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1.发明授权Composition and method for controlling polymerization rate of cyclic polycarbonate oligomer with encapsulated catalyst 失效用封装催化剂控制环状聚碳酸酯低聚物的聚合速度的组成和方法
公开(公告)号：US4755588A
公开(公告)日：1988-07-05
申请号：US899375
申请日：1986-08-22
CPC分类号： C08G64/30
摘要： The polymerization rate of a cyclic polycarbonate oligomer composition to linear polycarbonates is controlled by encapsulating a polycarbonate formation catalyst in a thermoplastic polymer which is soluble or stably dispersible in said oligomer compositions at elevated temperatures; blending the encapsulated catalyst with the oligomer composition under non-polymerization conditions; and heating the blend to a temperature at which polymerization takes place. Among the polymers suitable for encapsulating the catalyst are polyetherimides.
摘要翻译： 环状聚碳酸酯低聚物组合物对线性聚碳酸酯的聚合速率通过将聚碳酸酯形成催化剂包封在热可塑性聚合物中来控制，热塑性聚合物在高温下可溶或稳定地分散在所述低聚物组合物中; 在非聚合条件下将包封的催化剂与低聚物组合物共混; 并将共混物加热至发生聚合的温度。 适用于包封催化剂的聚合物中有聚醚酰亚胺。
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2.发明授权Method for converting cyclic polycarbonate oligomer mixtures to linear polycarbonate, and composition resulting therefrom 失效将环状聚碳酸酯低聚物混合物转化为线性聚碳酸酯的方法，以及由其制得的组合物
公开(公告)号：US4740583A
公开(公告)日：1988-04-26
申请号：US888673
申请日：1986-07-24
申请人： Daniel J. Brunelle , Thomas L. Evans , Michael A. Vallance , Kevin R. Stewart , Thomas G. Shannon , David A. Williams , Dwight J. Patterson , Niles R. Rosenquist , William Hilakos
发明人： Daniel J. Brunelle , Thomas L. Evans , Michael A. Vallance , Kevin R. Stewart , Thomas G. Shannon , David A. Williams , Dwight J. Patterson , Niles R. Rosenquist , William Hilakos
摘要： Cyclic polycarbonate (or thiol analog) oligomer mixtures are prepared by the reaction of bishaloformates or their thio analogs, or mixtures thereof with dihydroxy or dimercapto compounds, with alkali metal hydroxides and various amines. The oligomer mixtures may be converted to polycarbonates or their thiol analogs by a method which is particularly adaptable to integration with polycarbonate processing operations. Polymerization may be conducted simultaneously with molding, extrusion and the like. The oligomer mixtures are adaptable to the preparation of filled prepregs.
摘要翻译： 通过双卤代甲酸酯或其硫代类似物或其与二羟基或二巯基化合物的混合物与碱金属氢氧化物和各种胺的反应制备环状聚碳酸酯（或硫醇类似物）低聚物混合物。 低聚物混合物可以通过特别适用于与聚碳酸酯加工操作整合的方法转化为聚碳酸酯或其硫醇类似物。 聚合可以与成型，挤出等同时进行。 低聚物混合物适用于填充的预浸料的制备。
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3.发明申请FLAME RETARDANT POLY(SILOXANE-ETHERIMIDE) COPOLYMER COMPOSITIONS, METHODS OF MANUFACTURE, AND ARTICLES FORMED THEREFROM 有权阻燃聚合物（SILOXANE-ETHERIMIDE）共聚物组合物，制造方法及其形成的制品公开(公告)号：US20130085240A1
公开(公告)日：2013-04-04
申请号：US13251130
申请日：2011-09-30
申请人： Paul D. Sybert , Thomas L. Evans
发明人： Paul D. Sybert , Thomas L. Evans
IPC分类号： C08G59/06
CPC分类号： C08G73/106 , C08G73/1042 , C08G73/1046 , C08G77/455 , C08G77/46 , C08L69/00 , C08L79/08 , C08L83/12 , C09K21/14 , Y10T428/31507 , Y10T428/31721 , C08L83/10
摘要： A composition comprising: a first polymer comprising a poly(etherimide-siloxane) copolymer comprising (a) a repeating polyetherimide unit, and (b) a poly(siloxane) block unit, a second polymer different from the first polymer and comprising bromine; and optionally, a third polymer comprising a polycarbonate different from the first polymer and second polymer; wherein polysiloxane block units are present in the composition in an amount of at least 0.3 wt %, and bromine is present in the composition in an amount of at least 7.8 wt %, each based on the sum of the wt % of the first, second, and third polymers; and further wherein an article molded from the composition has an OSU integrated 2 minute heat release test value of less than 65 kW-min/m2 and a peak heat release rate of less than 65 kW/m2, and an E662 smoke test Dmax value of less than 200.
