公开(公告)号：US20100028679A1

公开(公告)日：2010-02-04

申请号：US12576062

申请日：2009-10-08

申请人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R.M. Martens ,  Stephen Nell Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

发明人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R.M. Martens ,  Stephen Nell Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

IPC分类号： C01B39/46 ,  B32B5/16 ,  C01B39/02

CPC分类号： B01J29/85 ,  C01B39/54 ,  C07C1/20 ,  C07C2529/70 ,  C07C2529/85 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S423/30 ,  Y10T428/2982 ,  C07C11/02

摘要： A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.

摘要翻译： 公开了一种硅铝磷酸盐分子筛，其包含CHA骨架型和AEI骨架型的第一和第二共生相，其中所述第一共生相的AEI / CHA比为约5/95至约40/60，如通过DIFFaX 分析中，第二共生相具有通过DIFFaX分析确定的约30/70至约的AEI / CHA比，并且所述分子筛具有约0.13至约0.24的二氧化硅与氧化铝的摩尔比（Si / Al 2）。

公开(公告)号：US07914760B2

公开(公告)日：2011-03-29

申请号：US12576062

申请日：2009-10-08

申请人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R. M. Martens ,  Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

发明人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R. M. Martens ,  Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

IPC分类号： C01B25/36 ,  C01B25/45 ,  B01J21/12 ,  B01J27/18 ,  B01J27/182

CPC分类号： B01J29/85 ,  C01B39/54 ,  C07C1/20 ,  C07C2529/70 ,  C07C2529/85 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S423/30 ,  Y10T428/2982 ,  C07C11/02

摘要： A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.

摘要翻译： 公开了一种硅铝磷酸盐分子筛，其包含CHA骨架型和AEI骨架型的第一和第二共生相，其中所述第一共生相的AEI / CHA比为约5/95至约40/60，如通过DIFFaX 分析中，第二共生相具有通过DIFFaX分析确定的约30/70至约的AEI / CHA比，并且所述分子筛具有约0.13至约0.24的二氧化硅与氧化铝的摩尔比（Si / Al 2）。

公开(公告)号：US07622624B2

公开(公告)日：2009-11-24

申请号：US11072830

申请日：2005-03-04

申请人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R. M. Martens ,  Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

发明人： Machteld M. Mertens ,  An Verberckmoes ,  Marcel J. Janssen ,  Yun Feng Chang ,  Luc R. M. Martens ,  Stephen Neil Vaughn ,  Kenneth Ray Clem ,  Wilfried J. Mortier

IPC分类号： C07C1/00 ,  C01B37/08

CPC分类号： B01J29/85 ,  C01B39/54 ,  C07C1/20 ,  C07C2529/70 ,  C07C2529/85 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S423/30 ,  Y10T428/2982 ,  C07C11/02

摘要： A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about 55/45 as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.

摘要翻译： 公开了一种硅铝磷酸盐分子筛，其包含CHA骨架型和AEI骨架型的第一和第二共生相，其中所述第一共生相的AEI / CHA比为约5/95至约40/60，如通过DIFFaX 分析表明，第二共生相具有通过DIFFaX分析确定的约30/70至约55/45的AEI / CHA比，并且所述分子筛具有约0.13至约0.24的二氧化硅与氧化铝的摩尔比（Si / Al 2）。

公开(公告)号：US06812372B2

公开(公告)日：2004-11-02

申请号：US09924016

申请日：2001-08-07

申请人： Marcel J. G. Janssen ,  An Verberckmoes ,  Machteld M. Mertens ,  Antonie Jan Bons ,  Wilfried J. Mortier

发明人： Marcel J. G. Janssen ,  An Verberckmoes ,  Machteld M. Mertens ,  Antonie Jan Bons ,  Wilfried J. Mortier

IPC分类号： B01J27182

CPC分类号： C01B39/54 ,  B01J29/005 ,  B01J29/85 ,  B01J37/0009 ,  C01B37/08 ,  C07C1/20 ,  C10G3/49 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02

摘要： The present invention relates to a silicoaluminophosphate molecular sieve comprising at least one intergrown phase of molecular sieves having AEI and CHA framework types, wherein said intergrown phase has an AEI/CHA ratio of from about 5/95 to 40/60 as determined by DIFFaX analysis, using the powder X-ray diffraction pattern of a calcined sample of said silicoaluminophosphate molecular sieve. It also relates to methods for its preparation and to its use in the catalytic conversion of methanol to olefins.

