公开(公告)号：US09701803B2

公开(公告)日：2017-07-11

申请号：US14118906

申请日：2012-05-25

申请人： Michael W Cobb ,  Vincent Galante ,  Mark Andrew Harmer ,  Vivek Kapur ,  Sharlene Renee Williams

发明人： Michael W Cobb ,  Vincent Galante ,  Mark Andrew Harmer ,  Vivek Kapur ,  Sharlene Renee Williams

IPC分类号： C08J9/12 ,  B32B5/18 ,  B32B5/02 ,  B32B7/12 ,  B32B13/04 ,  B32B15/04 ,  B32B15/18 ,  B32B15/20 ,  B32B21/04 ,  B32B27/06 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B29/00 ,  C08G65/40 ,  C08J9/14

CPC分类号： C08J9/12 ,  B32B5/022 ,  B32B5/024 ,  B32B5/18 ,  B32B7/12 ,  B32B13/045 ,  B32B15/046 ,  B32B15/18 ,  B32B15/20 ,  B32B21/047 ,  B32B27/065 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B29/007 ,  B32B2250/40 ,  B32B2255/26 ,  B32B2266/02 ,  B32B2266/0214 ,  B32B2266/0228 ,  B32B2266/0278 ,  B32B2266/06 ,  B32B2266/08 ,  B32B2266/104 ,  B32B2266/126 ,  B32B2307/304 ,  B32B2419/00 ,  C08G65/40 ,  C08J9/141 ,  C08J9/146 ,  C08J2205/052 ,  C08J2397/00 ,  C08J2399/00 ,  C08J2459/00 ,  Y10T428/249976

摘要： Disclosed are foam compositions and processes to form closed-cell tannin-based foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a tannin-based resin derived from a tannin, a first monomer, and a second monomer, wherein the first monomer comprises formaldehyde, paraformaldehyde, furfural, glyoxal, acetaldehyde, 5-hydroxymethylfurfural, acrolein, levulinate esters, sugars, 2,5-furandicarboxylic acid, 2,5-furandicarboxylic aldehyde, urea, difurfural (DFF), or mixtures thereof, and the second monomer comprises furfuryl alcohol, glycerol, sorbitol, lignin, or mixtures thereof, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising one or more blowing agents.

公开(公告)号：US09260579B2

公开(公告)日：2016-02-16

申请号：US14118940

申请日：2012-05-25

申请人： Michael W Cobb ,  Mark Andrew Harmer ,  Vivek Kapur ,  Ann Y Liauw ,  Sharlene Renee Williams

发明人： Michael W Cobb ,  Mark Andrew Harmer ,  Vivek Kapur ,  Ann Y Liauw ,  Sharlene Renee Williams

IPC分类号： C08J9/14 ,  C08J9/00 ,  B32B5/18

CPC分类号： C08J9/146 ,  B29C44/02 ,  B29C44/3415 ,  B29K2061/00 ,  B29K2105/046 ,  B29K2995/0015 ,  B29K2995/0016 ,  B29L2031/10 ,  B32B5/18 ,  C08J9/0061 ,  C08J9/14 ,  C08J9/141 ,  C08J2203/162 ,  C08J2361/06 ,  C08J2361/12 ,  C08J2497/00 ,  C08J2499/00 ,  E04C2/284 ,  Y10T428/249976

摘要： Disclosed are foam compositions and processes to form mixed tannin-phenolic foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a mixed-resin derived from a phenol, a tannin, and a first monomer, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising one or more blowing agents.

摘要翻译： 公开了形成混合单宁 - 酚醛泡沫的泡沫组合物和方法。 泡沫包括限定多个细胞的连续聚合物相，其中所述连续聚合物相包含衍生自苯酚，单宁和第一单体的混合树脂，并且其中所述多个细胞包含多个开放细胞和 根据ASTM D6226-5测量的具有开孔含量的多个闭孔小于50％。 所述泡沫组合物还包括设置在所述多个闭孔的至少一部分中的不连续相，所述不连续相包含一种或多种发泡剂。

