公开(公告)号：US6138913A

公开(公告)日：2000-10-31

申请号：US981859

申请日：1998-01-05

申请人： Michael John Cyr ,  James John Krutak, Sr. ,  Horst Clauberg ,  Tony Wayne Helton

发明人： Michael John Cyr ,  James John Krutak, Sr. ,  Horst Clauberg ,  Tony Wayne Helton

IPC分类号： G06K19/14 ,  G06K7/10

CPC分类号： G06K19/14

摘要： An invisible indicia or encoded information is imprinted on a substrate using a compound which produces a fluorescence at a wavelength greater than about 650 nm when exposed to near infrared radiation. The information covered by a layer of material that reflects or absorbs a substantial amount of the visible and UV radiation illuminating its surface.

摘要翻译： PCT No.PCT / US97 / 20342 Sec。 371日期：1998年1月5日 102（e）日期1998年1月5日PCT 1997年11月5日PCT公布。 第WO98 / 22291号公报 日期1998年5月28日当暴露于近红外辐射时，使用产生大于约650nm的波长的荧光的化合物将无形标记或编码信息印在底物上。 由材料层覆盖的信息，其反射或吸收大量可见光和UV辐射照射其表面。

公开(公告)号：US06174400B1

公开(公告)日：2001-01-16

申请号：US08811311

申请日：1997-03-04

申请人： James John Krutak, Sr. ,  Michael John Cyr ,  Nelson Zamora Escano ,  Horst Clauberg ,  Barbara Crawford Jackson ,  Tony Wayne Helton

发明人： James John Krutak, Sr. ,  Michael John Cyr ,  Nelson Zamora Escano ,  Horst Clauberg ,  Barbara Crawford Jackson ,  Tony Wayne Helton

IPC分类号： B41M526

CPC分类号： B41M5/465 ,  B41M3/14 ,  B41M3/144 ,  B41M5/385 ,  G06K1/121 ,  G07D7/00 ,  Y10S428/913 ,  Y10S428/914

摘要： The present invention relates to thermal transfer ribbons comprising a ribbon backing element and at least one printing media layer comprising at least one near infrared fluorescent compound in a concentration which provides detectable fluorescence without imparting color to a mark made from said printing media layer. Methods for printing marks containing said at least one near infrared fluorescent compounds via thermal transfer and methods for reading said marks are also disclosed.

摘要翻译： 本发明涉及包含带状背衬元件的热转印带和至少一种包含至少一种近红外荧光化合物的印刷介质层，其浓度可提供可检测的荧光，而不会对由所述印刷介质层制成的标记赋予颜色。 还公开了通过热转印印刷含有所述至少一种近红外荧光化合物的标记的方法和用于读取所述标记的方法。

公开(公告)号：US6099930A

公开(公告)日：2000-08-08

申请号：US11805

申请日：1998-07-20

申请人： Michael John Cyr ,  Horst Clauberg ,  Tony Wayne Helton ,  Gregory W. Nelson ,  Randy B. Meade ,  James E. Moore ,  G. Russell Owens ,  Barbara C. Jackson ,  James John Krutak, Sr.

发明人： Michael John Cyr ,  Horst Clauberg ,  Tony Wayne Helton ,  Gregory W. Nelson ,  Randy B. Meade ,  James E. Moore ,  G. Russell Owens ,  Barbara C. Jackson ,  James John Krutak, Sr.

IPC分类号： G11B7/24 ,  G11B7/244 ,  G11B7/246 ,  G11B7/248 ,  G11B7/253 ,  G11B7/2531 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2535 ,  G11B7/2542 ,  G11B7/2585 ,  G11B7/26 ,  G11B23/28 ,  G11B23/40 ,  B32B3/00

CPC分类号： G11B23/281 ,  G11B23/40 ,  G11B7/24 ,  G11B7/244 ,  G11B7/245 ,  G11B7/248 ,  G11B7/253 ,  G11B7/2542 ,  G11B7/2585 ,  G11B7/26 ,  G11B2007/24624 ,  G11B7/2531 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2535 ,  Y10S428/913 ,  Y10S430/146 ,  Y10T428/21

摘要： A digital recording medium, such as a compact disc, having a substrate, a reflective layer and a protective layer includes a near infrared fluorophore in one of the layers. The near infrared fluorophore can be incorporated into the CD by coating, admixing, blending or copolymerization and in an amount to impart a detectable fluorescence from the fluorophore when exposed to electromagnetic radiation having a wavelength ranging from about 670 nanometers (nm) to about 1100 nm. A method of marking a CD with an invisible marking and an apparatus for detecting the fluorophore is further provided.