摘要翻译： 一种组合物，其包含：包含（a）重复聚醚酰亚胺单元的聚（醚酰亚胺 - 硅氧烷）共聚物的第一聚合物和（b）聚（硅氧烷）嵌段单元，不同于第一聚合物并包含溴的第二聚合物; 和任选地，包含不同于第一聚合物和第二聚合物的聚碳酸酯的第三聚合物; 其中聚硅氧烷嵌段单元以至少0.3重量％的量存在于组合物中，并且组合物中溴以至少7.8重量％的量存在，每个量基于第一个，第二个 和第三聚合物; 并且其中由所述组合物成型的制品具有小于65kW-min / m 2的OSU集成的2分钟的热释放试验值和小于65kW / m 2的峰值放热率，以及E662烟雾试验Dmax值 小于200。
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4.发明申请Marine vehicle component comprising flame retardant compositions and methods of manufacture 有权包含阻燃剂组合物和制造方法的船用载体组分公开(公告)号：US20120269994A1
公开(公告)日：2012-10-25
申请号：US13436782
申请日：2012-03-30
CPC分类号： C08L83/10 , C08K3/22 , C08K5/0041 , C08K2003/2237 , C08L63/00 , C08L69/00 , C08L83/06 , Y10T428/1352 , Y10T428/31507 , Y10T428/31663
摘要： A marine vehicle component wherein the component is a partition or a light cover, and wherein the marine vehicle component is molded or formed from a thermoplastic polymer composition comprising a siloxane-containing copolymer in an amount effective to provide a total of 0.2 to 6.5 wt % of siloxane units based on the total weight of the polymers in the thermoplastic polymer composition, a bromine-containing polymer in an amount effective to provide 9 to 13 wt % of bromine, based on the total weight of the polymers in the thermoplastic polymer composition, and optionally a third polymer, wherein the wt % of the siloxane-containing copolymer, the bromine-containing polymer, and the optional third polymer, sum to 100 wt %, and 0.05 to 10 wt % of a light diffuser additive, based on the total weight of polymers in the thermoplastic polymer composition.
摘要翻译： 一种船用车辆部件，其中所述部件是隔板或灯罩，并且其中所述船用车辆部件由热塑性聚合物组合物模制或形成，所述热塑性聚合物组合物包含含有硅氧烷的共聚物，其量有效地提供总计为0.2至6.5重量％ 的基于热塑性聚合物组合物中的聚合物总重量的硅氧烷单元，基于热塑性聚合物组合物中聚合物的总重量，有效提供9至13重量％溴的含溴聚合物， 和任选的第三聚合物，其中基于所述第三聚合物，所述含硅氧烷的共聚物，含溴聚合物和任选的第三聚合物的总重量为100重量％，和0.05至10重量％的光漫射添加剂 热塑性聚合物组合物中聚合物的总重量。
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公开(公告)号：US20090266991A1
公开(公告)日：2009-10-29
申请号：US12258176
申请日：2008-10-24
申请人： Thomas L. Evans , Sriramakrishna Maruvada , Vandita Pai-Paranjape , Philippe Schottland , David Lawrence Zoller
发明人： Thomas L. Evans , Sriramakrishna Maruvada , Vandita Pai-Paranjape , Philippe Schottland , David Lawrence Zoller
CPC分类号： G11B23/281 , G01N21/64 , G11B7/2433 , G11B7/2472 , G11B7/248 , G11B7/252 , G11B7/2534 , G11B7/254 , G11B7/2578 , G11B7/258 , G11B23/283
摘要： In one embodiment, a tagged polymer composition, comprises: a base polymer composition comprising a forensic polymer composition and a dynamic response authentication marker. The forensic polymer composition comprises a marked polymer having a forensic authentication marker. The forensic authentication marker is present in an amount sufficient to be detected by a forensic analytical technique. The dynamic response authentication marker is present in an amount sufficient to be detected by a dynamic response analytical technique and wherein, when tested, the dynamic response authentication marker has a change in mode.
