/02

    摘要： Methods of forming a catalyst, catalysts, polymerization processes and polymers formed therefrom are described herein. The method of forming a catalyst generally includes contacting an alkyl magnesium compound with an alcohol to form a magnesium alkoxide compound; contacting the magnesium alkoxide compound with a first titanium alkoxide and a first agent to form a reaction product “A”, wherein the titanium alkoxide and the first agent are nonblended individual components prior to contacting the magnesium alkoxide; and sequentially contacting the reaction product “A” with a second agent, followed by a third agent, and subsequently a first reducing agent to form a catalyst component.

    MULTI-COMPONENT CATALYST SYSTEMS AND POLYMERIZATION PROCESSES FOR FORMING IN-SITU HETEROPHASIC COPOLYMERS AND/OR VARYING THE XYLENE SOLUBLES CONTENT OF POLYOLEFINS
    4.
    发明申请
    MULTI-COMPONENT CATALYST SYSTEMS AND POLYMERIZATION PROCESSES FOR FORMING IN-SITU HETEROPHASIC COPOLYMERS AND/OR VARYING THE XYLENE SOLUBLES CONTENT OF POLYOLEFINS 有权
    多组分催化剂体系和形成异源共聚物的聚合方法和/或改变聚烯烃的二甲苯溶液含量

    公开(公告)号：US20130102743A9

    公开(公告)日：2013-04-25

    申请号：US13180672

    申请日：2011-07-12

    申请人： Tim J. Coffy ,  Michel Daumerie ,  Kenneth P. Blackmon ,  William Gauthier ,  Jun Tian ,  Joseph Thorman

    发明人： Tim J. Coffy ,  Michel Daumerie ,  Kenneth P. Blackmon ,  William Gauthier ,  Jun Tian ,  Joseph Thorman

    IPC分类号： C08F4/76 ,  C08F4/42

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/06 ,  Y10S526/943 ,  C08F4/65904 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/05

    摘要： Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.

    摘要翻译： 本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和异相共聚物。 多组分催化剂体系通常包括选自齐格勒 - 纳塔催化剂体系的第一催化剂组分，其包括二醚内电子给体和由通式XCpACpBMAn表示的茂金属催化剂，其中X是结构桥，CpA和CpB各自表示环戊二烯基 基团或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是过渡金属，A是烷基，烃基或卤素基团，n是0和4之间的整数。多组分催化剂 系统还包括通常由式XCpACpBMAn表示的第二催化剂组分，其中X是结构桥，CpA和CpB各自表示环戊二烯基或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是 过渡金属，A是烷基，烃基或卤素基团，n是0至4之间的整数， nd催化剂组分表现出比第一催化剂组分更高的乙烯响应。

    Supported metallocene catalysts
    6.
    发明申请
    Supported metallocene catalysts 审中-公开
    负载金属茂催化剂

    公开(公告)号：US20080287619A1

    公开(公告)日：2008-11-20

    申请号：US11804483

    申请日：2007-05-18

    申请人： William Gauthier ,  David Rauscher ,  Jun Tian ,  Nathan Williams

    发明人： William Gauthier ,  David Rauscher ,  Jun Tian ,  Nathan Williams

    IPC分类号： B01J31/14 ,  C08F4/46

    CPC分类号： C08F210/16 ,  B01J31/143 ,  B01J31/2295 ,  B01J2231/122 ,  B01J2531/48 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/06 ,  C08F4/65916 ,  C08F2500/15 ,  C08F2500/12

    摘要： Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m 2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn   (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′   (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′ are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.

    摘要翻译： 在制备全同立构乙烯丙烯共聚物中使用负载型茂金属催化剂组合物的方法。 组合物包含负载在平均粒度为10-40微米，孔体积为1.3-1.6毫升/克，表面积为200-400平方米/克的粒状二氧化硅载体上的金属茂组分。 在载体上加入烷基铝氧烷助催化剂组分。 特殊的茂金属的特征在于以下公式：<？in-line-formula description =“In-line formula”end =“lead”？> B（CpRaRb）（FlR'2 > n （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>或通过公式：<？in-line-formula description =“在线公式 “end =”lead“？> B'（Cp'R'aR'b）（Fl'）M'Q'N'（2）<？in-line-formula description =”In 在式中，Cp和Cp'是取代的环戊二烯基，Fl和Fl'是芴基，B和B'是结构桥。 R'是2和7位的取代基，Ra和R'a是桥的远端的取代基，Rb和R'b靠近桥。 M和M'是过渡金属，Q'是卤素或C 1 -C 4 -C 4烷基; 并且n'是0-4的整数。

    Transition metal catalyst and formation thereof
    7.
    发明申请
    Transition metal catalyst and formation thereof 有权
    过渡金属催化剂及其形成

