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    Process for the coloration of aluminium
    2.
    发明申请
    Process for the coloration of aluminium 审中-公开

    公开(公告)号：US20050155162A1

    公开(公告)日：2005-07-21

    申请号：US10503152

    申请日：2003-01-28

    申请人： Hans-Thomas Schacht ,  Gibert Moegle ,  Didier Bauer ,  Leonhard Feiler ,  Olof Wallquist ,  Martin Muller

    发明人： Hans-Thomas Schacht ,  Gibert Moegle ,  Didier Bauer ,  Leonhard Feiler ,  Olof Wallquist ,  Martin Muller

    IPC分类号： C09B1/34 ,  C09B5/48 ,  C09B29/42 ,  C09B29/50 ,  C09B31/14 ,  C09B31/143 ,  C09B47/24 ,  C09B48/00 ,  C09B57/00 ,  C09B67/02 ,  C09B67/20 ,  C09C1/64 ,  C25D11/18 ,  C25D11/24 ,  C09C1/62 ,  C08K5/00 ,  D06P5/00

    CPC分类号： C25D11/243 ,  C01P2004/20 ,  C01P2004/51 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2004/80 ,  C01P2006/60 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C09C1/642 ,  C09C1/644 ,  C25D11/246

    摘要： The present invention relates to a proces for producing colored oxide layers on aluminum or on aluminum alloys by dyeing in an aqueous dye bath, rinsing with water and sealing, wherein there is used for the dyeing at least one dye of the general formula wherein m is a value from 1 to 8, especially from 1 to 4, n is a value from 0 to 7, especially from 1 to 4, the sum of m and n being less than or equal to 8, A is the radical of a chromophore of the 1-aminoanthraquinone, anthraquinone, anthrapyrimidine, azo, azomethine, benzodifuranone, quinacridone, quinacridonequinone, quinophthalone, diketopyrrolopyrrole, dioxazine, flavanthrone, indanthrone, indigo, isoindoline, isoindolinone, isoviolanthrone, perinone, perylene, phthalocyanine, pyranthrone or thioindigo series, B is a hydrogen atom, a branched or straight-chain C1-8alkyl, C2-8alkenyl or C2-8alkynyl radical, an aryl radical, an N—, O— or S-containing 5- or 6-membered heterocyclic ring, or a C1-8alkyl-arylene, aryl-C1-8alkylene or aryl-L-arylene radical, each of which may be substituted by one or more groups —OH, —Ocat, —COOH, —COOcat, —SH, —Scat, —OR1, —SR2, —C(O)OR3, —C(O)R4, —NR5R6, it being possible for the C1-8alkyl radical to be uninterrupted or interrupted one or more times by —O— or by —S—, R1, R2, R3 and R4 are each independently of the others a C1-8alkyl radical, C7-11aralkyl radical or C6-10aryl radical and R4 additionally may be a hydrogen atom, L is a bond, is —NR7 wherein R7 is a hydrogen atom or a C1-4alkyl radical, or is a —N═N— group, and R5 and R6 are each independently of the other a hydrogen atom, a C1-8-alkyl radical, a C1-4alkoxy-C1-4alkyl radical, a C6-10aryl radical, a C7-11aralkyl radical or a —(CH2)oOH radical wherein o is an integer from 2 to 6, X1 is a hydrogen atom or cat and X2 is a hydrogen atom or cat, cat being a cation, and to the colored substrates obtained according to such a process. Compared with commercially available dyes and dyes of formula I in which cat+ is an alkali metal, the dyeings obtainable according to the process of the invention have surprisingly high light-fastness properties.

    Functionalized nanoparticles
    6.
    发明申请
    Functionalized nanoparticles 审中-公开
    官能化纳米粒子

    公开(公告)号：US20090099282A1

    公开(公告)日：2009-04-16

    申请号：US11920295

    申请日：2006-05-17

    申请人： Martin Muller ,  Andreas Muhlebach ,  Thomas Giesenberg ,  Didier Bauer ,  Thomas Ruch ,  Francois Rime ,  Leonhard Feiler ,  Roman Lenz ,  Laurent Michau

    发明人： Martin Muller ,  Andreas Muhlebach ,  Thomas Giesenberg ,  Didier Bauer ,  Thomas Ruch ,  Francois Rime ,  Leonhard Feiler ,  Roman Lenz ,  Laurent Michau

