利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

17 条记录 (耗时 0.027 秒)

    NOVEL DICARBANIONIC INITIATOR, A PROCESS FOR THE PREPARATION AND USE THEREOF
    5.
    发明申请
    NOVEL DICARBANIONIC INITIATOR, A PROCESS FOR THE PREPARATION AND USE THEREOF 有权
    新西兰DICARBANIONIC INITIATOR，其制备和使用的过程

    公开(公告)号：US20070197723A1

    公开(公告)日：2007-08-23

    申请号：US11539222

    申请日：2006-10-06

    申请人： Yves Gnanou ,  Rachid Matmour ,  Arvind Sudhakar More ,  Prakash Purushottam Wadgaonkar

    发明人： Yves Gnanou ,  Rachid Matmour ,  Arvind Sudhakar More ,  Prakash Purushottam Wadgaonkar

    IPC分类号： C08L53/00 ,  C08F297/00

    CPC分类号： C07F1/02

    摘要： The present invention provides a novel dicarbanionic initiator of formula (I). The present process further provides a process for the preparation of dicarbanionic initiator of formula (I) comprising reacting 1-bromo-4-(4′-bromophenoxy)-2-pentadecyl benzene of formula (II) with alkyllithium compound for an effecting halogen-lithium exchange reaction of 1-bromo-4-(4′-bromophenoxy)-2-pentadecyl benzene with sec-butyllithium in the presence of a non polar solvent, at a temperature in the range of 0 to 250 C and its use as an initiator for the synthesis of telechelic polydienes and polystyrenes and SBS or SIS triblock copolymers.

    摘要翻译： 本发明提供了新的式（I）二碳酸酯引发剂。 本发明进一步提供了制备式（I）的二羧酸引发剂的方法，包括使式（II）的1-溴-4-（4'-溴苯氧基）-2-十五烷基苯与烷基锂化合物反应， 在非极性溶剂的存在下，在0至25℃的温度下，1-溴-4-（4'-溴苯氧基）-2-十五烷基苯与仲丁基锂的锂交换反应， 并且其用作合成远电离子聚二烯和聚苯乙烯和SBS或SIS三嵌段共聚物的引发剂。

    Dicarbanionic initiator, a process for the preparation and use thereof
    6.
    发明授权
    Dicarbanionic initiator, a process for the preparation and use thereof 有权
    二胺引发剂，其制备方法和用途

    公开(公告)号：US07709687B2

    公开(公告)日：2010-05-04

    申请号：US11539222

    申请日：2006-10-06

    申请人： Yves Gnanou ,  Rachid Matmour ,  Arvind Sudhakar More ,  Prakash Purushottam Wadgaonkar

    发明人： Yves Gnanou ,  Rachid Matmour ,  Arvind Sudhakar More ,  Prakash Purushottam Wadgaonkar

    IPC分类号： C07C43/205 ,  C07F1/02 ,  C08F297/04 ,  C07C41/09

    CPC分类号： C07F1/02

    摘要： The present invention provides a novel dicarbanionic initiator of formula (I). The present process further provides a process for the preparation of dicarbanionic initiator of formula (I) comprising reacting 1-bromo-4-(4′-bromophenoxy)-2-pentadecyl benzene of formula (II) with alkyllithium compound for an effecting halogen-lithium exchange reaction of 1-bromo-4-(4′-bromophenoxy)-2-pentadecyl benzene with sec-butyllithium in the presence of a non polar solvent, at a temperature in the range of 0 to 25° C. and its use as an initiator for the synthesis of telechelic polydienes and polystyrenes and SBS or SIS triblock copolymers.

    摘要翻译： 本发明提供了新的式（I）二碳酸酯引发剂。 本发明进一步提供了制备式（I）的二羧酸引发剂的方法，其包括使式（II）的1-溴-4-（4'-溴苯氧基）-2-十五烷基苯与烷基锂化合物反应， 在非极性溶剂的存在下，在0至25℃的温度范围内，1-溴-4-（4'-溴苯氧基）-2-十五烷基苯与仲丁基锂的锂交换反应及其用途 作为合成远电离子聚二烯和聚苯乙烯和SBS或SIS三嵌段共聚物的引发剂。

    Process for manufacturing multisequence star or network polycondensates by di- or multi-aldehyde coupling, and polycondensates obtained
    8.
    发明授权
    Process for manufacturing multisequence star or network polycondensates by di- or multi-aldehyde coupling, and polycondensates obtained 失效
    通过二醛或多醛偶联制备多价星或网状缩聚物的方法和获得的缩聚物

    公开(公告)号：US5346956A

    公开(公告)日：1994-09-13

    申请号：US2818

    申请日：1993-01-11

    申请人： Yves Gnanou

    发明人： Yves Gnanou

    IPC分类号： C08F8/28 ,  C08F297/02 ,  C08G2/38 ,  C08L33/04 ,  C08K5/07 ,  C08L61/00

    CPC分类号： C08F297/026 ,  C08G2/38

    摘要： A novel process for coupling living polymers containing terminal (meth)acrylic units, which enables an increase in molecular weight and/or a defined multisequencing and/or a star structure with a defined number of branches, is disclosed. The disclosed process comprises the steps of: (i) anionic polymerization using an initiator system consisting of a functional initiator and a ligand to obtain a living polymer containing living terminal (meth)acrylics units; (ii) reacting it with an aldehyde compound of formula R--(CHO).sub.r in which r.gtoreq.2; and (iii) recovering the final polycondensate by means known per se.

    摘要翻译： 公开了一种用于偶联含有末端（甲基）丙烯酸单元的活性聚合物的新方法，其使得能够增加分子量和/或具有限定数量的分支的定义的多重度和/或星形结构。 所公开的方法包括以下步骤：（i）使用由官能引发剂和配体组成的引发剂体系进行阴离子聚合，得到含有活性末端（甲基）丙烯酸单元的活性聚合物; （ii）使其与其中r≥2的式R-（CHO）r的醛化合物反应; 和（iii）通过本身已知的方法回收最终缩聚物。