公开(公告)号：US09365704B2

公开(公告)日：2016-06-14

申请号：US13984753

申请日：2012-02-09

申请人： Masahiro Shibata ,  Koji Okada

发明人： Masahiro Shibata ,  Koji Okada

IPC分类号： C08L9/00 ,  C08L15/00 ,  B60C1/00 ,  C08K3/36

CPC分类号： C08L9/00 ,  B60C1/0016 ,  C08K3/36 ,  C08K5/0091 ,  C08L15/00 ,  Y02T10/862

摘要： A method for producing a rubber composition includes kneading: a rubber component comprising a conjugated diene polymer having at least one functional group selected from the group consisting of a thiol group, an oxetane group and a hydrocarbylthio group; silica particles; and a catalyst for condensing silanol to form an aggregate of the silica particles. Preferably, at least one polymer selected from the group consisting of a conjugate diene polymer having no functional group bondable to silica, and a polymer having no functional group bondable to silica and the polymer being other than conjugated diene polymer is also kneaded as a rubber component other than the conjugated diene polymer.

摘要翻译： 橡胶组合物的制造方法包括捏合：包含具有至少一个选自硫醇基，氧杂环丁烷基和烃基硫基的官能团的共轭二烯聚合物的橡胶组分; 二氧化硅颗粒; 和用于缩合硅烷醇以形成二氧化硅颗粒的聚集体的催化剂。 优选将至少一种选自不与二氧化硅结合的官能团的共轭二烯聚合物和不与二氧化硅键合的官能团的聚合物和除了共轭二烯聚合物以外的聚合物的聚合物混合，作为橡胶组分 除了共轭二烯聚合物之外。

公开(公告)号：US20130345335A1

公开(公告)日：2013-12-26

申请号：US13984749

申请日：2012-02-09

申请人： Masahiro Shibata ,  Koji Okada

发明人： Masahiro Shibata ,  Koji Okada

IPC分类号： C08L25/10 ,  C08K5/098

CPC分类号： C08L25/10 ,  B60C1/0016 ,  C08J3/20 ,  C08J2309/00 ,  C08K3/36 ,  C08K5/0091 ,  C08K5/098 ,  C08L9/00 ,  C08L15/00 ,  Y02T10/862

摘要： A rubber composition that can obtain a rubber elastic body having small rolling resistance and excellent impact resilience and a method for producing the same, and a tire having small rolling resistance and excellent impact resilience are provided. The rubber composition of the present invention is obtained by kneading a conjugated diene polymer having a functional group bondable to silica, an acylate compound containing metal and silica. In the present invention, a polymer having no functional group bondable to silica is preferably kneaded as a rubber component other than the conjugated diene polymer, together with the conjugated diene polymer having a functional group bondable to silica, the acylate compound containing metal and the silica.

摘要翻译： 提供一种橡胶组合物，其可以获得具有低滚动阻力和优异的冲击弹性的橡胶弹性体及其制造方法，并且提供具有小滚动阻力和优异的冲击弹性的轮胎。 本发明的橡胶组合物是通过捏合具有可与二氧化硅键合的官能团的共轭二烯聚合物，含有金属的酰化物化合物和二氧化硅得到的。 在本发明中，优选将不具有与二氧化硅结合的官能团的聚合物作为除共轭二烯系聚合物以外的橡胶成分与具有可与二氧化硅结合的官能团的共轭二烯聚合物，含有酰化物化合物的金属和二氧化硅 。

公开(公告)号：US20130324659A1

公开(公告)日：2013-12-05

申请号：US13984753

申请日：2012-02-09

申请人： Masahiro Shibata ,  Koji Okada

发明人： Masahiro Shibata ,  Koji Okada

IPC分类号： C08L9/00

CPC分类号： C08L9/00 ,  B60C1/0016 ,  C08K3/36 ,  C08K5/0091 ,  C08L15/00 ,  Y02T10/862

摘要： A rubber composition which can obtain a rubber elastic body having small rolling resistance and excellent impact resilience and a method for producing the same, and a tire having small rolling resistance and excellent impact resilience are provided.The rubber composition of the present invention is obtained by kneading a rubber component comprising a conjugated diene polymer having at least one functional group selected from the group consisting of a tertiary amino group, a thiol group, an epoxy group, a thioepoxy group, an oxetane group and a hydrocarbylthio group, a catalyst for condensing silanol, and silica.

