Use of aqueous film-forming preparations based on copolymers of methacrylic acid alkyl esters for coating mineral shaped bodies
    1.
    发明授权
    Use of aqueous film-forming preparations based on copolymers of methacrylic acid alkyl esters for coating mineral shaped bodies 失效
    使用基于甲基丙烯酸烷基酯共聚物的水性成膜剂用于涂覆矿物质体

    公开(公告)号:US06372287B1

    公开(公告)日:2002-04-16

    申请号:US09623874

    申请日:2000-09-11

    IPC分类号: B05D138

    CPC分类号: C04B41/483 C08F20/18

    摘要: The present invention provides for the use of aqueous film-forming formulations comprising at least one copolymer P as film-forming constituent which is present in disperse form in the formulation and is composed of ethylenically unsaturated monomers M, the monomers M comprising i. from 70 to 99.9% by weight of at least one ester of methacrylic acid with a C1-C10-alkanol and ii. from 0.1 to 30% by weight of at least one different monoethylenically unsaturated monomer and at least 50% by weight of the monomers M being other than methyl methacrylate and not more than 1% by weight of the monomers M having two or more ethylenically unsaturated double bonds, for coating mineral moldings. The present invention additionally provides a method of coating the mineral moldings, and also the mineral moldings themselves.

    摘要翻译: 本发明提供包含至少一种共聚物P作为成膜组分的含水成膜剂,其用于分散形式存在于制剂中并且由烯属不饱和单体M组成,单体M包含1。 70至99.9重量%的至少一种甲基丙烯酸与C 1 -C 10烷醇和ii的酯。 0.1至30重量%的至少一种不同的单烯属不饱和单体和至少50重量%的单体M不同于甲基丙烯酸甲酯和不超过1重量%的具有两个或更多个烯属不饱和双键的单体M ,用于涂覆矿物模制品。本发明另外提供了一种涂覆矿物模制品的方法,以及矿物模制品本身。

    Aqueous, film forming preparations for coating mineral shaped bodies
    3.
    发明授权
    Aqueous, film forming preparations for coating mineral shaped bodies 有权
    用于涂层矿物成型体的水性成膜剂

    公开(公告)号:US06500492B1

    公开(公告)日:2002-12-31

    申请号:US09787895

    申请日:2001-03-28

    IPC分类号: B32B1300

    摘要: The present invention provides for the use of film-forming aqueous formulations comprising in dispersed form at least one crosslinked copolymer P for coating shaped mineral articles and for a method of coating shaped mineral articles, said copolymer P comprising in copolymerized form a) from 80 to 99.89% by weight of at least one monomer selected from esters of acrylic acid with C1-C12-alkanols, esters of methacrylic acid with C1-C8-alkanols, and monovinylaromatics, b) from 0.1 to 19.99% by weight of at least one monomer different from a), and c) from 0.01 to 1.9% by weight of at least one crosslinking monomer selected from esters of acrylic or methacrylic acid with linear or branched C3-C6-alkenols, cyclic C5-C7-alkenols and polycyclic C2-C12-alkenols.

    摘要翻译: 本发明提供了使用成膜水性制剂,其包含分散形式的至少一种交联共聚物P用于涂覆成型矿物制品和用于涂覆成形矿物制品的方法,所述共聚物P包含共聚形式)80至99.89 选自丙烯酸与C 1 -C 12烷醇的酯,甲基丙烯酸与C 1 -C 8 - 链烷醇的酯和单乙烯基芳族化合物的至少一种单体的重量%,b)0.1至19.99重量%的至少一种不同的单体 至少一种选自丙烯酸或甲基丙烯酸的酯与直链或支链C 3 -C 6 - 烯醇的交联单体,环状C 5 -C 7链烯醇和多环C 2 -C 12链烯 。

    Process of coating a mineral molding with an aqueous preparation comprising, as film-forming constituent, at least one polymer P
    4.
    发明授权
    Process of coating a mineral molding with an aqueous preparation comprising, as film-forming constituent, at least one polymer P 有权
    用包含作为成膜组分的至少一种聚合物P的水性制剂涂覆矿物模塑的方法

