公开(公告)号：US20210032397A1

公开(公告)日：2021-02-04

申请号：US17045912

申请日：2019-04-09

Applicant: MITSUI CHEMICALS, INC.

Inventor： Masakazu TANAKA ,  Toyoaki SASAKI ,  Tomoaki MATSUGI ,  Sadahiko MATSUURA ,  Naoto MATSUKAWA ,  Masatoshi CHINAKA

IPC: C08F297/08

Abstract: A 4-methyl-1-pentene polymer particle (X) which satisfies the following requirements (X-a), (X-b) and (X-c): (X-a) being composed of a 4-methyl-1-pentene polymer which has a content of a constitutional unit derived from 4-methyl-1-pentene being 30.0 to 99.7% by mol, and a content of a constitutional unit derived from at least one olefin selected from ethylene and an α-olefin having 3 to 20 carbon atoms (except for 4-methyl-1-pentene) being 0.3 to 70.0% by mol; (X-b) having, when measured in a cross fractionation chromatograph apparatus (CFC) using an infrared spectrophotometer as a detector part, at least one peak A of an amount of a component eluted present in the range of 100 to 140° C., and at least one peak B of an amount of a component eluted present at lower than 100° C.; and (X-c) having a meso diad fraction (m) measured by 13C-NMR falling within the range of 95.0 to 100%.

公开(公告)号：US20160280828A1

公开(公告)日：2016-09-29

申请号：US15034136

申请日：2014-11-05

Applicant: MITSUI CHEMICALS, INC.

Inventor： Kuniaki KAWABE ,  Hirotaka KANAYA ,  Masakazu TANAKA ,  Toshiyuki ITO ,  Masako YOSHIDA

IPC: C08F255/10 ,  C09J151/06 ,  C08L69/00 ,  C08L31/04 ,  C08L51/06 ,  C09D151/06

CPC classification number: C08F255/10 ,  C08F4/65912 ,  C08F4/65927 ,  C08F8/00 ,  C08F210/06 ,  C08F255/08 ,  C08L31/04 ,  C08L33/04 ,  C08L51/06 ,  C08L69/00 ,  C09D151/06 ,  C09J151/06 ,  C08F222/06 ,  C08F210/08 ,  C08F2500/02 ,  C08F2500/20 ,  C08F212/08 ,  C08F2220/1858 ,  C08F220/06 ,  C08F210/16

Abstract: The purpose of the present invention is to provide a polar-group-containing propylene-type wax having excellent properties including a low melting point. A modified propylene-(α-olefin) copolymer (A) according to the present invention is produced by grafting at least one compound selected from an unsaturated carboxylic acid, a derivative of the unsaturated carboxylic acid and an unsaturated sulfonic acid salt onto a propylene-(α-olefin) copolymer (A1) and has an acid value of 1 to 100 KOHmg/g, wherein the propylene-(α-olefin) copolymer (A1) comprises 60 to 95 mol % of a propylene-derived constituent unit (a) and 5 to 40 mol % of a constituent unit (b) derived from an α-olefin having 4 or more carbon atoms, and satisfies the specific requirements (i) to (iii).

Abstract translation: 本发明的目的是提供具有优异特性的含极性基团的丙烯类蜡，其包括低熔点。 根据本发明的改性丙烯 - （α-烯烃）共聚物（A）通过将选自不饱和羧酸，不饱和羧酸和不饱和磺酸盐的衍生物中的至少一种化合物接枝到丙烯 - （α-烯烃）共聚物（A1），酸值为1〜100KOHmg / g，丙烯 - （α-烯烃）共聚物（A1）含有60〜95摩尔％的丙烯衍生的构成单元（a ）和5〜40摩尔％的由具有4个或更多个碳原子的α-烯烃衍生的构成单元（b），并且满足特定要求（i）至（iii）。

公开(公告)号：US20160160044A1

公开(公告)日：2016-06-09

申请号：US14392197

申请日：2014-06-23

Applicant: MITSUI CHEMICALS, INC.