公开(公告)号：US20140093719A1

公开(公告)日：2014-04-03

申请号：US14118916

申请日：2012-05-25

申请人： Mark Andrew Harmer ,  Vivek Kapur ,  Sharlene Renee Williams

发明人： Mark Andrew Harmer ,  Vivek Kapur ,  Sharlene Renee Williams

IPC分类号： C08J9/12 ,  C08J9/14

CPC分类号： C08J9/12 ,  B32B5/022 ,  B32B5/024 ,  B32B5/18 ,  B32B7/12 ,  B32B13/045 ,  B32B15/046 ,  B32B15/18 ,  B32B15/20 ,  B32B21/047 ,  B32B27/065 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B29/007 ,  B32B2250/40 ,  B32B2255/26 ,  B32B2266/02 ,  B32B2266/0214 ,  B32B2266/0228 ,  B32B2266/0278 ,  B32B2266/06 ,  B32B2266/08 ,  B32B2266/104 ,  B32B2266/126 ,  B32B2307/304 ,  B32B2419/00 ,  C08G65/40 ,  C08J9/141 ,  C08J9/146 ,  C08J2205/052 ,  C08J2397/00 ,  C08J2399/00 ,  C08J2459/00 ,  Y10T428/249976

摘要： Disclosed are foam compositions and processes to form closed-cell tannin-based foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a tannin-based resin derived from a tannin and a monomer, wherein the monomer comprises furfural, glyoxal, acetaldehyde, 5-hydroxymethylfurfural, acrolein, levulinate esters, sugars, 2,5-furandicarboxylic acid, 2,5-furandicarboxylic aldehyde, urea, difurfural (DFF), furfuryl alcohol, glycerol, sorbitol, lignin, or mixtures thereof, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising one or more blowing agents.

摘要翻译： 公开了形成闭孔单宁单体泡沫的泡沫组合物和方法。 所述泡沫包括限定多个细胞的连续聚合物相，其中所述连续聚合物相包含衍生自单宁和单体的单宁类树脂，其中所述单体包含糠醛，乙二醛，乙醛，5-羟甲基糠醛，丙烯醛，乙酰丙酸酯 ，糖，2,5-呋喃二羧酸，2,5-呋喃二甲醛，尿素，二呋喃（DFF），糠醇，甘油，山梨醇，木质素或其混合物，其中多个细胞包含多个开放细胞 和根据ASTM D6226-5测量的具有开孔含量的多个闭孔小于50％。 所述泡沫组合物还包括设置在所述多个闭孔的至少一部分中的不连续相，所述不连续相包含一种或多种发泡剂。

公开(公告)号：US09790342B2

公开(公告)日：2017-10-17

申请号：US14118916

申请日：2012-05-25

申请人： Mark Andrew Harmer ,  Vivek Kapur ,  Sharlene Renee Williams

发明人： Mark Andrew Harmer ,  Vivek Kapur ,  Sharlene Renee Williams

IPC分类号： B32B3/26 ,  C08J9/12 ,  B32B5/18 ,  B32B5/02 ,  B32B7/12 ,  B32B13/04 ,  B32B15/04 ,  B32B15/18 ,  B32B15/20 ,  B32B21/04 ,  B32B27/06 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B29/00 ,  C08G65/40 ,  C08J9/14

CPC分类号： C08J9/12 ,  B32B5/022 ,  B32B5/024 ,  B32B5/18 ,  B32B7/12 ,  B32B13/045 ,  B32B15/046 ,  B32B15/18 ,  B32B15/20 ,  B32B21/047 ,  B32B27/065 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B29/007 ,  B32B2250/40 ,  B32B2255/26 ,  B32B2266/02 ,  B32B2266/0214 ,  B32B2266/0228 ,  B32B2266/0278 ,  B32B2266/06 ,  B32B2266/08 ,  B32B2266/104 ,  B32B2266/126 ,  B32B2307/304 ,  B32B2419/00 ,  C08G65/40 ,  C08J9/141 ,  C08J9/146 ,  C08J2205/052 ,  C08J2397/00 ,  C08J2399/00 ,  C08J2459/00 ,  Y10T428/249976

摘要： Disclosed are foam compositions and processes to form closed-cell tannin-based foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a tannin-based resin derived from a tannin and a monomer, wherein the monomer comprises furfural, glyoxal, acetaldehyde, 5-hydroxymethylfurfural, acrolein, levulinate esters, sugars, 2,5-furandicarboxylic acid, 2,5-furandicarboxylic aldehyde, urea, difurfural (DFF), furfuryl alcohol, glycerol, sorbitol, lignin, or mixtures thereof, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising one or more blowing agents.

