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    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
    3.
    发明授权
    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
    含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途

    公开(公告)号：US07754187B2

    公开(公告)日：2010-07-13

    申请号：US11820908

    申请日：2007-06-21

    申请人： Guang Cao ,  Machteld M. Mertens ,  Anil S. Guram ,  Hailian Li ,  Jeffrey C. Yoder

    发明人： Guang Cao ,  Machteld M. Mertens ,  Anil S. Guram ,  Hailian Li ,  Jeffrey C. Yoder

    IPC分类号： C01B37/02 ,  C01B39/04

    CPC分类号： C01B39/48 ,  B01J29/70 ,  B01J29/80 ,  C01B39/023 ,  C07C1/20 ,  Y02P30/42 ,  C07C11/02

    摘要： A method is disclosed of synthesizing a crystalline material comprising a CHA framework type molecular sieve and having a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to less than 0.01. The method comprises preparing a reaction mixture capable of forming said material, said mixture comprising a source of water, a source of an oxide of a tetravalent element Y and optionally a source of an oxide of a trivalent element X, wherein the reaction mixture is substantially free of fluoride ions added as HF; maintaining the reaction mixture under conditions sufficient to form crystals of the crystalline material; and than recovering the crystalline material. The reaction mixture comprises either a specific directing agent for directing the formation of a CHA framework type molecular sieve and/or a H2O:YO2 molar ratio of greater than 20. In one embodiment, the resultant crystalline material is free of stacking faults and/or any intergrown phase with an AEI framework type molecular sieve.

    摘要翻译： 公开了一种合成包含CHA骨架型分子筛并具有摩尔关系的组成的结晶材料的方法：（n）X 2 O 3：YO 2，其中X是三价元素; Y是四价元素; 并且n为0至小于0.01。 该方法包括制备能够形成所述材料的反应混合物，所述混合物包含水源，四价元素Y的氧化物源和任选的三价元素X的氧化物源，其中反应混合物基本上 不含氟离子作为HF添加; 在足以形成结晶材料晶体的条件下保持反应混合物; 而不是回收结晶材料。 反应混合物包括用于引导形成CHA骨架型分子筛和/或H 2 O:YO 2摩尔比大于20的特定导向剂。在一个实施方案中，所得结晶材料不含堆垛层错和/或 任何与AEI框架型分子筛的共生相。

    Synthesis of Chabazite-Containing Molecular Sieves and Their Use in the Conversion of Oxygenates to Olefins
    4.
    发明申请
    Synthesis of Chabazite-Containing Molecular Sieves and Their Use in the Conversion of Oxygenates to Olefins 有权
    含有含异噻唑啉的分子筛的合成及其在烯烃转化中的应用

    公开(公告)号：US20120202954A1

    公开(公告)日：2012-08-09

    申请号：US13449424

    申请日：2012-04-18

    申请人： Machteld M. Mertens ,  Stephen N. Vaughn ,  Guang Cao ,  Luc R.M. Martens ,  Mobae Afeworki

    发明人： Machteld M. Mertens ,  Stephen N. Vaughn ,  Guang Cao ,  Luc R.M. Martens ,  Mobae Afeworki

    IPC分类号： C08F10/02 ,  C08F10/06 ,  C08F2/00

    CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

    摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.

    摘要翻译： 在合成具有90％+ CHA骨架类型特征的硅铝磷酸盐分子筛的方法中，制备反应混合物，其包括首先将活性的铝源与磷的反应源混合以形成老化的初级混合物。 然后可以加入硅的反应性源和用于引导分子筛形成的模板以形成合成混合物。 然后在合成混合物中诱导结晶。 有利地，（i）硅源包含有机硅酸盐，（ii）磷源任选地包含有机磷酸盐，和（iii）结晶的硅铝磷酸盐分子筛具有使其平均晶体尺寸不大于5的晶体尺寸分布 μm。 分子筛可以优选用于烃（含氧化合物 - 烯烃）转化过程中。

    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
    5.
    发明授权
    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
    含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途

    公开(公告)号：US08182780B2

    公开(公告)日：2012-05-22

    申请号：US12477750

    申请日：2009-06-03

    申请人： Machteld M. Mertens ,  Stephen N. Vaughn ,  Guang Cao ,  Luc R. M. Martens ,  Mobae Afeworki

    发明人： Machteld M. Mertens ,  Stephen N. Vaughn ,  Guang Cao ,  Luc R. M. Martens ,  Mobae Afeworki

    IPC分类号： C01B37/08 ,  B01J27/182 ,  C07C1/24

    CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

    摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.

    摘要翻译： 在合成具有90％+ CHA骨架类型特征的硅铝磷酸盐分子筛的方法中，制备反应混合物，其包括首先将活性的铝源与磷的反应源混合以形成老化的初级混合物。 然后可以加入硅的反应性源和用于引导分子筛形成的模板以形成合成混合物。 然后在合成混合物中诱导结晶。 有利地，（i）硅源包含有机硅酸盐，（ii）磷源任选地包含有机磷酸盐，和（iii）结晶的硅铝磷酸盐分子筛具有使其平均晶体尺寸不大于5的晶体尺寸分布 μm。 分子筛可以优选用于烃（含氧化合物 - 烯烃）转化过程中。