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公开(公告)号:US20050181421A1
公开(公告)日:2005-08-18
申请号:US11084308
申请日:2005-03-18
申请人: Mark Trulson , Glenn McGall , Jacqueline Fidanza
发明人: Mark Trulson , Glenn McGall , Jacqueline Fidanza
IPC分类号: B01J19/00 , C07H21/00 , C40B40/06 , C40B50/14 , C40B60/14 , C12Q1/68 , C07H21/04 , G01N33/53
CPC分类号: B82Y30/00 , B01J19/0046 , B01J2219/00427 , B01J2219/00432 , B01J2219/00529 , B01J2219/00576 , B01J2219/00585 , B01J2219/00596 , B01J2219/00608 , B01J2219/0061 , B01J2219/00612 , B01J2219/00626 , B01J2219/00637 , B01J2219/00675 , B01J2219/00711 , B01J2219/00722 , C07H21/00 , C40B40/06 , C40B50/14 , C40B60/14 , Y02P20/55
摘要: Radiation-activated catalysts (RACs), autocatalytic reactions, and protective groups are employed to achieve a highly sensitive, high resolution, radiation directed combinatorial synthesis of pattern arrays of diverse polymers When irradiated, RACs produce catalysts that can react with enhancers, such as those involved in autocatalytic reactions The autocatalytic reactions produce at least one product that removes protecting groups from synthesis intermediates This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers
摘要翻译: 使用辐射活化催化剂(RAC),自催化反应和保护基团来实现高灵敏度,高分辨率,多种聚合物图案阵列的辐射导向组合合成。当照射时,RAC产生可与增强子反应的催化剂,例如那些 涉及自催化反应自催化反应产生至少一种从合成中间体中除去保护基的产物本发明具有广泛的应用,并且特别适用于聚合物的固相组合合成
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公开(公告)号:US06887665B2
公开(公告)日:2005-05-03
申请号:US09922426
申请日:2001-08-03
申请人: Mark Trulson , Glenn McGall , Jacqueline Fidanza
发明人: Mark Trulson , Glenn McGall , Jacqueline Fidanza
IPC分类号: B01J19/00 , C07B61/00 , C07H21/00 , C07K1/04 , C12Q1/68 , C40B40/06 , C40B50/14 , C40B60/14 , C07H21/04 , C07G1/00
CPC分类号: B82Y30/00 , B01J19/0046 , B01J2219/00427 , B01J2219/00432 , B01J2219/00529 , B01J2219/00576 , B01J2219/00585 , B01J2219/00596 , B01J2219/00608 , B01J2219/0061 , B01J2219/00612 , B01J2219/00626 , B01J2219/00637 , B01J2219/00675 , B01J2219/00711 , B01J2219/00722 , C07B2200/11 , C07H21/00 , C07K1/04 , C07K1/045 , C12Q1/6837 , C40B40/06 , C40B50/14 , C40B60/14 , Y02P20/55
摘要: Radiation-activated catalysts (RACs), autocatalytic reactions, and protective groups are employed to achieve a highly sensitive, high resolution, radiation directed combinatorial synthesis of pattern arrays of diverse polymers. When irradiated, RACs produce catalysts that can react with enhancers, such as those involved in autocatalytic reactions. The autocatalytic reactions produce at least one product that removes protecting groups from synthesis intermediates. This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers.
摘要翻译: 辐射活化的催化剂(RAC),自催化反应和保护基被用于实现高灵敏度,高分辨率的辐射定向组合合成各种聚合物的图案阵列。 当照射时,RAC产生可与增强剂反应的催化剂,例如参与自催化反应的那些。 自催化反应产生至少一种从合成中间体中除去保护基的产物。 本发明具有广泛的应用,并且对聚合物的固相组合合成特别有用。
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公开(公告)号:US08366973B2
公开(公告)日:2013-02-05
申请号:US11933357
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号: H01B1/12
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译: 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制备墨水的方法,制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB,IIIA和(任选地)VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围,其中大部分颗粒的质量包括尺寸不超过平均粒度的约40%或以下的颗粒,或 如果平均粒度小于约5纳米,高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要,并且允许在膜退火期间更均匀的熔融,更均匀的纳米颗粒的混合,并且允许形成更高质量的吸收膜。
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公开(公告)号:US08206616B2
公开(公告)日:2012-06-26
申请号:US11933285
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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公开(公告)号:US08168089B2
公开(公告)日:2012-05-01
申请号:US11933322
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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公开(公告)号:US20080135099A1
公开(公告)日:2008-06-12
申请号:US11933407
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号: H01L31/0216
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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公开(公告)号:US08038909B2
公开(公告)日:2011-10-18
申请号:US11933338
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译: 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制造墨水的方法,制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB,IIIA和(任选地)VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围,其中大部分颗粒的质量包括尺寸不超过平均粒度的约40%或以下的颗粒,或 如果平均粒度小于约5纳米,高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要,并且允许在膜退火期间更均匀的熔融,更均匀的纳米颗粒的混合,并且允许形成更高质量的吸收膜。
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公开(公告)号:US07645934B1
公开(公告)日:2010-01-12
申请号:US10427749
申请日:2003-04-29
CPC分类号: H01L31/036 , H01L31/0203 , H01L31/04 , H01L31/048 , H01L31/0481 , Y02E10/50 , Y10T428/249953
摘要: Nanostructured layers with 10 nm to 50 nm pores spaced 10-50 nm apart, a method for making such nanostructured layers, optoelectronic devices having such nanostructured layers and uses for such nanostructured layers are disclosed. The nanostructured layer can be formed using precursor sol, which generally includes one or more covalent metal complexes, one or more surfactants, a solvent, one or more optional condensation inhibitors, and (optionally) water. Evaporating the solvent from the precursor sol forms a surfactant-templated film. Covalently crosslinking the surfactant-templated film forms a nanostructured porous layer. Pore size is controlled, e.g., by appropriate solvent concentration, choice of surfactant, use of chelating agents, use of swelling agents or combinations of these.
摘要翻译: 公开了具有间隔10-50nm的10nm至50nm孔的纳米结构层,制造这种纳米结构层的方法,具有这种纳米结构层的光电子器件以及用于这种纳米结构层的纳米结构层。 纳米结构层可以使用通常包括一种或多种共价金属络合物,一种或多种表面活性剂,溶剂,一种或多种任选的缩合抑制剂和(任选的)水的前体溶胶形成。 从前体溶胶蒸发溶剂形成表面活性剂模板的膜。 共价交联表面活性剂模板的膜形成纳米结构多孔层。 例如通过适当的溶剂浓度,选择表面活性剂,使用螯合剂,使用溶胀剂或这些的组合来控制孔径。
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公开(公告)号:US20080142081A1
公开(公告)日:2008-06-19
申请号:US11933136
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号: H01L31/0216 , C09D11/00 , B05C1/08
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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公开(公告)号:US20080135812A1
公开(公告)日:2008-06-12
申请号:US11933400
申请日:2007-10-31
申请人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人: Dong Yu , Jacqueline Fidanza , Brian M. Sager
CPC分类号: H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要: An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
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