摘要翻译： 提供一种橡胶组合物，其能够获得具有低滚动阻力和优异的冲击弹性的橡胶弹性体及其制造方法，并且提供具有小滚动阻力和优异冲击弹性的轮胎。 本发明的橡胶组合物是将包含具有至少一个选自叔氨基，硫醇基，环氧基，硫代环氧基，氧杂环丁烷中的至少一个官能团的共轭二烯聚合物的橡胶组分 基团和烃基硫基，用于缩合硅烷醇的催化剂和二氧化硅。

公开(公告)号：US09206264B2

公开(公告)日：2015-12-08

申请号：US13347115

申请日：2012-01-10

申请人： Masahiro Shibata ,  Takaomi Matsumoto ,  Tamotsu Nagaoka ,  Takuo Sone ,  Toshihiro Tadaki

发明人： Masahiro Shibata ,  Takaomi Matsumoto ,  Tamotsu Nagaoka ,  Takuo Sone ,  Toshihiro Tadaki

IPC分类号： C08C19/44 ,  C08C19/12 ,  C08L15/00 ,  C08L21/00 ,  C08K3/00 ,  C08K3/04 ,  C08K3/34 ,  C08K3/36 ,  C08K5/548 ,  C08L7/00 ,  C08L9/00 ,  C08L9/02 ,  C08L9/06

CPC分类号： C08C19/12 ,  C08C19/44 ,  C08K3/013 ,  C08K3/04 ,  C08K3/34 ,  C08K3/36 ,  C08K5/548 ,  C08L7/00 ,  C08L9/00 ,  C08L9/02 ,  C08L9/06 ,  C08L15/00 ,  C08L21/00 ,  C08L2666/08 ,  C08K3/0033

摘要： The method for producing a modified conjugated diene based (co)polymer, according to the present invention comprises a step of reacting a conjugated diene based (co)polymer with a metal halide compound to obtain a modified conjugated diene based (co)polymer, the conjugated diene based (co)polymer having a weight-average molecular weight of 150,000 to 2,000,000 and being obtained by bonding, to a polymer having at least a conjugated diene unit, an alkoxysilyl group and an optionally protected primary amino group. The method can satisfactorily produce a conjugated diene based (co)polymer which has a high Mooney viscosity, excellent shape stability and good processability.

摘要翻译： 根据本发明的改性共轭二烯系（共）聚合物的制造方法包括使共轭二烯系（共）聚合物与金属卤化物反应，得到改性共轭二烯系（共）聚合物的工序， 通过与具有至少共轭二烯单元的聚合物，烷氧基甲硅烷基和任意保护的伯氨基键合获得的共轭二烯系（共）聚合物，其重均分子量为15万〜200万。 该方法可以令人满意地生产具有高门尼粘度，优异形状稳定性和良好加工性能的共轭二烯基（共）聚合物。

公开(公告)号：USD687078S1

公开(公告)日：2013-07-30

申请号：US29409503

申请日：2011-12-23

申请人： Masahiro Shibata ,  Kazuki Yamamichi

设计人： Masahiro Shibata ,  Kazuki Yamamichi

公开(公告)号：US20130085228A1

公开(公告)日：2013-04-04

申请号：US13702809

申请日：2011-05-24

申请人： Ryouji Tanaka ,  Masahiro Shibata ,  Takaomi Matsumoto ,  Kenji Hasegawa ,  Toshihiro Tadaki

发明人： Ryouji Tanaka ,  Masahiro Shibata ,  Takaomi Matsumoto ,  Kenji Hasegawa ,  Toshihiro Tadaki

IPC分类号： C08L9/06

CPC分类号： C08L9/06 ,  B60C1/00 ,  C08C19/22 ,  C08C19/24 ,  C08C19/25 ,  C08C19/44 ,  C08K3/04 ,  C08K3/36 ,  C08K5/0091 ,  C08K5/057 ,  C08K5/5415 ,  C08K5/544 ,  C08K5/548 ,  C08L9/00

摘要： By a method comprising a process including (a) producing a modified conjugated diene polymer through reaction of a conjugated diene polymer having an alkali metal or alkaline-earth metal active terminal with a first alkoxysilane compound which has both an alkoxysilyl group and at least one group convertible into an onium, and (b) mixing the modified conjugated diene polymer, an agent for producing onium, a second alkoxysilane compound having an alkoxysilyl group and at least one group convertible into an onium and a condensation catalyst containing metal element(s) for alkoxysilane compounds, conjugated diene rubber usable as a starting material of cross-linked rubber which is used for a tire tread or the like and allows enhancement of low fuel consumption property can be obtained.