Inventor： Hirotaka KANAYA ,  Kuniaki KAWABE ,  Masakazu TANAKA

IPC: C08L69/00 ,  C08J3/22

CPC classification number: C08L69/00 ,  B29B9/06 ,  B29B9/12 ,  C08J3/226 ,  C08J5/043 ,  C08J2369/00 ,  C08J2409/06 ,  C08J2433/10 ,  C08J2433/20 ,  C08J2451/06 ,  C08J2455/02 ,  C08J2491/06 ,  C08K7/14 ,  C08L51/06 ,  C08L55/02 ,  C08L67/00 ,  C08L91/06

Abstract: Problem to be solved by the present invention is to provide a molding resin composition containing an inorganic reinforcing material which enables a molded body having excellent impact resistance, high surface glossiness, and good mold releasability. This problem is solved by a molding resin composition comprising: 94 to 49 parts by weight of at least one resin (A) selected from a thermoplastic resin and a thermosetting resin; 5 to 50 parts by weight of an inorganic reinforcing material (B); 1 to 46 parts by weight of a functional group-containing olefin polymer (C) containing a component having a Tg of −140° C. to 0° C. (total of the components (A), (B) and (C) being 100 parts by weight), and 0.01 to 10 parts by weight of an olefin wax (D) having an oxygen- or nitrogen-containing group, the weight ratio C/D of component C to component D being 0.1 to 30.

Abstract translation: 本发明要解决的问题是提供一种含有无机增强材料的成型树脂组合物，其能够使具有优异的耐冲击性，高表面光泽度和良好的脱模性的成型体。 该成型树脂组合物能够解决上述问题，该组合物包含：94〜49重量份的选自热塑性树脂和热固性树脂的至少一种树脂（A） 5〜50重量份的无机增强材料（B）; 1〜46重量份含有Tg为-140℃〜0℃的成分的含官能团的烯烃聚合物（C）（组分（A），（B）和（C） 为100重量份）和0.01〜10重量份的具有含氧或含氮基团的烯烃蜡（D），组分C与组分D的重量比C / D为0.1〜30。

公开(公告)号：US20160115334A1

公开(公告)日：2016-04-28

申请号：US14896059

申请日：2014-06-06

Applicant: MITSUI CHEMICALS, INC.

Inventor： Kuniaki KAWABE ,  Hirotaka KANAYA ,  Masakazu TANAKA ,  Toshiyuki ITO

IPC: C09D123/14

CPC classification number: C09D123/14 ,  C09D123/142 ,  C08L51/06

Abstract: The present invention relates to an olefin-based paint. The purpose of the present invention is to provide a paint with excellent organic solvent solubility or dispersibility, low paint viscosity, minimal coating irregularities even at high concentrations, excellent handling and storage stability, and excellent blocking resistance and coated film stability. In order to meet this purpose, an olefin-based paint is used that is characterized by containing a solution or dispersion obtained by dissolving or dispersing 0.1-55 parts by mass of a propylene-α-olefin copolymer (A) for 100 parts by mass of an organic solvent. The copolymer (A) is characterized by containing 60-90 mol % of propylene-derived constituent units (a) having a weight-average molecular weight (Mw), measured by GPC, in the range of 3,000 to 40,000, and 10-40 mol % of α-olefin-derived constituent units (b) having 4 or more carbon atoms [wherein (a)+(b)=100 mol %].

Abstract translation: 本发明涉及烯烃类涂料。 本发明的目的是提供具有优异的有机溶剂溶解性或分散性，低涂料粘度，甚至高浓度的最小涂布不规则性，优异的操作和储存稳定性以及优异的耐粘连性和涂膜稳定性的涂料。 为了达到这个目的，使用了一种烯烃类涂料，其特征在于含有将0.1-55质量份丙烯-α-烯烃共聚物（A）溶解或分散在100质量份 的有机溶剂。 共聚物（A）的特征在于含有60-90摩尔％的丙烯衍生的结构单元（a），其通过GPC测量的重均分子量（Mw）在3,000至40,000的范围内，并且10-40 摩尔％的具有4个以上碳原子的α-烯烃衍生的构成单元（b）[其中（a）+（b）= 100摩尔％]。

公开(公告)号：US20240076425A1

公开(公告)日：2024-03-07

申请号：US18280163

申请日：2022-02-24

Applicant: MITSUI CHEMICALS, INC.