摘要翻译： 本发明涉及包含具有AEI和CHA骨架类型的分子筛的至少一个共生相的硅铝磷酸盐分子筛，其中所述共生相具有通过DIFFaX分析测定的约5/95至40/60的AEI / CHA比 ，使用所述硅铝磷酸盐分子筛的煅烧样品的粉末X射线衍射图。 它还涉及其制备方法及其在将甲醇催化转化成烯烃中的用途。

公开(公告)号：US06953767B2

公开(公告)日：2005-10-11

申请号：US10092792

申请日：2002-03-07

申请人： Marcel J. G. Janssen ,  An Verberckmoes ,  Machteld M. Mertens ,  Antonie Jan Bons ,  Wilfried J. Mortier

发明人： Marcel J. G. Janssen ,  An Verberckmoes ,  Machteld M. Mertens ,  Antonie Jan Bons ,  Wilfried J. Mortier

IPC分类号： B01J29/83 ,  B01J29/00 ,  B01J29/85 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C01B37/08 ,  C01B39/54 ,  C07B61/00 ,  C07C1/20 ,  C07C1/207 ,  C07C1/213 ,  C10G3/00 ,  C01B33/26 ,  B01J27/182 ,  C07C1/247

CPC分类号： B01J29/005 ,  B01J29/85 ,  B01J37/0009 ,  C01B37/08 ,  C01B39/54 ,  C07C1/20 ,  C10G3/49 ,  C10G2400/20 ,  Y02P30/20 ,  C07C11/02

摘要： The present invention relates to a silicoaluminophosphate molecular sieve comprising at least one intergrown phase of molecular sieves having AEI and CHA framework types, wherein said intergrown phase has an AEI/CHA ratio of from about 5/95 to 40/60 as determined by DIFFaX analysis, using the powder X-ray diffraction pattern of a calcined sample of said silicoaluminophosphate molecular sieve. It also relates to methods for its preparation and to its use in the catalytic conversion of methanol to olefins.

摘要翻译： 本发明涉及包含具有AEI和CHA骨架类型的分子筛的至少一个共生相的硅铝磷酸盐分子筛，其中所述共生相具有通过DIFFaX分析测定的约5/95至40/60的AEI / CHA比 ，使用所述硅铝磷酸盐分子筛的煅烧样品的粉末X射线衍射图。 它还涉及其制备方法及其在将甲醇催化转化成烯烃中的用途。

公开(公告)号：US07094389B2

公开(公告)日：2006-08-22

申请号：US11017286

申请日：2004-12-20

申请人： Guang Cao ,  Machteld M. Mertens ,  Karl G. Strohmaier ,  Richard B. Hall ,  Thomas Herman Colle ,  Mobae Afeworki ,  Antonie J. Bons ,  Wilfried J. Mortier ,  Chris Kliewer ,  Hailian Li ,  Anil S. Guram ,  Robert J. Saxton ,  Mark T. Muraoka ,  Jeffrey C. Yoder

发明人： Guang Cao ,  Machteld M. Mertens ,  Karl G. Strohmaier ,  Richard B. Hall ,  Thomas Herman Colle ,  Mobae Afeworki ,  Antonie J. Bons ,  Wilfried J. Mortier ,  Chris Kliewer ,  Hailian Li ,  Anil S. Guram ,  Robert J. Saxton ,  Mark T. Muraoka ,  Jeffrey C. Yoder

IPC分类号： C01B39/48

CPC分类号： C01B39/46 ,  C01B37/02 ,  C01B39/023 ,  C01B39/48 ,  C10G3/45 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/708 ,  C10G2300/802 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42

摘要： A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.

