公开(公告)号：US09238703B2

公开(公告)日：2016-01-19

申请号：US12527588

申请日：2008-12-02

申请人： Masato Saito ,  Yukio Kishi ,  Masuo Koyama

发明人： Masato Saito ,  Yukio Kishi ,  Masuo Koyama

IPC分类号： C08F290/06 ,  C08K5/10 ,  C08K5/06 ,  C08G18/38 ,  G02B1/10 ,  C09D4/00

CPC分类号： C08F290/06 ,  C08G18/3853 ,  C08K5/06 ,  C08K5/10 ,  C09D4/00 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/264 ,  Y10T428/265

摘要： A hard coat layer on which adhered fingerprints are inconspicuous is provided. The hard coat layer 1 consists of a cured product. The cured product is formed by curing a curable composition by irradiating it with an ultraviolet ray. The curable composition contains a curable resin. The curable resin contains reactive monomers. The reactive monomers contain an isocyanuric acid derivative. The isocyanuric acid derivative is preferably tri(meth)acrylate of an ethylene oxide and ε-caprolactone adduct of isocyanuric acid.

摘要翻译： 提供粘附指纹不显眼的硬涂层。 硬涂层1由固化产物组成。 固化产物通过用紫外线照射固化可固化组合物而形成。 可固化组合物含有可固化树脂。 可固化树脂含有反应性单体。 反应性单体含有异氰脲酸衍生物。 异氰脲酸衍生物优选为环氧乙烷的三（甲基）丙烯酸酯和异氰尿酸的ε-己内酯加合物。

公开(公告)号：US20100040871A1

公开(公告)日：2010-02-18

申请号：US12528532

申请日：2008-02-15

申请人： Masato Saito ,  Masuo Koyama ,  Yukio Kishi

发明人： Masato Saito ,  Masuo Koyama ,  Yukio Kishi

IPC分类号： B32B27/08 ,  C08G63/06 ,  C08G77/04 ,  C08F265/00

CPC分类号： G02B1/18 ,  C08J7/047 ,  C08J2367/02 ,  C08J2400/24 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/264

摘要： The hard coat film 1 of the present invention shows a contact angle for water of 110 degrees or smaller and a contact angle for camellia oil of 50 degrees or smaller. According to the present invention, even if fingerprints are adhered to the hard coat film 1, these fingerprints are inconspicuous. The hard coat film 1 of the present invention preferably shows a contact angle for water of 50 degrees or larger and a wet tension of 27 to 45 mN/m. With these characteristics, in addition to inconspicuousness of fingerprints, wiping-off property for fingerprints is improved.

摘要翻译： 本发明的硬涂膜1表现出110度以下的水接触角和50度以下的山茶油的接触角。 根据本发明，即使指纹附着在硬涂膜1上，这些指纹也不明显。 本发明的硬涂膜1优选显示50度以上的水的接触角和27〜45mN / m的湿张力。 具有这些特征，除了指纹的不显眼之外，指纹的擦除性能得到改善。

公开(公告)号：US20100035053A1

公开(公告)日：2010-02-11

申请号：US12527588

申请日：2008-12-02

申请人： Yukio Kishi ,  Masuo Koyama ,  Masato Saito

发明人： Yukio Kishi ,  Masuo Koyama ,  Masato Saito

IPC分类号： C08F126/06 ,  B32B27/28 ,  B32B27/36

CPC分类号： C08F290/06 ,  C08G18/3853 ,  C08K5/06 ,  C08K5/10 ,  C09D4/00 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/264 ,  Y10T428/265

摘要： A hard coat layer on which adhered fingerprints are inconspicuous is provided. The hard coat layer 1 consists of a cured product. The cured product is formed by curing a curable composition by irradiating it with an ultraviolet ray. The curable composition contains a curable resin. The curable resin contains reactive monomers. The reactive monomers contain an isocyanuric acid derivative. The isocyanuric acid derivative is preferably tri(meth)acrylate of an ethylene oxide and ε-caprolactone adduct of isocyanuric acid.