摘要翻译： 通过包括以下方法的方法，所述方法包括：（a）通过具有碱金属或碱土金属活性末端的共轭二烯聚合物与具有烷氧基甲硅烷基和至少一个基团的第一烷氧基硅烷化合物的反应制备改性共轭二烯聚合物 可转化成鎓，和（b）将改性共轭二烯聚合物，用于制备鎓的试剂，具有烷氧基甲硅烷基的第二烷氧基硅烷化合物和至少一个可转化为鎓的基团和含有金属元素的缩合催化剂混合， 烷氧基硅烷化合物，可用作轮胎胎面等的交联橡胶的起始原料的共轭二烯橡胶，并且可以获得提高低燃料消耗性能。

公开(公告)号：US20110013027A1

公开(公告)日：2011-01-20

申请号：US12813913

申请日：2010-06-11

申请人： Masahiro Shibata ,  Kenichi Miyasako

发明人： Masahiro Shibata ,  Kenichi Miyasako

IPC分类号： H04N5/228 ,  G03B17/00

CPC分类号： G03B17/00 ,  H04N5/23248

摘要： There is provided a shake correction apparatus having an image pickup optical system that includes a correction lens capable of moving in a direction orthogonal to an optical axis. The shake correction apparatus comprises: a detection unit that detects shake applied to the shake correction apparatus; a determination unit that determines a reference position of the correction lens; and a drive unit that drives the correction lens with the reference position serving as a center position, so as to correct the shake detected by the detection unit. The determination unit determines the reference position, in a range where a condition that a Modulation Transfer Function (MTF) of the image pickup optical system when the correction lens is positioned at the determined reference position is equal to or larger than a threshold is satisfied.

摘要翻译： 提供一种具有摄像光学系统的抖动校正装置，该摄像光学系统包括能够在与光轴正交的方向上移动的校正透镜。 抖动校正装置包括：检测单元，其检测施加到抖动校正装置的抖动; 确定单元，确定校正透镜的基准位置; 以及驱动单元，其以参考位置驱动所述校正透镜作为中心位置，以便校正由所述检测单元检测到的抖动。 确定单元确定在校正透镜位于所确定的基准位置处的摄像光学系统的调制传递函数（MTF）等于或大于阈值的条件的范围内的基准位置。

公开(公告)号：US20100303486A1

公开(公告)日：2010-12-02

申请号：US12791412

申请日：2010-06-01

申请人： Masahiro Shibata ,  Masahiro Yoshida ,  Kazunori Hashimoto ,  Kazuhiro Okubo ,  Hisashi Yamauchi

发明人： Masahiro Shibata ,  Masahiro Yoshida ,  Kazunori Hashimoto ,  Kazuhiro Okubo ,  Hisashi Yamauchi

IPC分类号： G03G15/08 ,  G03G15/00

CPC分类号： G03G15/065 ,  G03G15/0808

摘要： An image forming apparatus includes a toner carrying member for supplying toner to the image bearing member to visualize the latent image; a rotatable toner supply member, contacted to the toner carrying member, for supplying the toner to the toner carrying member, the toner supply member including a surface foam layer; a voltage applying device for applying voltages to the toner carrying member and the toner supply member; a controller for controlling the voltage application apparatus such that A and B have a polarity which is the same as a regular charging polarity of the toner, where A=Vs2−Vd2; B=(Vs2−Vd2)−(Vs1−Vd1); Vd1 is a voltage applied to the toner carrying member during a period in which the latent image is visualized; Vs1 is a voltage applied to the toner supplying member during the period; vd2 is a voltage applied to the toner carrying member during at least a part of a period which is after the visualization of the latent image and before stoppage of rotation of the toner supplying member; and Vs2 is a voltage applied to the toner supplying member during the at least the part of the period.

