摘要:
The present invention relates to a process for preparing a low boiling monoisocyanate having a boiling point of between 70 and 320° C. at standard pressure by reacting A) a high boiling isocyanate compound having a boiling point of at least 180° C. at standard pressure and an HC content of at least 50 ppm with B) a monoamine having a primary amino group, at a maximum reaction temperature of 180° C. and a molar ratio of isocyanate groups to amino groups of at least 4:1 to form a compound containing a biuret/urea group, simultaneously thermally decomposing this compound in situ to form a monoisocyanate corresponding to monoamine B) and removing the monoisocyanate by distillation, optionally under vacuum.
摘要:
The present invention relates to substantially solvent-free binder compositions containing a) a polyisocyanate component containing heteroallophanate groups and having aromatically-bound isocyanate groups, i) an NCO content of 3 to 16%, ii) an average functionality of 1.8 to 4, iii) an allophanate group content (calculated as C2N2O3, MW: 101) of 5 to 35% and iv) a hydrocarbon chain content of 10 to 65%, wherein the hydrocarbon chains are attached to allophanate groups via oxygen and have an average of 2 to 23 carbon atoms and b) an isocyanate-reactive component. The present invention also relates to the use of these binder compositions in one- and two-component coating compositions.
摘要:
The invention relates to olefinically unsaturated polyisocyanates containing allophanate groups and having an NCO content of 6 to 20% by weight, an iodine value of 15 to 150, a content of hydrocarbon chains containing 12 to 30 carbon atoms of 100 to 700 mg/g and a content of allophanate groups of 10 to 300 mg/g, to a process for their production by reaction of a polyisocyanate component containing urethane groups with excess polyisocyanates, and to a one-component coating composition containing these olefinically unsaturated polyisocyanates as binders.
摘要:
The present invention relates to a process for preparing polyisocyanates containing allophanate groups by reacting compounds a), which i) contain urethane groups, but which are substantially free of hydroxyl groups and isocyanate groups, ii) have an average of at least two urethane groups per molecule, iii) are prepared by reacting organic isocyanates a1) with organic hydroxyl compounds a2) and iv) have an average molecular weight of at most 2,500, with excess quantities, based on the urethane groups, of distillable organic polyisocyanates b) to form polyisocyanates containing allophanate groups and subsequently removing by distillation the unreacted excess of component b) to a residual content of less than 0.5 wt. %, provided that polyisocyanates a1) and polyisocyanates b) are different. The present invention also relates to the products obtained from this process and to their use as binders or binder components in coating compositions.
摘要:
Water-dispersible polyisocyanate compositions based on aliphatic and aromatic diisocyanates and having an NCO content, based on solids, of 6 to 21% by weight, a weight ratio of incorporated TDI units to incorporated HDI units of 6:1 to 0.1:1 and a content of ethylene oxide units, arranged within terminal polyether chains, of 5 to 40% by weight; a method for the preparation of these polyisocyanate compositions by reacting a polyisocyanate component with monovalent polyether alcohols containing ethylene oxide units at an NCO/OH equivalent ratio of 2:1 to 120:1; and aqueous coating compositions containing these polyisocyanate compositions and polyhydroxyl compounds as the binder.
摘要:
The present invention relates to olefinically unsaturated, urethane group-containing isocyanates which are prepared by reacting at an NCO/OH equivalent ratio of 4 to 40a) an isocyanate component substantially containing urethane group-free cycloaliphatic diisocyanates withb) an unsaturated alcohol component substantially containing monohydric olefinically unsaturated alcoholsand subsequently removing distillable unreacted isocyanates by distillation. The present invention also relates to a process for the preparation of these isocyanates and to their use as a binder component in one-component, coating compositions which may be cured at room temperature.
摘要:
A process for the production of olefinically unsaturated isocyanates by reacting a1) isophorone diisocyanate or mixtures of isophorone diisocyanate with a2) other organic polyisocyanates with b1.1) olefinically unsaturated carboxylic acids or mixtures thereof with b1.2) other monobasic or polybasic carboxylic acids, b2.1) olefinically unsaturated alcohols and/or b2.2) other monohydric or polyhydric alcohols, the unsaturated resulting isocyanates and their use as binders for one-component coating compositions which may be cured at room temperature.
摘要:
A process for the production of polyisocyanates containing isocyanurate groups by the catalytic trimerization of a mixture of low molecular weight isocyanate components having aliphatically and aromatically bound isocyanate groups in the presence of aminosilyl compounds, the resulting polyisocyanates and their use in coating compositions.
摘要:
A water-dispersible polyisocyanate composition obtained by the partial urethanization of the isocyanate groups of 2,4- and/or 2,6-diisocyanatotoluene with monohydric and polyhydric alcohols, a process for its production, its use as the binder for an aqueous two-component coating composition in combination with a water-soluble or water-dispersible polyhydroxyl component and coatings for water-resistant sheet-form substrates prepared from this coating composition.
摘要:
A process for preparing liquid lacquer polyisocyanates with aliphatically and aromatically bound isocyanate groups and an NCO content of 5 to 25 wt. % by trimerizing an isocyanate component A), containing A1) 70 to 100 wt. % of diisocyanatotoluene and A2) 0 to 30 wt. % of other aromatic isocyanates and B) aliphatic lacquer polyisocyanates, optionally with prior, simultaneous and/or subsequent reaction of a portion of the isocyanate groups with an alcohol component C) having a molecular weight of 32 to 900, and optionally in the presence of D) inert solvents; the resulting lacquer polyisocyanates; and their use in coating compositions, in particular as a cross-linking agent for polyhydroxyl compounds in two-component polyurethane coating compositions.