摘要翻译： 提供粘附指纹不显眼的硬涂层。 硬涂层1由固化产物组成。 固化产物通过用紫外线照射固化可固化组合物而形成。 可固化组合物含有可固化树脂。 可固化树脂含有反应性单体。 反应性单体含有异氰脲酸衍生物。 异氰尿酸衍生物优选为环氧乙烷的三（甲基）丙烯酸酯和异氰脲酸的ε-己内酯加成物。

公开(公告)号：US20090042017A1

公开(公告)日：2009-02-12

申请号：US10594255

申请日：2005-03-25

申请人： Keiichi Kitahara ,  Masato Saito ,  Masuo Koyama ,  Yoshihisa Kimura

发明人： Keiichi Kitahara ,  Masato Saito ,  Masuo Koyama ,  Yoshihisa Kimura

IPC分类号： B32B5/16

CPC分类号： G09F7/002 ,  G09F7/00 ,  G09F13/04 ,  Y10T428/25

摘要： To provide a surface protective sheet having superior anti-ultraviolet property and exhibiting little yellow tint.The surface protective sheet of the present invention has an anti-ultraviolet layer on at least one surface of a plastic film, and the anti-ultraviolet layer comprises an ultraviolet absorber, an ionizing radiation curable resin composition, and spherical microparticles having a mean particle diameter of 1 to 20 μm, and the microparticles are contained in an amount of 0.4 to 3% by weight in the anti-ultraviolet layer. The anti-ultraviolet layer preferably contains 0.01 to 1% by weight of organopolysiloxane.

摘要翻译： 提供具有优异抗紫外线性能并且显示出很少黄色色调的表面保护片。 本发明的表面保护片在塑料膜的至少一个表面上具有防紫外线层，抗紫外线层含有紫外线吸收剂，电离辐射固化性树脂组合物，平均粒径 在抗紫外线层中含有0.4〜3重量％的微粒。 抗紫外线层优选含有0.01〜1重量％的有机聚硅氧烷。

公开(公告)号：US07709084B2

公开(公告)日：2010-05-04

申请号：US10588951

申请日：2005-02-10

申请人： Masato Saito ,  Keiichi Kitahara ,  Masuo Koyama ,  Yoshihisa Kimura

发明人： Masato Saito ,  Keiichi Kitahara ,  Masuo Koyama ,  Yoshihisa Kimura

IPC分类号： B32B27/32 ,  B32B5/16 ,  B32B17/10 ,  G02F1/133 ,  G06F3/041

CPC分类号： C08J7/047 ,  C08J2433/00 ,  G06F3/045 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/26 ,  Y10T428/269

摘要： There is provided an anti-Newton ring sheet having an excellent anti-sparkle property, which can prevent the generation of sparkles when it is used in a touch panel using a high-definition color display, and a touch panel using this anti-Newton ring sheet.The anti-Newton ring sheet 1 of the present invention has an anti-Newton ring layer 3 comprising ionizing radiation curable organic-inorganic hybrid resin (binder component 32) and fine particles 31 on one surface of a transparent substrate 2, and preferably the mean diameter and the coefficient of variation of the diameter of the particle 31 is not less than 0.5 μm and not more than 3.0 μm and not less than 20% and not more than 80%, respectively, and the thickness of the anti-Newton ring layer 3 is preferably not less than 0.2 μm and not more than 3.5 μm.

摘要翻译： 提供了具有优异防火花性能的抗牛顿环片，其可以在使用高清晰度彩色显示器的触摸面板中使用时防止产生闪光，并且使用该抗牛顿环的触摸面板 片。 本发明的抗牛顿环片1具有包含电离辐射固化型有机 - 无机杂化树脂（粘合剂成分32）和透明基板2的一个表面上的微粒31的抗牛顿环层3， 颗粒31的直径和直径的变化系数分别不小于0.5μm且不大于3.0μm且不小于20％且不大于80％，并且抗牛顿环层的厚度 3优选为0.2μm以上且3.5μm以下。

公开(公告)号：US08279383B2

公开(公告)日：2012-10-02

申请号：US12440158

申请日：2007-09-21

申请人： Masato Saito ,  Masuo Koyama

发明人： Masato Saito ,  Masuo Koyama

IPC分类号： G02F1/1333

CPC分类号： G06F3/045 ,  G02F1/13338 ,  Y10T428/24942

摘要： The present invention provides a film for optical use wherein interference patterns are inconspicuous, while hard coat properties and image sharpness are maintained.In the film for optical use, an undercoat layer 22 is disposed between a base material layer 21 and a resin layer 23 having hard coat properties. Refractive index na of the base material layer 21, refractive index nb of the undercoat layer 22 and refractive index nc of the resin layer 23 satisfy the relationship of na≦nb≦nc or na≧nb≧nc (provided that na≠nc). The difference between the refractive index na of the base material layer 21 and the refractive index nb of the resin layer 23 is 0.5 or smaller. Since the difference of refractive indexes of adjacent layers is low, interference unevenness can be suppressed and image sharpness can be maintained.

