摘要:
A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要:
A crystalline material has a DDR framework type and, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element, Y is a tetravalent element and n is from 0 to less than 0.01 and wherein the crystals of said material have an average diameter less than or equal to 2 microns. The material is synthesized in the presence of an N-ethyltropanium compound as directing agent.
摘要翻译:结晶材料具有DDR框架型,并且以其煅烧的无水形式具有涉及摩尔关系的组成:<?in-line-formula description =“In-line formula”end =“lead”?>(n) X 2 O 3:YO 2,<β在线式描述=“在线式”末端=“尾”→其中X为三价元素,Y为四价元素,n为0至小于0.01,其中 所述材料的晶体具有小于或等于2微米的平均直径。 该物质在N-乙基anium化合物作为引导剂的存在下合成。
摘要:
A crystalline material is described that has an AEI framework type, wherein the material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element, Y is a tetravalent element n is from 0 to less than 0.01. The material is normally synthesized in a halide, typically a fluoride, medium and exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译:描述了具有AEI骨架类型的结晶材料,其中以煅烧的无水形式的材料具有涉及摩尔关系的组成:<?in-line-formula description =“In-line Formulas”end =“lead “?”(n)X 2 O 3:YO 2,<βin-line-formula description =“In-Line Formulas” end =“tail”?>其中X为三价元素,Y为四价元素,n为0至小于0.01。 该材料通常在卤化物(通常为氟化物)介质中合成,并且在甲醇转化为低级烯烃,特别是乙烯和丙烯中表现出活性和选择性。
摘要:
A method for the post synthesis modification of molecular sieves with organometallic reagents. The method may be used for large pore molecular sieves and small pore molecular sieves, such as SAPO-34. SAPO-34 is a useful catalyst for the conversion of oxygenates, such as methanol, to olefins. Post synthesis organometallic modification improves catalyst performance and increases light olefin selectivity in the conversion of methanol to olefins.
摘要:
The invention is directed to a method for preparing microporous aluminophosphate or silicoaluminophosphate molecular sieves having the CHA framework type, the process comprising the steps of a) forming a reaction mixture comprising a source of aluminum, a source of phosphorus, optionally a source of silicon, at least one source of fluoride ions and at least one template containing one or more N,N-dimethylamino moieties, b) inducing crystallization of aluminophosphate and/or silicoaluminophosphate molecular sieve from the reaction mixture; c) recovering aluminophosphate and/or silicoaluminophosphate molecular sieve from the reaction mixture. The invention also relates to the molecular sieves obtained by this method and to molecular sieve catalyst compositions containing these molecular sieves.
摘要:
A method for the post synthesis modification of molecular sieves with organometallic reagents. The method may be used for large pore molecular sieves and small pore molecular sieves, such as SAPO-34. SAPO-34 is a useful catalyst for the conversion of oxygenates, such as methanol, to olefins. Post synthesis organometallic modification improves catalyst performance and increases light olefin selectivity in the conversion of methanol to olefins.
摘要:
The invention is directed to a method of synthesizing aluminophosphate or silicoaluminophosphate molecular sieves and in particular to the synthesis of silicoaluminophosphate molecular sieves using synthesis templates in combination with a source of fluoride comprising at least two fluoride substituents. The use of such fluorine containing compounds results in good quality low silica SAPO molecular sieves of CHA framework type.
摘要:
A large pore (metallo)aluminophosphate molecular sieve is disclosed The material has an X-ray diffraction pattern including the lines listed in Table 4 and is synthesized in the presence of 4-dimethylaminopyridine as structure directing agent.
摘要:
In a process for selectively separating 1-butene from a C4 feed stream comprising at least 1-butene, cis-2-butene and trans-2-butene, the feed stream is passed through a first bed of an adsorbent comprising a crystalline microporous material to form a substantially trans-2-butene-free effluent stream. Then, the substantially trans-2-butene-free effluent stream is passed through a second bed of an adsorbent comprising a crystalline microporous material to form a substantially 1-butene-free effluent stream, whereby the 1-butene is separated from the feed stream. The adsorbed 1-butene is then typically desorbed from the second adsorbent bed either by lowering the pressure or raising the temperature of the bed.
摘要翻译:在从包含至少1-丁烯,顺式-2-丁烯和反式-2-丁烯的C 4 H 4进料流中选择性分离1-丁烯的方法中,使进料流通过第一床 的吸附剂,其包含结晶微孔材料以形成基本上反式-2-丁烯的流出物流。 然后,将基本上反式-2-丁烯的流出物流通过包含结晶微孔材料的吸附剂的第二床,以形成基本上不含1-丁烯的流出物流,由此从进料流中分离出1-丁烯 。 吸附的1-丁烯通常通过降低压力或升高床的温度而从第二吸附剂床解吸。
摘要:
A method for maintaining the activity of silicoaluminophosphate (SAPO) molecular sieve catalyst particles during oxygenate to olefin conversion reactions. After regeneration of SAPO catalyst particles, the regenerated particles are mixed with particles having coke on their surface in a manner that maintains their catalytic activity at a predetermined level.