摘要翻译： 图像形成装置包括用于向图像承载部件供应调色剂以使潜像可视化的调色剂承载部件; 与所述调色剂承载构件接触的用于将调色剂供给到所述调色剂承载构件的可旋转调色剂供给构件，所述调色剂供给构件包括表面泡沫层; 电压施加装置，用于向调色剂承载构件和调色剂供应构件施加电压; 用于控制电压施加装置的控制器，使得A和B具有与调色剂的常规充电极性相同的极性，其中A = Vs2-Vd2; B =（Vs2-Vd2） - （Vs1-Vd1）; Vd1是在潜像可视化的期间中施加到调色剂承载构件的电压; Vs1是在该期间施加到调色剂供给构件的电压; vd2是在潜像的可视化之后和在调色剂供给构件的停止转动之前的期间的至少一部分期间施加到调色剂承载构件的电压; Vs2是在该周期的至少一部分期间施加到调色剂供给部件的电压。

公开(公告)号：US20100119902A1

公开(公告)日：2010-05-13

申请号：US12279884

申请日：2007-06-22

申请人： Hideki Uematsu ,  Masahiro Shibata ,  Hiroshi Sumi ,  Hiroya Ishikawa

发明人： Hideki Uematsu ,  Masahiro Shibata ,  Hiroshi Sumi ,  Hiroya Ishikawa

IPC分类号： H01M8/12 ,  H01M8/10 ,  H01M8/24

CPC分类号： H01M8/04089 ,  H01M8/0273 ,  H01M8/04014 ,  H01M8/04201 ,  H01M8/1246 ,  H01M8/242 ,  H01M8/2425 ,  H01M8/2457 ,  H01M8/248 ,  H01M8/2483 ,  H01M2008/1293 ,  Y02E60/525 ,  Y02P70/56

摘要： A solid state electrolyte fuel cell stack includes: layered solid state electrolyte fuel cells, each formed by a solid state electrolyte body having a fuel pole in contact with a fuel gas and an air pole in contact with an oxidant gas; and inter-connectors arranged between the solid state electrolyte fuel cells so as to separate a gas flow path between the solid state electrolyte fuel cells and assure electric conduction between the solid state electrolyte fuel cells. The solid state electrolyte fuel cell stack has two or more air vents for supplying a fuel gas or two or more air vents for supplying the oxidant gas which vents penetrate a part or the whole of the fuel cell stack in the stack layering direction. The different air vents communicate with the different solid state electrolyte fuel cells.

摘要翻译： 固态电解质燃料电池堆包括：分层的固体电解质燃料电池，分别由具有与燃料气体接触的燃料极和与氧化剂气体接触的空气极的固体电解质体形成; 以及布置在固体电解质燃料电池之间的连接器，以分离固态电解质燃料电池之间的气体流路，并确保固态电解质燃料电池之间的导电。 固体电解质燃料电池堆具有用于供给燃料气体的两个或更多个通风口或用于供应氧化剂气体的两个或更多个通气口，该排气口以堆叠层叠方向穿透部分或全部燃料电池堆叠。 不同的通风口与不同的固体电解质燃料电池连通。

公开(公告)号：US07427651B2

公开(公告)日：2008-09-23

申请号：US11573308

申请日：2005-07-21

申请人： Masahiro Shibata ,  Naokazu Kobayashi ,  Toshihiro Tadaki

发明人： Masahiro Shibata ,  Naokazu Kobayashi ,  Toshihiro Tadaki

IPC分类号： C08C19/00 ,  C08C19/25 ,  C08C19/26 ,  C08F236/10

CPC分类号： C08L15/00 ,  C08C19/44 ,  C08F236/10 ,  C08F4/48

摘要： A process for producing a conjugated diene copolymer rubber which comprises initiating a copolymerization reaction in a reaction system containing a first conjugated diene compound and a first aromatic vinyl compound and completing the reaction, adding a first polyfunctional monomer to the reaction system, optionally further adding a second conjugated diene compound and a second aromatic vinyl compound, and further conducting copolymerization reaction, and adding a modifier to the reaction system to react the modifier with the copolymer. A rubber composition having excellent processability, exhibiting sufficient hardness even after vulcanization, and possessing reduced rolling resistance can be obtained.

摘要翻译： 一种共轭二烯共聚物橡胶的制造方法，其包括在含有第一共轭二烯化合物和第一芳族乙烯基化合物的反应体系中引发共聚反应，并完成反应，向反应体系中加入第一多官能单体，任选地， 第二共轭二烯化合物和第二芳族乙烯基化合物，进一步进行共聚反应，并在该反应体系中加入改性剂以使改性剂与共聚物反应。 可以获得具有优异的加工性，即使在硫化后显示出足够的硬度并且具有降低的滚动阻力的橡胶组合物。