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公开(公告)号：US20060224002A1
公开(公告)日：2006-10-05
申请号：US11382760
申请日：2006-05-11
CPC分类号： C07F15/008 , B01J31/185 , B01J31/1855 , B01J31/186 , B01J31/2234 , B01J31/2295 , B01J2231/32 , B01J2231/321 , B01J2231/641 , B01J2531/16 , B01J2531/80 , B01J2531/822 , C07C45/505 , C07F9/657154 , C07F9/65746 , C07F15/0073
摘要： The invention claims chiral di- and triphosphites of general formulas (I) or (II), which are bridged by suitable groups. The claimed compounds can be used in asymmetric transition metal catalysis and as chiral transition metal catalysts.
摘要翻译： 本发明要求通过合适的基团桥连的通式（I）或（II）的手性二 - 和三亚磷酸酯。 所要求保护的化合物可用于不对称过渡金属催化剂和手性过渡金属催化剂。
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公开(公告)号：US09061963B2
公开(公告)日：2015-06-23
申请号：US14111217
申请日：2012-04-03
申请人： Manfred Reetz , Gerlinde Mehler
发明人： Manfred Reetz , Gerlinde Mehler
IPC分类号： C07D215/38 , C07D217/22 , C07D295/033 , C07D213/74 , C07C209/10 , C07B43/04
CPC分类号： C07C209/10 , C07B43/04 , C07D213/74 , C07D215/38 , C07D217/22 , C07D295/033
摘要： A process is described for preparing aromatic and heteroaromatic amines of the general formula (I) Ar—NR1R2, in which an aromatic compound with the general formula (II) Ar—X is reacted in the presence of a catalyst with an amine of the general formula (III) H—NR1R2 and a base, wherein the catalyst is selected from transition metal complexes having one or more ligands with the general formula (IV).
摘要翻译： 描述了用于制备通式（I）Ar-NR1R2的芳族和杂芳族胺的方法，其中通式（II）Ar-X的芳族化合物在催化剂存在下与一般的胺反应 式（III）H-NR1R2和碱，其中催化剂选自具有一个或多个具有通式（IV）的配体的过渡金属配合物。
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公开(公告)号：US20140213785A1
公开(公告)日：2014-07-31
申请号：US14111217
申请日：2012-04-03
申请人： Manfred Reetz , Gerlinde Mehler
发明人： Manfred Reetz , Gerlinde Mehler
IPC分类号： C07C209/10 , C07D217/22 , C07D215/38 , C07D295/033 , C07D213/74
CPC分类号： C07C209/10 , C07B43/04 , C07D213/74 , C07D215/38 , C07D217/22 , C07D295/033
摘要： A process is described for preparing aromatic and heteroaromatic amines of the general formula (I) Ar—NR1R2, in which an aromatic compound with the general formula (II) Ar—X is reacted in the presence of a catalyst with an amine of the general formula (III) H—NR1R2 and a base, wherein the catalyst is selected from transition metal complexes having one or more ligands with the general formula (IV).
摘要翻译： 描述了用于制备通式（I）Ar-NR1R2的芳族和杂芳族胺的方法，其中通式（II）Ar-X的芳族化合物在催化剂存在下与一般的胺反应 式（III）H-NR1R2和碱，其中催化剂选自具有一个或多个具有通式（IV）的配体的过渡金属配合物。
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4.发明申请Mixtures of chiral monophosphorus compounds used as ligand systems for asymmetric transition metal catalysis 失效用作不对称过渡金属催化配体体系的手性单磷化合物的混合物公开(公告)号：US20060014981A1
公开(公告)日：2006-01-19
申请号：US10530818
申请日：2003-09-26
CPC分类号： B01J31/185 , B01J23/464 , B01J31/1845 , B01J31/1855 , B01J31/1865 , B01J31/187 , B01J31/24 , B01J31/2409 , B01J31/2452 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/327 , B01J2231/342 , B01J2231/348 , B01J2231/4211 , B01J2231/4238 , B01J2231/4255 , B01J2231/4261 , B01J2231/641 , B01J2231/72 , B01J2531/0266 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07B53/00 , C07C67/303 , C07C231/12 , C07F9/46 , C07F9/5022 , C07F9/52 , C07F9/6568 , C07F9/65683 , C07F9/65742 , C07F9/65744 , C07F9/65842 , C07F9/65844 , C07F9/65848 , Y10S502/506 , C07C69/34 , C07C233/05 , C07C233/13 , C07C233/18
摘要： The invention relates to certain chiral transition metal catalysts, to the metal of which at least two structurally different monophosphorus ligands are bonded, at least one of said monophosphorus ligands being chiral. Said chiral transition metal catalysts are suitable as catalysts for use in asymmetric transition metal-catalyzed reactions, providing better enantioselectivities than in cases where only one structurally defined ligand is used.