摘要翻译： 本发明提供了一种用于光学用途的膜，其中干涉图案不显眼，同时保持硬涂层性质和图像清晰度。 在光学用膜中，在基材层21和具有硬涂层性质的树脂层23之间设置底涂层22。 基材层21的折射率na，底涂层22的折射率nb和树脂层23的折射率nc满足na＆nlE; nb＆nlE; nc或na≥bn≥nc（n≠nc）的关系。 基材层21的折射率na与树脂层23的折射率nb的差为0.5以下。 由于相邻层的折射率差较小，因此可以抑制干涉不均匀性，并且可以保持图像清晰度。

公开(公告)号：US20090315844A1

公开(公告)日：2009-12-24

申请号：US12440158

申请日：2007-09-21

申请人： Masato Saito ,  Masuo Koyama

发明人： Masato Saito ,  Masuo Koyama

IPC分类号： G06F3/041 ,  B32B7/02 ,  G02B1/10

CPC分类号： G06F3/045 ,  G02F1/13338 ,  Y10T428/24942

摘要： The present invention provides a film for optical use wherein interference patterns are inconspicuous, while hard coat properties and image sharpness are maintained.In the film for optical use, an undercoat layer 22 is disposed between a base material layer 21 and a resin layer 23 having hard coat properties. Refractive index na of the base material layer 21, refractive index nb of the undercoat layer 22 and refractive index nc of the resin layer 23 satisfy the relationship of na≦nb≦nc or na≧nb≧nc (provided that na≠nc). The difference between the refractive index na of the base material layer 21 and the refractive index nb of the resin layer 23 is 0.5 or smaller. Since the difference of refractive indexes of adjacent layers is low, interference unevenness can be suppressed and image sharpness can be maintained.

摘要翻译： 本发明提供了一种用于光学用途的膜，其中干涉图案不显眼，同时保持硬涂层性质和图像清晰度。 在光学用膜中，在基材层21和具有硬涂层性质的树脂层23之间设置底涂层22。 基材层21的折射率na，底涂层22的折射率nb和树脂层23的折射率nc满足na <= nb <= nc或na> = nb> = nc的关系（条件是纳米 ）。 基材层21的折射率na与树脂层23的折射率nb的差为0.5以下。 由于相邻层的折射率差较小，因此可以抑制干涉不均匀性，并且可以保持图像清晰度。

公开(公告)号：US08236406B2

公开(公告)日：2012-08-07

申请号：US10535242

申请日：2003-11-20

申请人： Masuo Koyama ,  Keiichi Kitahara ,  Masato Saito ,  Junji Ichinokawa ,  Yoshihisa Kimura

发明人： Masuo Koyama ,  Keiichi Kitahara ,  Masato Saito ,  Junji Ichinokawa ,  Yoshihisa Kimura

IPC分类号： G02F1/1335

CPC分类号： C08J7/047 ,  C08J2369/00 ,  Y10T428/24355 ,  Y10T428/24372

摘要： A fingerprint easily erasable film formed by providing a resin layer on a substrate, in which surface of the resin layer is matted and which is formed so that the surface of the resin layer should show a wet tension (JIS-K 6768:1999) of 25 mN/m or higher. Preferably, the resin layer has a surface roughness of 0.2 to 2.0 μm in terms of the ten point mean roughness Rz (JIS-B 0601:1994). The resin layer preferably contains an ionizing radiation curable resin and a matting agent, more preferably, two kinds of matting agents having different average particle diameters. On the fingerprint easily erasable film having such a configuration, ingredients of fingerprint are unlikely to adhere, and even if ingredients of fingerprint adhere, the ingredients of fingerprint can be removed substantially completely or to such a degree that they cannot be visually observed by wiping with cloth or the like.