摘要翻译： PCT No.PCT / US97 / 23265 Sec。 371日期：1998年7月20日 102（e）1998年7月20日PCT PCT 1997年12月15日PCT公布。 公开号WO98 / 29238 日期1998年7月9日具有基板，反射层和保护层的诸如光盘的数字记录介质包括一层中的近红外荧光团。 通过涂布，混合，共混或共聚，可以将近红外荧光团掺入到CD中，并且当暴露于波长范围为约670纳米（nm）至约1100nm）的电磁辐射时，能够使荧光团发出可检测的荧光 。 还提供了用不可见标记标记CD的方法和用于检测荧光团的装置。

公开(公告)号：US5959296A

公开(公告)日：1999-09-28

申请号：US880037

申请日：1997-06-20

申请人： Michael John Cyr ,  James John Krutak, Sr. ,  Horst Clauberg ,  Randy Barnett Meade ,  James Edward Moore ,  Gabor Patonay

发明人： Michael John Cyr ,  James John Krutak, Sr. ,  Horst Clauberg ,  Randy Barnett Meade ,  James Edward Moore ,  Gabor Patonay

IPC分类号： G02B6/38 ,  G06K7/12 ,  G06K7/10

CPC分类号： G06K7/12 ,  G02B6/3861 ,  G02B6/3862 ,  G02B6/3887

摘要： An apparatus for detecting an invisible, near infrared fluorescing mark disposed on a background comprises: includes an excitation source for exciting the mark, having sufficient power to excite the mark and provide a fluorescent signal the mark from a; a signal detector for detecting the fluorescent signal from the mark; a and power modulator means for varying the power if the excitation source between zero and the maximum power level to produce a decodable fluorescent signal from the mark disposed on the background. A process for decoding an invisible mark having a near infrared fluorescing material includes the steps of: providing at least one invisible, near infrared fluorescing mark disposed on at least one portion of a background; exciting the mark with a laser having a maximum power level sufficient to provide a fluorescent signal from the mark; detecting the fluorescent signal and concurrently varying the power of the laser between zero and its maximum power, to obtain a decodable fluorescent signal.

摘要翻译： 用于检测设置在背景上的不可见的近红外荧光标记的装置包括：包括用于激发标记的激励源，具有足够的功率来激发标记并从a提供标记的荧光信号; 用于从标记检测荧光信号的信号检测器; a和功率调制器装置，用于如果激励源在零和最大功率水平之间改变功率，以从设置在背景上的标记产生可解码的荧光信号。 用于解码具有近红外荧光材料的不可见标记的方法包括以下步骤：提供设置在背景的至少一部分上的至少一个不可见的近红外荧光标记; 使用具有足以提供来自标记的荧光信号的最大功率电平的激光器来激发标记; 检测荧光信号并同时改变激光器在0和最大功率之间的功率，以获得可解码的荧光信号。

公开(公告)号：US06610772B1

公开(公告)日：2003-08-26

申请号：US09630518

申请日：2000-08-02

申请人： Horst Clauberg ,  Michael John Cyr ,  Robert Boyd Barbee ,  Tony Wayne Helton

发明人： Horst Clauberg ,  Michael John Cyr ,  Robert Boyd Barbee ,  Tony Wayne Helton

IPC分类号： C08K334

CPC分类号： B82Y30/00 ,  C08J5/005 ,  C08K5/0091 ,  C08K5/098 ,  C08K9/04

摘要： The present invention relates to oxygen scavenging compositions comprising a) platelet particles having attached thereto at least one oxygen scavenging organic cation and b) at least one oxidation catalyst. The oxygen scavenging compositions of the present invention maybe readily incorporated into a variety of matrix polymers to create polymer composites, which display improved passive barrier and oxygen scavenging capabilities. Articles formed from these composites are also disclosed.