    IPC分类号： C08K5/5419 ,  C04B16/00 ,  C08K5/00

    CPC分类号： C09B69/103 ,  C09B67/0097 ,  C09B68/20 ,  C09B68/443 ,  C09B69/10

    摘要： The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of formula (1), wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, R1 and R2 are independently of each other hydrogen, nanoparticle surface-O—, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, and Y is a radical of formula —B1-D1 (2a), wherein B1 is the direct bond or a bridge member, and D1 is a radical of a cationic dye, a radical of a phthalocyanine dye which carries no water-solubilizing group, or a radical of a fluorescent dye selected from the group consisting of coumarins, benzocoumarins, xanthenes, benzo[a]xanthenes, benzo[b]xanthenes, benzo[c]xanthenes, phenoxazines, benzo[a]phenoxazines, benzo[b]phenoxazines, benzo[c]phenoxazines, napthalimides, naphtholactams, azlactones, methines, oxazines, thiazines, diketopyrrolopyrroles, quinacridones, benzoxanthenes, thio-epindolines, lactamimides, diphenylmaleimides, acetoacetamides, imidazothiazines, benzanthrones, phthalimides, benzotriazoles, pyrimidines, pyrazines and triazines, or Y is a radical of formula —B2D2 (2b), wherein B2 is an organic radical comprising at least one group having a negative charge, and D2 is a cationic dye selected from the group consisting of monoazo, disazo, polyazo, methine, azamethine, diphenylmethane, triphenylmethane, triaminotriaryl methane, azine, oxazine, cyanine and anthraquinone dyes.

    摘要翻译： 本发明公开了在表面上包含式（1）的共价结合基团的官能化纳米颗粒，其中纳米颗粒是SiO 2，Al 2 O 3或混合的SiO 2和Al 2 O 3纳米颗粒，R 1和R 2彼此独立地是氢，纳米颗粒表面-O-， 或取代基，n为1,2,3,4,5,6,7或8，并且Y为式-B1-D1（2a）的基团，其中B1为直接键或桥式构件，D1为 是阳离子染料的自由基，不含水溶性基团的酞菁染料的基团，或选自香豆素，苯并香豆素，呫吨，苯并[a]呫吨，苯并[b 苯并[c]呫吨酮，苯并[c]呫吨酮，吩恶嗪，苯并[a]吩恶嗪，苯并[b]吩恶嗪，苯并[c]吩恶嗪，萘酰亚胺，萘并内酰胺，吖内酯，次甲基，恶嗪，噻嗪，二酮吡咯并吡咯，喹吖啶酮，苯并恶庚烯，硫代 - ，内酰胺，二苯基马来酰亚胺，乙酰乙酰胺，咪唑硫基 吖嗪，苯并呋喃，邻苯二甲酰亚胺，苯并三唑，嘧啶，吡嗪和三嗪，或Y是式-B2D2（2b）的基团，其中B2是包含至少一个具有负电荷的基团的有机基团，并且D2是选择的阳离子染料 来自由单偶氮，双偶氮，多偶氮，次甲基，氮杂酮，二苯基甲烷，三苯甲烷，三氨基三芳基甲烷，吖嗪，恶嗪，花青和蒽醌染料组成的组。

    Inorganic Bismuth-Containing Pigments
    7.
    发明申请
    Inorganic Bismuth-Containing Pigments 审中-公开
    无机含铋颜料

    公开(公告)号：US20080092778A1

    公开(公告)日：2008-04-24

    申请号：US11665628

    申请日：2005-10-19

    申请人： Didier Bauer ,  Philippe Bugnon ,  Robertus Hermans ,  Rene Kubben ,  Johannes Luijten ,  Martin Muller ,  Gregor Schmitt

    发明人： Didier Bauer ,  Philippe Bugnon ,  Robertus Hermans ,  Rene Kubben ,  Johannes Luijten ,  Martin Muller ,  Gregor Schmitt

    IPC分类号： C09C1/00 ,  C01G29/00

    CPC分类号： C09C1/00 ,  C01P2002/50 ,  C01P2006/62 ,  C01P2006/65 ,  C01P2006/66 ,  C09D5/36 ,  C09D11/037

    摘要： The invention relates to a coloured pigment of the general formula BiOIaBrbClcMdAe; wherein M is a cation of the alkaline-earth metals, a cation of the earth metals, a cation of the rare earth metals including the lanthanides or a cation of the metals Ge, Sn, Pb, Sb, Ti, Zr, Hf, Mn, Re, Fe, Ru, Os or Zn or a mixture of cations of those metals; A is a fluoride, aquoxide, hydroxide, carbonate, silicate, molybdate, tungstate, sulfate, borate or phosphate anion or a mixture of those anions; a is a number from 0.10 to 0.999; preferably from 0.50 to 0.90; b, c, d and e are numbers from 0 to 0.90; preferably from 0.10 to 0.50; a+b+c+d+e=1 and a+b+c

    摘要翻译： 本发明涉及以下通式的有色颜料：其中R 1，R 2，R 3， > e 其中M是碱土金属的阳离子，地球金属的阳离子，包括镧系元素的稀土金属的阳离子或金属Ge，Sn，Pb，Sb，Ti，Zr，Hf，Mn的阳离子 ，Re，Fe，Ru，Os或Zn或这些金属的阳离子的混合物; A是氟化物，氧化物，氢氧化物，碳酸盐，硅酸盐，钼酸盐，钨酸盐，硫酸盐，硼酸盐或磷酸盐阴离子或这些阴离子的混合物; a是从0.10到0.999的数字; 优选为0.50〜0.90; b，c，d和e是从0到0.90的数字; 优选为0.10〜0.50; a + b + c + d + e = 1，a + b + c <1; 涉及其制备方法及其在着色高分子量有机材料如表面涂料组合物，塑料和印刷油墨中的用途。

