Macrocyclic complex modified electrodes and capacitors made therefrom
    2.
    发明授权
    Macrocyclic complex modified electrodes and capacitors made therefrom 失效
    大环复合改性电极和由其制成的电容器

    公开(公告)号:US5729427A

    公开(公告)日:1998-03-17

    申请号:US780557

    申请日:1997-01-08

    IPC分类号: H01G9/04 H01G9/042 H01G9/00

    CPC分类号: H01G9/042

    摘要: Electrodes for electrochemical capacitor are modified with a metal macrocyclic complex made up of phthalocyanine or porphyrin ligands bound to a transition metal to achieve improved conductivity, reversibility, and charge storage capacity. The electrode is formed from a metal base and coated with an oxide, nitride or carbide of a transition metal or with a conductive polymer. This coating is modified with the metal macrocyclic complex. Suitable metal macrocyclic complexes are iron phthalocyanine (FePc), iron meso-tetra(N-methyl-4-phenyl)porphyrin (FeTPP) or cobalt protoporphyrin (CoPP).

    摘要翻译: 用电化学电容器的电极用与过渡金属结合的酞菁或卟啉配体组成的金属大环络合物进行改性以实现改进的导电性,可逆性和电荷存储容量。 电极由金属基底形成并涂覆有过渡金属或导电聚合物的氧化物,氮化物或碳化物。 该涂层用金属大环络合物改性。 合适的金属大环配合物是铁酞菁(FePc),内消旋 - 四(N-甲基-4-苯基)卟啉(FeTPP)或钴原卟啉(CoPP)。

    Rechargeable electrochemical cell with modified electrolyte
    5.
    发明授权
    Rechargeable electrochemical cell with modified electrolyte 失效
    具有改性电解质的可充电电化学电池

    公开(公告)号:US5830601A

    公开(公告)日:1998-11-03

    申请号:US613697

    申请日:1996-03-11

    IPC分类号: H01M4/24 H01M10/26 H01M10/40

    CPC分类号: H01M4/244 H01M10/26

    摘要: An electrochemical battery cell (10) including a zinc electrode (20), and may be fabricated with an electrolyte (50) system including an electrolyte active species and a modifier. The electrolyte active species is typically a metal hydroxide such as KOH or NaOH, while the modifier may be a porphine such as a metal porphine, and/or a polymeric material. The polymeric material may be, for example, a polyvinyl resin such as polyvinyl alcohol or polyvinyl acetate. The resulting electrolyte typically includes between 3 and 10 weight percent of the polyvinyl resin, 5 and 50 weight percent of the metal hydroxide, and between 1 PPM and 1 wt % of the modifier. Employing such an electrolyte in a cell including a zinc electrode results in an energy storage device having improved power density and substantially longer cycle life.

    摘要翻译: 一种包括锌电极(20)的电化学电池(10),并且可以用包括电解质活性物质和改性剂的电解质(50)系统制造。 电解质活性物质通常是金属氢氧化物如KOH或NaOH,而改性剂可以是卟吩如金属卟吩和/或聚合物材料。 聚合物材料可以是例如聚乙烯醇树脂如聚乙烯醇或聚乙酸乙烯酯。 所得电解质通常包含3至10重量%的聚乙烯基树脂,5重量%和50重量%的金属氢氧化物,以及1PPM与1重量%的改性剂之间。 在包括锌电极的电池中使用这种电解质导致能量存储装置具有改善的功率密度和显着更长的循环寿命。

    Electrically conductive polymeric coating for an electrochemical charge
storage device
    6.
    发明授权
    Electrically conductive polymeric coating for an electrochemical charge storage device 失效
    用于电化学电荷存储装置的导电聚合物涂层

    公开(公告)号:US5824436A

    公开(公告)日:1998-10-20

    申请号:US808269

    申请日:1997-02-28

    IPC分类号: H01B1/20 H01M4/66 H01G9/00

    摘要: An electrochemical cell is provided with first (10) and second (11) electrodes and a solid polymer electrolyte (15) disposed therebetween. The electrodes include a current collecting layer, a layer of electrode active material, and a layer of an electrically conductive, polymeric protection material disposed therebetween. The protective layer protects, for example, the current collecting layer from the deleterious effects of the acid or alkaline electrolyte active species found in most electrochemical cells. The protective layer is formed of an intermetallic compound dispersed through a layer of appropriately chosen polymeric material.

    摘要翻译: 电化学电池设置有第一电极(10)和第二电极(11),以及设置在其间的固体聚合物电解质(15)。 电极包括集流层,电极活性材料层和设置在它们之间的导电的聚合物保护材料层。 保护层例如保护电流收集层免受大多数电化学电池中发现的酸或碱性电解质活性物质的有害影响。 保护层由分散在适当选择的聚合材料层中的金属间化合物形成。

    Polymer electrolyte and an electrochemical cell containing the
electrolyte
    7.
    发明授权
    Polymer electrolyte and an electrochemical cell containing the electrolyte 失效
    聚合物电解质和含有电解质的电化学电池

    公开(公告)号:US5723231A

    公开(公告)日:1998-03-03

    申请号:US762477

    申请日:1996-12-09

    IPC分类号: H01M6/18 H01M6/04

    CPC分类号: H01M6/181

    摘要: An electrolyte for an electrochemical cell is provided. The electrolyte is an admixture of H.sub.3 PO.sub.4 and a high temperature polymer such as poly(benzimidazole) in ratios between 2:1 and 50:1, Fumed silica is added to the electrolyte at levels between 0.2% and 8% by weight. An electrochemical cell is fabricated using the electrolyte, and exhibits improved adhesion between the electrolyte and the electrode.

    摘要翻译: 提供了一种用于电化学电池的电解质。 电解质是H 3 PO 4和高温聚合物如聚(苯并咪唑)之比为2:1至50:1的混合物,热解法二氧化硅以0.2重量%至8重量%的含量加入到电解质中。 使用电解质制造电化学电池,并且在电解质和电极之间表现出改进的粘附性。

    Electrochemical cell having a polymer electrolyte
    8.
    发明授权
    Electrochemical cell having a polymer electrolyte 失效
    具有聚合物电解质的电化学电池

    公开(公告)号:US5688613A

    公开(公告)日:1997-11-18

    申请号:US629174

    申请日:1996-04-08

    摘要: An electrochemical cell is provided with a first and second electrodes, and a solid polymer electrolyte disposed therebetween. The electrodes may either be of the same or different materials and may be fabricated from ruthenium, iridium, cobalt, tungsten, vanadium, iron, molybdenum, nickel, silver, zinc, and combinations thereof. The solid polymer electrolyte is in intimate contact with both the anode and the cathode, and is made from a polymeric support structure having dispersed therein an electrolyte active species. The polymer support structure is preferably a polybenzimidazole.

    摘要翻译: 电化学电池设置有第一和第二电极以及设置在它们之间的固体聚合物电解质。 电极可以是相同或不同的材料,并且可以由钌,铱,钴,钨,钒,铁,钼,镍,银,锌及其组合制成。 固体聚合物电解质与阳极和阴极紧密接触,并且由其中分散有电解质活性物质的聚合物支撑结构制成。 聚合物载体结构优选为聚苯并咪唑。