摘要翻译： 在一个实施方案中，标记的聚合物组合物包含：包含法医聚合物组合物和动态响应认证标记的基础聚合物组合物。 法医聚合物组合物包含具有法医认证标记的标记聚合物。 法医认证标记以足以通过法医分析技术检测的量存在。 动态响应认证标记以足以由动态响应分析技术检测的量存在，并且其中当被测试时，动态响应认证标记具有模式改变。
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6.发明授权Multilayer composite pipe fluid conduit system using multilayer composite pipe and method of making the composite 失效多层复合管流体管道系统采用多层复合管及复合材料的制作方法公开(公告)号：US06293311B1
公开(公告)日：2001-09-25
申请号：US09083803
申请日：1998-05-22
申请人： John C. Bushi , Girish T. Dalal , Thomas L. Evans , Andrew M. Olah , Theodore J. Schmitz , Andrew L. Auvil , A. Donald Meltzer , Stefanie Hahnen-Schroeder , Anthony Kordecki
发明人： John C. Bushi , Girish T. Dalal , Thomas L. Evans , Andrew M. Olah , Theodore J. Schmitz , Andrew L. Auvil , A. Donald Meltzer , Stefanie Hahnen-Schroeder , Anthony Kordecki
IPC分类号： F16L1104
CPC分类号： B32B1/08 , B29C47/0023 , B29C47/0052 , B29C47/065 , B29C53/08 , B29C65/48 , B29C65/4815 , B29C65/4835 , B29C66/1222 , B29C66/1224 , B29C66/12469 , B29C66/341 , B29C66/5221 , B29C66/52231 , B29C66/52291 , B29C66/52292 , B29C66/52293 , B29C66/5344 , B29C66/71 , B29C66/72321 , B29C66/73771 , B29C66/73773 , B29C66/7392 , B29C66/73921 , B29D23/001 , B29L2009/00 , B29L2009/003 , B32B7/12 , B32B15/08 , B32B15/20 , B32B27/304 , B32B37/00 , B32B37/153 , B32B2311/24 , B32B2327/06 , B32B2597/00 , F16L9/147 , F16L47/02 , Y10S138/01 , B29K2027/06 , B29K2081/06 , B29K2069/00 , B29K2055/02 , B29K2033/12 , B29K2033/08 , B29K2027/16
摘要： A multilayer composite pipe structure is described. The multilayer composite pipe comprises a hollow inner conduit, a first layer of adhesive, a metallic intermediate layer, a second layer of adhesive, as well as, the outer thermoplastic layer, respectively. The hollow inner conduit is made from any rigid thermoplastic material. The outer thermoplastic layer is made from a rigid, amorphous thermoplastic polymer. This multilayer composite pipe is pressure bearing. In one embodiment, the multilayer composite pipe is solvent cementable; whereas in another embodiment, the multilayer composite pipe is heat fusible. In still yet another embodiment of the invention, the multilayer composite pipe is bendable. Furthermore, the multilayer composite pipe can be used in a fluid conduit system with fittings with an optional insert.
摘要翻译： 描述了多层复合管结构。 多层复合管分别包括中空的内部导管，第一粘合剂层，金属中间层，第二层粘合剂，以及外部热塑性层。 中空内导管由任何刚性热塑性材料制成。 外部热塑性层由刚性的无定形热塑性聚合物制成。 该多层复合管是压力轴承。 在一个实施方案中，多层复合管是可溶剂粘结的; 而在另一个实施例中，多层复合管是热熔的。 在本发明的另一个实施例中，多层复合管是可弯曲的。 此外，多层复合管可以用于具有可选插入件的配件的流体管道系统中。
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公开(公告)号：USD332021S
公开(公告)日：1992-12-29
申请号：US557504
申请日：1990-07-24
申请人： Derwyn Cugley , Thomas L. Evans
设计人： Derwyn Cugley , Thomas L. Evans
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8.发明授权Method of regulating the polymerization of cyclic polycarbonate with initiator and polyhydric phenol 失效用引发剂和多元酚调节环状聚碳酸酯聚合的方法
公开(公告)号：US4849502A
公开(公告)日：1989-07-18
申请号：US158450
申请日：1988-02-22
CPC分类号： C08G64/307 , C08G64/30
摘要： A phenol or bisphenol has been found effective as a chain transfer agent in the polymerization of cyclic carbonates to make hydroxyl-terminated polycarbonate oligomer of varying molecular weight.
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9.发明授权Cyclic polycarbonate-polyepoxide reaction product and method for their preparation 失效环状聚碳酸酯 - 聚环氧化物反应产物及其制备方法
公开(公告)号：US4746725A
公开(公告)日：1988-05-24
申请号：US19153
申请日：1987-02-25
CPC分类号： C08G64/30
摘要： Resinous compositions are prepared by the reaction of a composition comprising cyclic polycarbonate oligomers with at least one polyepoxide compound, in the presence of a polycarbonate formation catalyst. The cyclic polycarbonate oligomer composition is preferably a mixture of oligomers of varying degrees of polymerization, and the polyepoxy compound is preferably triglycidyl isocyanurate or a bis-epoxy-terminated bisphenol A-epichlorohydrin concentrate. There may also be present a polycarbonate crosslinking agent. The product of the reaction is a crosslinked polycarbonate network. The method is particularly useful in reactive processing operations such as reaction injection molding.
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10.发明授权Method for preparing linear polycarbonate from cyclic oligomer with aryl carbanion generating catalyst 失效由环状低聚物与芳基碳负离子产生催化剂制备线性聚碳酸酯的方法
公开(公告)号：US4605731A
公开(公告)日：1986-08-12
申请号：US723672
申请日：1985-04-16
申请人： Thomas L. Evans , David A. Williams
发明人： Thomas L. Evans , David A. Williams
CPC分类号： C08G64/30
摘要： Cyclic polycarbonate oligomers are converted to linear polycarbonate resins by heating with a polycarbonate formation catalyst which generates aryl carbanions at temperatures up to about 300.degree. C. The preferred catalysts are tetraarylborates such as tetramethylammonium tetraphenylborate.
摘要翻译： 通过用聚碳酸酯形成催化剂加热将环状聚碳酸酯低聚物转化成线性聚碳酸酯树脂，该聚碳酸酯形成催化剂在高达约300℃的温度下产生芳基碳阴离子。优选的催化剂是四芳基硼酸盐，例如四苯基硼酸四甲基铵。
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