    PHOTO-LATENT TITANIUM CATALYSTS
    8.
    发明申请
    PHOTO-LATENT TITANIUM CATALYSTS 审中-公开
    钛酸钡催化剂

    公开(公告)号：US20120220685A1

    公开(公告)日：2012-08-30

    申请号：US13395467

    申请日：2010-09-09

    申请人： Tobias Hintermann ,  Didier Bauer ,  Antoine Carroy ,  Caroline Lordelot ,  Rachel Kohli Steck

    发明人： Tobias Hintermann ,  Didier Bauer ,  Antoine Carroy ,  Caroline Lordelot ,  Rachel Kohli Steck

    IPC分类号： C08G18/32 ,  C09D11/10 ,  C09D175/04 ,  C08F4/76 ,  C09J175/04

    CPC分类号： B01J31/2234 ,  B01J31/0208 ,  B01J31/2213 ,  B01J31/2226 ,  B01J2231/34 ,  B01J2531/46 ,  C08G18/222 ,  C08G18/6216 ,  C08G18/792 ,  C09D175/04

    摘要： The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R1 is C1-C20alkyl or C2-C20alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y1 is formula (III) or optionally substituted phenyl; Y2 is formula (IV) or optionally substituted phenyl; Y3 is formula (V) or optionally substituted phenyl; R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are hydrogen, halogen, optionally substituted C1-C20alkyl, or R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are optionally substituted C6-C14aryl, provided that only one of R2, R3, R4 is hydrogen and only one of R5, R6, R7 is hydrogen and only one of R8, R9, R10 is hydrogen and only one of R11, R12, R13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y′ is formula (VI) or formula (VII); Y′1 is formula (VIII) or formula (IX); R′2, R′3, R′4, R′5, R′6 and R′7 independently of each other have on of the meanings as given for R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13; and R′14, R′15 and R′16 independently of each other have on of the meanings as given for R14, R15 and R16.

    摘要翻译： 本发明提供了一种光催化剂钛螯合催化剂制剂，其包含（i）至少一种式（I）化合物，其中R 1是被一个或多个非连续O原子间隔的C 1 -C 20烷基或C 2 -C 20烷基; Y是式（II）或任选取代的苯基; Y1是式（III）或任选取代的苯基; Y2是式（IV）或任选取代的苯基; Y 3是式（V）或任选取代的苯基; R2，R3，R4，R5，R6，R7，R8，R9，R10，R11，R12和R13彼此独立地是氢，卤素，任选取代的C 1 -C 20烷基，或者R 2，R 3，R 4，R 5，R 6，R 7 R 8，R 9，R 10，R 11，R 12和R 13彼此独立地是任选取代的C 6 -C 14芳基，条件是R 2，R 3，R 4中只有一个是氢，并且R 5，R 6，R 7中只有一个是氢， R8，R9，R10是氢，R11，R12，R13中只有一个是氢; 和（ii）式IIa，IIb或IIc的至少一种螯合配体化合物，其中Y'为式（VI）或式（VII）; Y'1是式（VIII）或式（IX）; R'2，R'3，R'4，R'5，R'6和R'7彼此独立地具有对R2，R3，R4，R5，R6，R7，R8，R9给出的含义 ，R10，R11，R12和R13; 并且R 14，R'15和R 16彼此独立地具有对R 14，R 15和R 16给出的含义。

    Photo-latent titanium catalysts
    10.
    发明授权
    Photo-latent titanium catalysts 有权

    公开(公告)号：US10207261B2

    公开(公告)日：2019-02-19

    申请号：US13395467

    申请日：2010-09-09

    申请人： Tobias Hintermann ,  Didier Bauer ,  Antoine Carroy ,  Caroline Lordelot ,  Rachel Kohli Steck

    发明人： Tobias Hintermann ,  Didier Bauer ,  Antoine Carroy ,  Caroline Lordelot ,  Rachel Kohli Steck

    IPC分类号： B01J31/22 ,  B01J31/02 ,  C09D175/04 ,  C08G18/79 ,  C08G18/62 ,  C08G18/22

    摘要： The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R1 is C1-C20alkyl or C2-C20alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y1 is formula (III) or optionally substituted phenyl; Y2 is formula (IV) or optionally substituted phenyl; Y3 is formula (V) or optionally substituted phenyl; R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are hydrogen, halogen, optionally substituted C1-C20alkyl, or R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are optionally substituted C6-C14aryl, provided that only one of R2, R3, R4 is hydrogen and only one of R5, R6, R7 is hydrogen and only one of R8, R9, R10 is hydrogen and only one of R11, R12, R13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y′ is formula (VI) or formula (VII); Y′1 is formula (VIII) or formula (IX); R′2, R′3, R′4, R′5, R′6 and R′7 independently of each other have on of the meanings as given for R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13; and R′14, R′15 and R′16 independently of each other have on of the meanings as given for R14, R15 and R16.