    公开(公告)号：US20070232484A1

    公开(公告)日：2007-10-04

    申请号：US11492351

    申请日：2006-07-25

    申请人： Jun Tian ,  William Gauthier ,  Joseph L. Thorman ,  Shady N. Henry

    发明人： Jun Tian ,  William Gauthier ,  Joseph L. Thorman ,  Shady N. Henry

    IPC分类号： B01J23/70 ,  B01J31/00

    CPC分类号： C08F10/00 ,  C08F4/65927 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2500/18 ,  C08F2500/03

    摘要： Catalyst systems and methods of forming the catalyst systems are described herein. The methods generally include contacting a support material with an activator to form a support composition, contacting a component with at least a portion of an aluminum containing compound including TIBAl, wherein the component is selected from the support composition, the transition metal catalyst compound and combinations thereof and contacting the support composition with a transition metal catalyst compound to form a supported catalyst system.

    摘要翻译： 本文描述了形成催化剂体系的催化剂体系和方法。 所述方法通常包括使支撑材料与活化剂接触以形成载体组合物，使组分与包含TIBAl的含铝化合物的至少一部分接触，其中所述组分选自载体组合物，过渡金属催化剂化合物和组合 并使载体组合物与过渡金属催化剂化合物接触以形成负载型催化剂体系。

    Polyorganosilsesquioxane supported metallocene catalysts
    8.
    发明申请
    Polyorganosilsesquioxane supported metallocene catalysts 失效
    聚有机倍半硅氧烷负载金属茂催化剂

    公开(公告)号：US20060154809A1

    公开(公告)日：2006-07-13

    申请号：US10765688

    申请日：2004-01-27

    申请人： David Rauscher ,  William Gauthier

    发明人： David Rauscher ,  William Gauthier

    IPC分类号： B01J31/00 ,  C08F4/44

    CPC分类号： C08F10/00 ,  B01J2531/0263 ,  B01J2531/40 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  Y02P20/52 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65916 ,  C08F2500/18

    摘要： Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to produce syndiotactic polypropylene or isotactic polypropylene. The supported catalyst comprises a stereospecific metallocene catalyst component and a co-catalyst component comprising an alkylalumoxane. Both the metallocene catalyst component and the co-catalyst component are supported on a particulate polyorganosilsesquioxane support comprising spheroidal particles of a polyorganosilsesquioxane having an average. diameter with the range of 0.3-20 microns. The polyorganosilsesquioxane support is characterized by relatively low surface area, specifically a surface area less than 100 square meters per gram. The metallocene component can take the form of a single metallocene or two or more metallocenes which are co-supported on the polyorganosilsesquioxane support.

    摘要翻译： 支持的立体定向催化剂和用于衍生自烯属不饱和单体的聚合物链的立体定向扩散的方法，例如丙烯聚合以产生间同立构聚丙烯或全同立构聚丙烯。 载体催化剂包括立体特异性茂金属催化剂组分和包含烷基铝氧烷的助催化剂组分。 金属茂催化剂组分和助催化剂组分均负载在包含具有平均值的聚有机倍半硅氧烷的球状颗粒的颗粒聚有机倍半硅氧烷载体上。 直径范围为0.3-20微米。 聚有机倍半硅氧烷载体的特征在于相对较低的表面积，特别是小于100平方米/克的表面积。 茂金属组分可以采用共聚在有机倍半硅氧烷载体上的单一茂金属或两种或多种茂金属的形式。

    Polyolefin production with a high performance support for a metallocene catalyst system
    10.
    发明授权
    Polyolefin production with a high performance support for a metallocene catalyst system 有权
    聚烯烃生产具有高性能支持的茂金属催化剂体系

    公开(公告)号：US08436112B2

    公开(公告)日：2013-05-07

    申请号：US12013774

    申请日：2008-01-14

    申请人： Jun Tian ,  William Gauthier ,  David Rauscher ,  Shady Henry

    发明人： Jun Tian ,  William Gauthier ,  David Rauscher ,  Shady Henry

    IPC分类号： C08F4/52 ,  C08F4/64 ,  C08F4/76

    CPC分类号： C08F4/76 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  Y10T428/2982 ,  C08F4/65916 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F2500/15

    摘要： The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.

    摘要翻译： 本发明涉及一种茂金属催化剂体系，其包含惰性二氧化硅载体，其具有在孔直径约250埃至约350埃之间具有大于约0.115mL / g的峰孔体积的孔，以及铝氧烷活化剂与茂金属 在整个支撑体上大体上被束缚。 将活化剂在甲苯的回流温度下在溶剂中接枝到载体上，得到二氧化硅上的铝氧烷，并加入金属茂组分以制备茂金属负载量为约2重量％的MCS。 这促进了催化活性增加的茂金属催化剂体系的生产，其催化活性比之前所公认的高约1％（重量），其中活化剂在室温下接枝到载体上的金属茂负载量的催化活性高至少约20％。