Inventor： Akihiro ASANO ,  Masakazu TANAKA ,  Toyoaki SASAKI ,  Yusuke MIZOBUCHI ,  Takuya IWATA

IPC: C08F10/14 ,  C08L23/20 ,  C09D123/20

CPC classification number: C08F10/14 ,  C08L23/20 ,  C09D123/20

Abstract: To provide a 4-methyl-1-pentene polymer being excellent in storage stability when dissolved in a solvent and solubility, and being excellent in at least one of heat resistance, and a coating appearance when a coating film is stretched, for example, when such a film is bended or used in a flexible application.
A 4-methyl-1-pentene polymer (A) being a copolymer of 4-methyl-1-pentene and at least one selected from linear α-olefins having 6 to 20 carbon atoms, the 4-methyl-1-pentene polymer (A) satisfying the following requirements (I) and (II):



(I) an endotherm end temperature (TmE) in a melting (endothermic) curve measured by DSC is 230° C. or lower; and
(II) an exotherm start temperature (TcS) in a crystallization (exothermic) curve measured by DSC is 210° C. or lower.

公开(公告)号：US20200071475A1

公开(公告)日：2020-03-05

申请号：US16466279

申请日：2017-12-13

Applicant: MITSUI CHEMICALS, INC.

Inventor： Masakazu TANAKA ,  Toyoaki SASAKI ,  Yasuhito TSUGANE ,  Kenkichi YOSHIDA ,  Kenjiro TAKAMINE ,  Masahiko OKAMOTO ,  Takanori TADA

IPC: C08J5/18 ,  C08L67/02 ,  C08F10/14

Abstract: A polyester sheet including a polyester (A), a 4-methyl-1-pentene polymer (B) having a specific heat of fusion and a meso diad fraction (m) of 98.5 to 100%, and a compatibilizing agent (C), wherein content proportions of the (A), (B), and (C) are 60 to 98.9 parts by mass for (A), 1 to 25 parts by mass for (B), and 0.1 to 15 parts by mass for (C), when a total content of (A), (B), and (C) is set as 100 parts by mass, and wherein (B) satisfies the requirements (a) to (d) described herein.

公开(公告)号：US20170037227A1

公开(公告)日：2017-02-09

申请号：US15303970

申请日：2015-04-17

Applicant: MITSUI CHEMICALS, INC.

Inventor： Masakazu TANAKA ,  Kuniaki KAWABE ,  Hirotaka KANAYA ,  Keiichi TAKI ,  Yuichi KAIDA

IPC: C08L23/04 ,  C08L101/00 ,  C09J11/08 ,  G03G9/087 ,  C09J123/08

CPC classification number: C08L23/04 ,  C08L101/00 ,  C09J11/08 ,  C09J123/0853 ,  G03G9/08 ,  G03G9/087 ,  G03G9/08711

Abstract: Provided is a resin composition which contains (A) a polyethylene wax satisfying the requirements (i)-(iv) described below and (B) at least one resin selected from the group consisting of thermoplastic resins and thermosetting resins, wherein the mass ratio of (A) to (B) is from 0.1/99.9 to 50/50. This resin composition is useful for providing a toner which can be fixed by means of a relatively-low-temperature heating body and has good offset resistance, and which is suppressed in increase of particle diameters even if the toner is stored for a long period of time. (i) The weight average molecular weight (Mw) is within the range from 400 to 1,500. (ii) The molecular weight distribution (Mw/Mn) is within the range from 1.2 to 2.5. (iii) The penetration as measured at 25° C. is 5 dmm or less. (iv) The melting point (Tm) is within the range from 50° C. to 110° C.