摘要翻译： 本发明涉及除氧组合物，其包含a）附着有至少一种除氧有机阳离子的b）至少一种氧化催化剂的血小板颗粒。 本发明的除氧组合物可以容易地并入各种基质聚合物中以产生聚合物复合材料，其显示改进的被动屏障和除氧能力。 还公开了由这些复合材料形成的制品。

公开(公告)号：US06777479B1

公开(公告)日：2004-08-17

申请号：US09630517

申请日：2000-08-02

申请人： Linda Gail Bernard ,  Horst Clauberg ,  Michael John Cyr ,  John Walker Gilmer ,  Jeffrey Todd Owens ,  Mark Edward Stewart ,  Sam Richard Turner ,  Shriram Bagrodia ,  James Christopher Matayabas, Jr.

发明人： Linda Gail Bernard ,  Horst Clauberg ,  Michael John Cyr ,  John Walker Gilmer ,  Jeffrey Todd Owens ,  Mark Edward Stewart ,  Sam Richard Turner ,  Shriram Bagrodia ,  James Christopher Matayabas, Jr.

IPC分类号： C08K334

CPC分类号： B82Y30/00 ,  C08J5/005 ,  C08J2377/00 ,  C08K3/34 ,  C08K7/00 ,  C08K2201/008 ,  C08L77/00

摘要： Polymer composite materials comprising of least one polymer resin and platelet particles from at least one layered silicate material uniformly dispersed in the resin and articles prepared from the polymer composite materials. The polymer composite contains at least one polyamide resin, at least one oxygen scavenging system, and at least one layered silicate material. These polymer composite materials are especially useful for manufacturing clear polyester bottles and polyester film that are recyclable have improved active gas barrier properties to oxygen, and have improved passive barrier properties to carbon dioxide and other gases. The polymer composite materials can be used in relatively minor amounts as either a blend or a coextruded thin layer with virgin or post consumer recycled polyesters and related copolymners.

摘要翻译： 包含至少一种聚合物树脂的聚合物复合材料和均匀分散在树脂中的至少一种层状硅酸盐材料的片晶颗粒和由聚合物复合材料制备的制品。 聚合物复合材料含有至少一种聚酰胺树脂，至少一种除氧系统和至少一种层状硅酸盐材料。 这些聚合物复合材料特别可用于制造可再循环的透明聚酯瓶和聚酯膜，其具有改善的对氧的活性气体阻隔性能，并且具有改善的对二氧化碳和其它气体的被动阻挡性能。 聚合物复合材料可以以相对小的量用作共混物或共挤出的薄层，其具有原始或消费后的再生聚酯和相关共聚物。

公开(公告)号：US06455620B1

公开(公告)日：2002-09-24

申请号：US09630519

申请日：2000-08-02

申请人： Michael John Cyr ,  Horst Clauberg ,  Mark Edward Stewart ,  Stephen Neal Falling ,  Martin Emerson Rogers

发明人： Michael John Cyr ,  Horst Clauberg ,  Mark Edward Stewart ,  Stephen Neal Falling ,  Martin Emerson Rogers

IPC分类号： C08K506

CPC分类号： C08L71/02 ,  C08G63/672 ,  C08K5/098 ,  C08K2201/012 ,  C08L67/02

摘要： The present invention relates to oxygen scavenging compositions comprising an oxidation catalyst and at least one polyether selected from the group consisting of unsubstituted poly(alkylene glycol)s having alkylene chains of 1 to 3 carbon atoms, substituted or unsubstituted poly(alkylene glycol)s having alkylene chains of at least 4 carbon atoms, copolymers of poly(alkylene glycol)s, blends containing poly(alkylene glycol)s and mixtures thereof. The invention further relates to polymers containing said oxygen scavenging compounds and articles made therefrom.