摘要翻译： 基本上不含骨架磷的结晶物质，其包含具有堆垛层错的CHA骨架型分子筛或CHA骨架型分子筛和AEI骨架型分子筛的至少一个共生相，其中所述材料以其煅烧的无水形式 具有涉及摩尔关系的组成：<？in-line-formula description =“In-line Formulas”end =“lead”？>（n）X＆lt; 2＆lt; 3＆lt; 3＆ 其中X是三价元素;其中X是三价元素;其中X是三价元素; Y是四价元素; 且n为0至约0.5。 该材料在甲醇转化为低级烯烃，特别是乙烯和丙烯时具有活性和选择性。

公开(公告)号：US06316683B1

公开(公告)日：2001-11-13

申请号：US09391770

申请日：1999-09-08

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C07C120

CPC分类号： B01J37/08 ,  B01J29/85 ,  B01J2229/24 ,  B01J2229/40 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G2300/4018 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

公开(公告)号：US07345213B2

公开(公告)日：2008-03-18

申请号：US10615753

申请日：2003-07-09

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C01C1/00 ,  B01J27/82

CPC分类号： B01J29/85 ,  B01J37/08 ,  B01J2229/24 ,  B01J2229/40 ,  B23K1/002 ,  B23K2101/06 ,  C07C1/20 ,  C07C2529/85 ,  Y02P30/20 ,  Y10S502/514 ,  Y10S585/906 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

摘要翻译： 本发明涉及从含氧化合物原料制备烯烃产物的方法和保护硅铝磷酸盐分子筛的催化活性的方法。 所述方法包括提供在分子筛内具有催化位点的硅铝磷酸盐分子筛; 屏蔽催化部位以防止催化活性的丧失; 并且在有效产生烯烃产物的条件下，在不期望的催化活性丧失之前，将处于其活化状态的受保护筛与含氧化合物原料接触。 当活化分子筛与含氧化合物原料接触的甲醇吸收指数至少为0.15时，催化活性就会出现不希望的损失。

公开(公告)号：US06503863B2

公开(公告)日：2003-01-07

申请号：US09929949

申请日：2001-08-15

申请人： Shun C. Fung ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Machteld M. Mertens ,  Albert Edward Schweizer ,  Luc R. M. Martens ,  Richard B. Hall ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Yi-Gang Xiong

发明人： Shun C. Fung ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Machteld M. Mertens ,  Albert Edward Schweizer ,  Luc R. M. Martens ,  Richard B. Hall ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Yi-Gang Xiong

IPC分类号： B01J27182

CPC分类号： C01B39/02 ,  B01J29/04 ,  B01J29/85 ,  B01J37/084 ,  B01J2229/14 ,  B01J2229/24 ,  B01J2229/40 ,  B01J2229/42 ,  C01B37/00 ,  C07C1/20 ,  C07C2529/85 ,  C07C11/02

摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.

公开(公告)号：US06455748B2

公开(公告)日：2002-09-24

申请号：US09760289

申请日：2001-01-12

申请人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Marcel J. G. Janssen ,  Cornelius W. M. Van Oorschot ,  Shun C. Fung ,  Luc R. M. Martens ,  Wilfried J. Mortier ,  Ronald G. Searle ,  Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C07C100

CPC分类号： B01J37/08 ,  B01J29/85 ,  B01J2229/24 ,  B01J2229/40 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G2300/4018 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.

摘要翻译： 本发明涉及从含氧化合物原料制备烯烃产物的方法和保护硅铝磷酸盐分子筛的催化活性的方法。 所述方法包括提供在分子筛内具有催化位点的硅铝磷酸盐分子筛; 屏蔽催化部位以防止催化活性的丧失; 并且在有效产生烯烃产物的条件下，在不期望的催化活性丧失之前，将处于其活化状态的受保护筛与含氧化合物原料接触。 当活化分子筛与含氧化合物原料接触的甲醇吸收指数至少为0.15时，催化活性就会出现不希望的损失。