摘要翻译： 一种指纹易擦除膜，其通过在基板上设置树脂层而形成，其中树脂层的表面被消光，并且形成为使得树脂层的表面应该呈现湿的张力（JIS-K 6768：1999） 25 mN / m以上。 优选地，根据十点平均粗糙度Rz（JIS-B 0601：1994），树脂层的表面粗糙度为0.2〜2.0μm。 树脂层优选含有电离辐射固化性树脂和消光剂，更优选含有平均粒径不同的两种消光剂。 在具有这种配置的指纹容易擦除的薄膜上，指纹的成分不可能粘附，并且即使指纹的成分粘附，指纹的成分可以基本上完​​全去除或者通过用 布等。

公开(公告)号：US20100040840A1

公开(公告)日：2010-02-18

申请号：US12528711

申请日：2008-03-19

申请人： Masato Saito ,  Masuo Koyama

发明人： Masato Saito ,  Masuo Koyama

IPC分类号： B32B3/10 ,  C08G18/28 ,  C08F22/10 ,  B32B27/40 ,  B32B27/30 ,  B32B7/12

CPC分类号： B29C45/14811 ,  B29K2715/006 ,  B29K2995/002 ,  B29K2995/0087 ,  C08J7/047 ,  C08J2333/06 ,  C08J2369/00 ,  C08J2400/24 ,  Y10T428/24802 ,  Y10T428/265 ,  Y10T428/2848 ,  Y10T428/31551 ,  Y10T428/31678

摘要： A film for insert molding comprising a base material film and a hard coat layer provided on at least one surface of the base material film, wherein the hard coat layer is formed from an ionizing radiation curable resin containing a reactive monomer having a cyclo ring structure containing at least one kind of element selected from carbon, nitrogen, oxygen, and silicon. The hard coat layer of this film for insert molding has sufficient surface hardness, and can prevent cracks which are likely to be generated at the time of molding (it has superior anti-cracking property).

摘要翻译： 一种嵌入成型用薄膜，其特征在于，在基材薄膜的至少一个表面上设置有基材薄膜和硬涂层，其特征在于，所述硬涂层由含有具有环状结构的反应性单体的电离辐射固化性树脂形成，所述反应性单体含有 选自碳，氮，氧和硅中的至少一种元素。 用于嵌入成型的该薄膜的硬涂层具有足够的表面硬度，并且可以防止在模制时可能产生的裂纹（具有优异的抗裂纹性）。

公开(公告)号：US20090130464A1

公开(公告)日：2009-05-21

申请号：US12224227

申请日：2007-02-13

申请人： Hikaru Nishinaga ,  Keiichi Kitahara ,  Masato Saito ,  Kazushige Matsumoto ,  Masuo Koyama ,  Yoshihisa Kimura

发明人： Hikaru Nishinaga ,  Keiichi Kitahara ,  Masato Saito ,  Kazushige Matsumoto ,  Masuo Koyama ,  Yoshihisa Kimura

IPC分类号： B32B27/20

CPC分类号： G02B1/16 ,  C08G77/26 ,  C08J7/047 ,  C08J2367/02 ,  C08L83/08 ,  C09D4/06 ,  C09D183/08 ,  G02B1/105 ,  G02B1/111 ,  G02B1/14 ,  Y10T428/31663

摘要： An antistatic hard coat film showing antistatic property and antireflection property for outer lights as well as superior hard coat properties such as superior surface hardness and antiscratching property is provided. The antistatic hard coat film of the present invention comprises an antistatic hard coat layer formed from an ionizing radiation curable resin, a pigment and a polymer antistatic agent having an organopolysiloxane unit and a quaternary ammonium salt unit, and the hard coat layer contains 1 to 5% by weight of the pigment. Weight ratio of the ionizing radiation curable resin and the polymer antistatic agent is preferably 6:4 to 5:5.

摘要翻译： 本发明提供了表现出外部防静电性和防反射性的抗静电硬涂层以及优异的硬涂层性能，例如优异的表面硬度和抗锯切性。 本发明的抗静电硬涂膜包括由电离辐射固化树脂形成的抗静电硬涂层，具有有机聚硅氧烷单元和季铵盐单元的颜料和聚合物抗静电剂，硬涂层含有1至5个 重量％的颜料。 电离辐射固化树脂和聚合物抗静电剂的重量比优选为6:4至5:5。