公开(公告)号：US20140093720A1

公开(公告)日：2014-04-03

申请号：US14118940

申请日：2012-05-25

申请人： Michael W. Cobb ,  Mark Andrew Harmer ,  Vivek Kapur ,  Ann Y. Liauw ,  Sharlene Renee Williams

发明人： Michael W. Cobb ,  Mark Andrew Harmer ,  Vivek Kapur ,  Ann Y. Liauw ,  Sharlene Renee Williams

IPC分类号： C08J9/14 ,  B32B5/18

CPC分类号： C08J9/146 ,  B29C44/02 ,  B29C44/3415 ,  B29K2061/00 ,  B29K2105/046 ,  B29K2995/0015 ,  B29K2995/0016 ,  B29L2031/10 ,  B32B5/18 ,  C08J9/0061 ,  C08J9/14 ,  C08J9/141 ,  C08J2203/162 ,  C08J2361/06 ,  C08J2361/12 ,  C08J2497/00 ,  C08J2499/00 ,  E04C2/284 ,  Y10T428/249976

摘要： Disclosed are foam compositions and processes to form mixed tannin-phenolic foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a mixed-resin derived from a phenol, a tannin, and a first monomer, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising one or more blowing agents.

摘要翻译： 公开了形成混合单宁 - 酚醛泡沫的泡沫组合物和方法。 泡沫包括限定多个细胞的连续聚合物相，其中所述连续聚合物相包含衍生自苯酚，单宁和第一单体的混合树脂，并且其中所述多个细胞包含多个开放细胞和 根据ASTM D6226-5测量的具有开孔含量的多个闭孔小于50％。 所述泡沫组合物还包括设置在所述多个闭孔的至少一部分中的不连续相，所述不连续相包含一种或多种发泡剂。

公开(公告)号：US20140079941A1

公开(公告)日：2014-03-20

申请号：US14118957

申请日：2012-05-25

申请人： Michael W. Cobb ,  Mark Andrew Harmer ,  Vivek Kapur ,  Ann Y. Liauw ,  Sharlene Renee Williams

发明人： Michael W. Cobb ,  Mark Andrew Harmer ,  Vivek Kapur ,  Ann Y. Liauw ,  Sharlene Renee Williams

IPC分类号： C08L61/06 ,  B32B5/18

CPC分类号： C08L61/06 ,  B32B5/18 ,  B32B2250/03 ,  B32B2250/40 ,  B32B2266/0285 ,  B32B2266/06 ,  B32B2266/08 ,  B32B2305/022 ,  B32B2307/304 ,  B32B2307/3065 ,  B32B2307/72 ,  C08J9/146 ,  C08J2203/162 ,  C08J2205/052 ,  C08J2361/06 ,  Y10T428/249976

摘要： Disclosed are foam compositions and processes to form closed-cell phenolic foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a phenol-formaldehyde resole derived from a phenol and formaldehyde, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising 1,1,1,4,4,4-hexafluoro-2-butene.

摘要翻译： 公开了形成闭孔酚醛泡沫的泡沫组合物和方法。 所述泡沫包括限定多个细胞的连续聚合物相，其中所述连续聚合物相包含衍生自苯酚和甲醛的苯酚 - 甲醛甲阶酚醛树脂，并且其中所述多个细胞包含多个开放细胞和多个封闭 - 具有根据ASTM D6226-5测量的开孔含量小于50％的细胞。 所述泡沫组合物还包括设置在所述多个闭孔的至少一部分中的不连续相，所述不连续相包含1,1,1,4,4,4-六氟-2-丁烯。

公开(公告)号：US20140087175A1

公开(公告)日：2014-03-27

申请号：US14118906

申请日：2012-05-25

申请人： Michael W. Cobb ,  Vincent Galante ,  Marj Andrew Harmer ,  Vivek Kapur ,  Sharlene Renee Williams

发明人： Michael W. Cobb ,  Vincent Galante ,  Marj Andrew Harmer ,  Vivek Kapur ,  Sharlene Renee Williams

IPC分类号： C08G65/40

CPC分类号： C08J9/12 ,  B32B5/022 ,  B32B5/024 ,  B32B5/18 ,  B32B7/12 ,  B32B13/045 ,  B32B15/046 ,  B32B15/18 ,  B32B15/20 ,  B32B21/047 ,  B32B27/065 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B29/007 ,  B32B2250/40 ,  B32B2255/26 ,  B32B2266/02 ,  B32B2266/0214 ,  B32B2266/0228 ,  B32B2266/0278 ,  B32B2266/06 ,  B32B2266/08 ,  B32B2266/104 ,  B32B2266/126 ,  B32B2307/304 ,  B32B2419/00 ,  C08G65/40 ,  C08J9/141 ,  C08J9/146 ,  C08J2205/052 ,  C08J2397/00 ,  C08J2399/00 ,  C08J2459/00 ,  Y10T428/249976

摘要： Disclosed are foam compositions and processes to form closed-cell tannin-based foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a tannin-based resin derived from a tannin, a first monomer, and a second monomer, wherein the first monomer comprises formaldehyde, paraformaldehyde, furfural, glyoxal, acetaldehyde, 5-hydroxymethylfurfural, acrolein, levulinate esters, sugars, 2,5-furandicarboxylic acid, 2,5-furandicarboxylic aldehyde, urea, difurfural (DFF), or mixtures thereof, and the second monomer comprises furfuryl alcohol, glycerol, sorbitol, lignin, or mixtures thereof, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising one or more blowing agents.

