Olefin polymerization catalyst system

    公开(公告)号:US20050137367A1

    公开(公告)日:2005-06-23

    申请号:US10744297

    申请日:2003-12-22

    摘要: This invention relates to a catalyst precursor compound comprising a tridentate phenoxy-amide-amine group bound to a group 3 to 12 metal or lanthanide metal. In particular, this invention relates to a catalyst precursor compound represented by the formula: wherein: M is a group 3 to group 12 transition metal or lanthanide metal, provided however N1 is not part of a pyridine ring when M is a group 8, 9, or 10 metal; Q is oxygen or sulfur; N is nitrogen; N1 is nitrogen; R1, is a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a heteroatom or heteroatom containing group; R2 and R3 are independently, a hydrogen, a halogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, or a substituted halocarbyl, a heteroatom or heteratom containing group and R2 and R3 together may form a multidentate ligand, such as a bidentate dianionic ligand; R4 is hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a heteroatom or heteroatom containing group; R5 is a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a heteroatom or heteroatom containing group; R6, R7, and R8 are, independently, a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a heteroatom or heteroatom containing group, and any two of R1, R6, R7, and R8 may form a fused ring system; each Ris, independently, hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl group, or a heteroatom or heteroatom containing group; R10 is a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl group, or a heteroatom or heteroatom containing group; where any two adjacent R groups may form a ring structure.

    Catalyst compound containing divalent tridentate ligand
    5.
    发明申请
    Catalyst compound containing divalent tridentate ligand 有权
    含二价三齿配体的催化剂化合物

    公开(公告)号:US20060094842A1

    公开(公告)日:2006-05-04

    申请号:US11221990

    申请日:2005-09-08

    IPC分类号: C08F4/72 B01J31/00

    摘要: This invention relates to a catalyst compound represented by the formula: wherein: M is a Group 3 to 12 transition metal; each Ra is, independently, a hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group or halogen; each of R1, R2, R3, R4, R5, R7, R8, R9, R10, and R11 is, independently a hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group or halogen; R6 is hydrogen, a hydrocarbyl group, or a substituted hydrocarbyl group; x is 0, 1, 2, 3 or 4; and each Z is, independently, a group 15 atom. This invention also relates to catalyst systems comprising the above catalyst compound and a activator and the use of such catalyst systems to polymerize monomers, including olefin monomers.

    摘要翻译: 本发明涉及由下式表示的催化剂化合物:其中:M为第3至12族过渡金属; 每个R a a独立地是氢,烃基,取代的烃基或卤素; R 1,R 2,R 3,R 4,R 5,R 5,...中的每一个 R 7,R 8,R 9,R 10和R 11, SUP>独立地是氢,烃基,取代的烃基或卤素; R 6是氢,烃基或取代的烃基; x为0,1,2,3或4; 并且每个Z独立地是基团15原子。 本发明还涉及包含上述催化剂化合物和活化剂的催化剂体系以及这种催化剂体系用于聚合单体(包括烯烃单体)的用途。