Abstract translation: 提供一种树脂组合物，其含有（A）满足下述要求（i） - （iv）的聚乙烯蜡和（B）选自热塑性树脂和热固性树脂中的至少一种树脂，其中， （A）〜（B）为0.1 / 99.9〜50/50。 该树脂组合物可用于提供可通过相对低温加热体固定并具有良好的抗粘附性的调色剂，并且即使调色剂长时间储存​​也抑制了颗粒直径的增加 时间。 （i）重均分子量（Mw）在400〜1500的范围内。 （ii）分子量分布（Mw / Mn）在1.2〜2.5的范围内。 （iii）在25℃下测量的穿透度为5dmm以下。 （iv）熔点（Tm）在50℃〜110℃的范围内

公开(公告)号：US20230331969A1

公开(公告)日：2023-10-19

申请号：US18023339

申请日：2021-08-30

Applicant: MITSUI CHEMICALS, INC.

Inventor： Shota ISHIHARA ,  Masakazu TANAKA ,  Toyoaki SASAKI

IPC: C08L23/20 ,  C08F210/14 ,  H01G4/18

CPC classification number: C08L23/20 ,  C08F210/14 ,  H01G4/18 ,  C08L2201/08 ,  C08L2201/10 ,  C08L2203/16 ,  C08L2203/20 ,  C08L2205/025

Abstract: The present invention provides a resin composition including a 4-methyl-1-pentene copolymer (A) that satisfies particular requirements and a 4-methyl-1-pentene copolymer (B) that satisfies particular requirements. The resin composition of the present invention can provide a smooth film with a small surface roughness and can be suitably used for molded articles such as films for capacitors, while containing the 4-methyl-1-pentene copolymers and having properties such as heat resistance. A film for capacitors of the present invention has a small surface roughness and is smooth, which eliminates problems such as worsening of dielectric properties and shortening of service life.

公开(公告)号：US20210139622A1

公开(公告)日：2021-05-13

申请号：US16492125

申请日：2017-12-19

Applicant: MITSUI CHEMICALS, INC.

Inventor： Masakazu TANAKA ,  Toyoaki SASAKI ,  Tomoaki MATSUGI

IPC: C08F210/14

Abstract: A 4-methyl-1-pentene polymer (X) wherein a content of a constitutional unit derived from 4-methyl-1-pentene is 90 to 100% by mol; a content of a constitutional unit derived from at least one olefin selected from ethylene and an α-olefin, other than 4-methyl-1-pentene, having 3 to 20 carbon atoms is 0 to 10% by mol; and the 4-methyl-1-pentene polymer satisfies certain requirements (a) to (f): (a) a meso diad fraction (m) measured by 13C-NMR falling within a certain range; (b) a ratio of weight-average molecular weight Mw within a certain range; (c) a melt flow rate (MFR) within a certain range; (d) a cumulative weight fraction within a certain range; (e) a proportion of a polymer having a molecular weight of a certain range; and (f) a heat of fusion and a melting point of the 4-methyl-1-pentene polymer within certain ranges.

公开(公告)号：US20190048109A1

公开(公告)日：2019-02-14

申请号：US16078594

申请日：2017-02-21

Applicant: MITSUI CHEMICALS, INC.

Inventor： Masakazu TANAKA ,  Masahiko OKAMOTO ,  Makoto NAKANO ,  Sadahiko MATSUURA

IPC: C08F10/14 ,  C08J5/18

Abstract: A 4-methyl-1-pentene polymer having: a unit derived from 4-methyl-1-pentene of 90 to 100% by mol; a unit selected from ethylene and an α-olefin, other than 4-methyl-1-pentene, having 3 to 20 carbon atoms of 0 to 10% by mol; and the polymer satisfying the following requirements: (a) a meso diad fraction measured by 13C-NMR within the range of 98 to 100%; (b) a ratio of Z-average molecular weight Mz to weight-average molecular weight Mw measured by GPC within the range of 2.5 to 20; (c) a ratio of weight-average molecular weight Mw to number-average molecular weight Mn measured by GPC within the range of 3.6 to 30; (d) a melt flow rate measured under conditions of 260° C. and a 5 kg load (ASTM D1238) within the range of 0.1 to 500 g/10 min; and (e) an amount of a decane-soluble portion at 23° C. is 5.0% by mass or less.