摘要翻译： 公开了形成闭孔单宁单体泡沫的泡沫组合物和方法。 所述泡沫包括限定多个细胞的连续聚合物相，其中所述连续聚合物相包含衍生自单宁的单宁类树脂，第一单体和第二单体，其中所述第一单体包含甲醛，多聚甲醛，糠醛，乙二醛 ，乙醛，5-羟甲基糠醛，丙烯醛，乙酰丙酸酯，糖，2,5-呋喃二羧酸，2,5-呋喃二甲醛，尿素，二氟脲（DFF）或其混合物，第二单体包括糠醇，甘油，山梨糖醇 ，木质素或其混合物，并且其中所述多个细胞包含多个开放细胞和根据ASTM D6226-5测量的具有小于50％的开放细胞含量的多个闭孔。 所述泡沫组合物还包括设置在所述多个闭孔的至少一部分中的不连续相，所述不连续相包含一种或多种发泡剂。

公开(公告)号：US20130212780A1

公开(公告)日：2013-08-22

申请号：US13882383

申请日：2011-12-05

申请人： Justin W. Chan ,  Michael W. Cobb ,  John Henry Henry McMinn ,  Sharlene Renee Williams

发明人： Justin W. Chan ,  Michael W. Cobb ,  John Henry Henry McMinn ,  Sharlene Renee Williams

IPC分类号： C08G73/08 ,  D03D15/00

CPC分类号： C08G73/08 ,  C08G2261/3228 ,  C08L79/06 ,  D03D15/00 ,  D10B2321/08 ,  Y10T442/30

摘要： A shaped article having a polymer having repeat units of Formula (I) and one or both of Formula (II) and (IIa): wherein M is a cation.

摘要翻译： 具有具有式（I）的重复单元和式（II）和（IIa）中的一种或两者的聚合物的成型制品：其中M是阳离子。

公开(公告)号：US20130210306A1

公开(公告)日：2013-08-15

申请号：US13881457

申请日：2011-12-05

申请人： Michael W. Cobb ,  Sharlene Renee Williams ,  Reiyao Zhu

发明人： Michael W. Cobb ,  Sharlene Renee Williams ,  Reiyao Zhu

IPC分类号： D02G3/44 ,  A41D31/00

CPC分类号： D02G3/443 ,  A41D31/08 ,  Y10T442/3984 ,  Y10T442/696

摘要： Described is a flame-resistant spun yarn having: about 50 to about 95 parts by weight of a sulfonated polyoxadiazole based staple fiber comprising repeat units of Formula (I) and one or both of Formula (II) and (IIa): wherein M is a cation; and about 5 to about 50 parts by weight of a textile staple fiber having limiting oxygen index of 21 or greater and a tenacity of about 4 grams per denier or greater, based on the total amount of the polymeric fiber and the textile fiber in the yarn.

摘要翻译： 描述了一种阻燃纺纱，其具有：约50至约95重量份的包含式（I）的重复单元和式（II）和（IIa）中的一个或两个的磺化聚恶二唑基短纤维：其中M为 阳离子 和约5至约50重量份的纺织短纤维，其限制氧指数为21或更大，强度为约4克/旦尼尔或更高，基于纱线中的聚合物纤维和纺织纤维的总量 。

公开(公告)号：US20130217856A1

公开(公告)日：2013-08-22

申请号：US13882520

申请日：2011-12-05

申请人： Michael W Cobb ,  Alexander Anthony Marchione ,  John Henry Mcminn ,  Sharlene Renee Williams

发明人： Michael W Cobb ,  Alexander Anthony Marchione ,  John Henry Mcminn ,  Sharlene Renee Williams

IPC分类号： C08G73/08

CPC分类号： C08G73/08 ,  C08G2261/3228 ,  C08L79/06 ,  D03D15/00 ,  D10B2321/08 ,  Y10T442/30

摘要： Described are sulfonated polyoxadiazole polymers with a high degree of sulfonation and good flammability properties. The polymer has repeat units of Formula (I) and one or both of Formula (II) and (IIa): wherein M is a cation. The polymers are useful in articles such as fibers.

摘要翻译： 描述了具有高磺化程度和良好可燃性的磺化聚恶二唑聚合物。 聚合物具有式（I）的重复单元和式（II）和（IIa）中的一个或两个：其中M是阳离子。 聚合物可用于诸如纤维的制品中。