    公开(公告)号:US06472024B1

    公开(公告)日:2002-10-29

    申请号:US09349511

    申请日:1999-07-09

    IPC分类号: B05D700

    摘要: A method of coating a mineral molding includes applying at least one aqueous preparation to at least one surface of the molding, the aqueous preparation including: (i) as film-forming constituent at least one polymer P which is composed of ethylenically unsaturated monomers M and which is present in dispersed form in the aqueous phase of the aqueous preparation and which has a glass transition temperature TG in the range from −25 to +80° C.; (ii) at least one anionic emulsifier selected from the group consisting of (a), (b), and (c): (a) salts of formula I: Alk−{O—Et}n—OSO2O−M+  (I)  wherein Alk is linear or branched, saturated alkyl having from 10 to 18 carbon atoms, Et is 1,2-ethylene, n is an integer from 25 to 40, and M+ is a monovalent cation or a cation equivalent, (b) mixtures of salts of formula I; and (c) mixtures of salts of formula I with other anionic emulsifiers, wherein the salts of formula I make up at least 80% by weight of the anionic emulsifiers; and (iii) at least one nonionic emulsifier.

    摘要翻译: 一种涂覆矿物成型的方法包括将至少一种含水制剂施用于模制品的至少一个表面,所述水性制剂包括:(i)作为成膜组分的至少一种聚合物P,其由烯属不饱和单体M和 其以分散形式存在于水性制剂的水相中,并且其玻璃化转变温度TG在-25至+ 80℃范围内;(ii)至少一种阴离子乳化剂,其选自( a),(b)和(c):( a)式I的盐:其中Alk是直链或支链的,具有10至18个碳原子的饱和烷基,Et是1,2-亚乙基,n是25的整数 至40,并且M +是一价阳离子或阳离子当量,(b)式I的盐的混合物; 和(c)式I的盐与其它阴离子乳化剂的混合物,其中式I的盐占阴离子乳化剂的至少80重量%; 和(iii)至少一种非离子乳化剂。

    Method for Producing Aqueous Composite Particle Dispersions
    8.
    发明申请
    Method for Producing Aqueous Composite Particle Dispersions 失效
    生产水性复合粒子分散体的方法

    公开(公告)号:US20080051500A1

    公开(公告)日:2008-02-28

    申请号:US11813456

    申请日:2005-12-31

    申请人: Harm Wiese

    发明人: Harm Wiese

    摘要: A process for preparing an aqueous dispersion of particles composed of addition polymer and finely divided inorganic solid (composite particles), in which process ethylenically unsaturated monomers are dispersely distributed in aqueous medium and polymerized by the method of free-radical aqueous emulsion polymerization by means of at least one free-radical polymerization initiator in the presence of at least one dispersely distributed, finely divided inorganic solid and at least one dispersant, which comprises using a monomer mixture comprising >0 and ≦10% by weight of at least one ethylenically unsaturated monomer containing an epoxide group.

    摘要翻译: 一种制备由加成聚合物和细碎无机固体(复合颗粒)组成的颗粒的水性分散体的方法,其中烯键式不饱和单体分散在水性介质中并通过自由基水乳液聚合方法通过自由基水乳液聚合方法进行聚合, 在至少一种分散分散的细碎无机固体和至少一种分散剂的存在下,至少一种自由基聚合引发剂,其包括使用包含≥0和≤10重量%的至少一种烯键式不饱和单体的单体混合物 含有环氧基的单体。

    Coating Materials
    9.
    发明申请
    Coating Materials 审中-公开
    涂料

    公开(公告)号:US20070269650A1

    公开(公告)日:2007-11-22

    申请号:US11718729

    申请日:2005-10-27

    IPC分类号: B32B5/16 B05D3/02 C09D1/00

    CPC分类号: C09D5/028 Y10T428/254

    摘要: Aqueous coating materials comprising a) particles having an average size ≧10 nm and ≦500 nm composed of addition polymer and finely divided inorganic solid (composite particles) and b) at least one pulverulent pigment selected from the group comprising zinc oxide, zinc sulfide, iron(III) oxide, tin dioxide and also titanium dioxide in the rutile, anatase and brookite modification.

    摘要翻译: 包含a)具有由加成聚合物和细碎无机固体(复合颗粒)组成的平均尺寸> 10nm和<= 500nm的颗粒的水性涂料,和b)至少一种选自氧化锌,锌 硫化物,氧化铁(III),二氧化锡和二氧化钛在金红石,锐钛矿和板钛矿改性。