摘要翻译： 本发明涉及某些手性过渡金属催化剂，其至少两个结构不同的单磷配体键合的金属，所述单磷配体中的至少一个是手性的。 所述手性过渡金属催化剂适合用作不对称过渡金属催化反应的催化剂，与仅使用一种结构限定的配体的情况相比，提供更好的对映选择性。
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公开(公告)号：US07265237B2
公开(公告)日：2007-09-04
申请号：US10297315
申请日：2001-06-05
IPC分类号： C07C253/00
CPC分类号： C07F9/65744 , C07B53/00 , C07B2200/07 , C07C67/303 , C07F9/657127 , C07C69/34
摘要： Certain chiral monophosphites and their monothio derivatives are suitable as ligands in the asymmetrical transition-metal-catalyzed hydrogenation, hydroborination and hydrocyanation of prochiral olefins, ketones and imines.
摘要翻译： 某些手性单亚磷酸酯及其单硫代衍生物适用于非手性过渡金属催化的氢化，加氢硼氢化和前体手性烯烃，酮和亚胺的氢化氰化物中的配体。
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6.发明授权Mixtures of chiral monophosphorus compounds used as ligand systems for asymmetric transition metal catalysis 失效用作不对称过渡金属催化配体体系的手性单磷化合物的混合物公开(公告)号：US07704912B2
公开(公告)日：2010-04-27
申请号：US10530818
申请日：2003-09-26
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , B01J27/00 , B01J21/04 , B01J23/02
CPC分类号： B01J31/185 , B01J23/464 , B01J31/1845 , B01J31/1855 , B01J31/1865 , B01J31/187 , B01J31/24 , B01J31/2409 , B01J31/2452 , B01J2231/321 , B01J2231/323 , B01J2231/325 , B01J2231/326 , B01J2231/327 , B01J2231/342 , B01J2231/348 , B01J2231/4211 , B01J2231/4238 , B01J2231/4255 , B01J2231/4261 , B01J2231/641 , B01J2231/72 , B01J2531/0266 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07B53/00 , C07C67/303 , C07C231/12 , C07F9/46 , C07F9/5022 , C07F9/52 , C07F9/6568 , C07F9/65683 , C07F9/65742 , C07F9/65744 , C07F9/65842 , C07F9/65844 , C07F9/65848 , Y10S502/506 , C07C69/34 , C07C233/05 , C07C233/13 , C07C233/18
摘要： The invention relates to certain chiral transition metal catalysts, to the metal of which at least two structurally different monophosphorus ligands are bonded, at least one of said monophosphorus ligands being chiral. Said chiral transition metal catalysts are suitable as catalysts for use in asymmetric transition metal-catalyzed reactions, providing better enantioselectivities than in cases where only one structurally defined ligand is used.
摘要翻译： 本发明涉及某些手性过渡金属催化剂，其至少两个结构不同的单磷配体键合的金属，所述单磷配体中的至少一个是手性的。 所述手性过渡金属催化剂适合用作不对称过渡金属催化反应的催化剂，与仅使用一种结构限定的配体的情况相比，提供更好的对映选择性。
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公开(公告)号：US20080207942A1
公开(公告)日：2008-08-28
申请号：US12066790
申请日：2006-09-12
申请人： Manfred T. Reetz , Gerlinde Mehler
发明人： Manfred T. Reetz , Gerlinde Mehler
IPC分类号： C07F9/547 , C07F9/576 , B01J31/02 , C07C69/34 , C07C229/06
CPC分类号： C07F9/657154 , B01J31/1845 , B01J2231/643 , B01J2531/822 , C07B53/00 , C07F15/008
摘要： Phosphoramidites with the general formulae I to VI are claimed together with the use of these compounds as ligands of transition metal compounds, in particular in transition metal catalysts, in the hydrogenation, transfer hydrogenation, hydroboration, hydrocyanation, 1,4-addition, hydroformylation, hydrosilylation, hydrovinylation, and Heck reactions of prochiral olefins, ketones, or ketimines.
摘要翻译： 具有通式I至VI的亚磷酰胺要求以及这些化合物作为过渡金属化合物的配体，特别是过渡金属催化剂在氢化，转移氢化，氢硼化，氢氰化，1,4-加成，加氢甲酰化， 前手性烯烃，酮或酮亚胺的氢化硅烷化，氢化和Heck反应。
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