摘要翻译： 本发明涉及包含氧化催化剂和至少一种选自具有1至3个碳原子的亚烷基链的未取代的聚（亚烷基二醇），取代或未取代的聚（亚烷基二醇）的聚醚的氧清除组合物，其具有 至少4个碳原子的亚烷基链，聚（亚烷基二醇）的共聚物，含有聚（亚烷基二醇）的共混物及其混合物。 本发明还涉及含有所述除氧化合物和由其制成的制品的聚合物。

公开(公告)号：US06870063B2

公开(公告)日：2005-03-22

申请号：US10719268

申请日：2003-11-21

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

IPC分类号： C09B1/28 ,  C07D249/08 ,  C07D249/12 ,  C08F246/00 ,  C08F283/00 ,  C08F290/06 ,  C08F290/14 ,  C09B1/32 ,  C09B1/58 ,  C09B1/62 ,  C09B69/10 ,  C09D4/00 ,  C09D4/06 ,  C09D7/12 ,  C09D201/00 ,  C09B1/00 ,  C09B1/34

CPC分类号： C08F290/14 ,  C08F246/00 ,  C08F283/00 ,  C08F283/008 ,  C08F290/06 ,  C08F290/061 ,  C08F290/141 ,  C09B69/101 ,  C09D4/00 ,  C09D4/06

摘要： Disclosed are thermally-stable, anthraquinone colorant compounds (dyes) which contain one or more vinyl groups which render the compounds copolymerizable with reactive vinyl monomers to produce colored, polymeric compositions such as acrylate and methacrylate polymeric materials. The compounds possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers, good color strength and excellent thermal stability. Also disclosed are (1) coating composition comprising (i) one or more polymerizable vinyl compounds, (ii) one or more of the dye compounds described above, and (iii) a photoinitiator and (2) polymeric materials, i.e., polymers derived from one or more acrylic acid esters, one or more methacrylic acid esters, one or more other polymerizable vinyl compounds or mixtures of any two or more thereof, having copolymerized therein one or more of the anthraquinone colorant compounds.

摘要翻译： 公开了热稳定的蒽醌着色剂化合物（染料），其含有一个或多个乙烯基，使得化合物与反应性乙烯基单体共聚以产生着色的聚合物组合物，例如丙烯酸酯和甲基丙烯酸酯聚合物材料。 该化合物对紫外线（UV）光具有良好的牢度（稳定性），在乙烯基单体中的良好溶解性，良好的着色强度和优异的热稳定性。 还公开了（1）涂料组合物，其包含（i）一种或多种可聚合乙烯基化合物，（ii）一种或多种上述染料化合物，和（iii）光引发剂和（2）聚合物材料，即衍生自 一种或多种丙烯酸酯，一种或多种甲基丙烯酸酯，一种或多种其它可聚合乙烯基化合物或其任何两种或多种的混合物，其中共聚有一种或多种蒽醌着色剂化合物。

公开(公告)号：US06787658B2

公开(公告)日：2004-09-07

申请号：US10719427

申请日：2003-11-21

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook ,  Jos Simon De Wit ,  Larry Keith Johnson

IPC分类号： C07C5018

CPC分类号： C08F290/14 ,  C08F246/00 ,  C08F283/00 ,  C08F283/008 ,  C08F290/06 ,  C08F290/061 ,  C08F290/141 ,  C09B69/101 ,  C09D4/00 ,  C09D4/06

摘要： Disclosed are thermally-stable, anthraquinone colorant compounds (dyes) which contain one or more vinyl groups which render the compounds copolymerizable with reactive vinyl monomers to produce colored, polymeric compositions such as acrylate and methacrylate polymeric materials. The compounds possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers, good color strength and excellent thermal stability. Also disclosed are (1) coating composition comprising (i) one or more polymerizable vinyl compounds, (ii) one or more of the dye compounds described above, and (iii) a photoinitiator and (2) polymeric materials, i.e., polymers derived from one or more acrylic acid esters, one or more methacrylic acid esters, one or more other polymerizable vinyl compounds or mixtures of any two or more thereof, having copolymerized therein one or more of the anthraquinone colorant compounds.

公开(公告)号：US07138539B2

公开(公告)日：2006-11-21

申请号：US11249793

申请日：2005-10-13

申请人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook

发明人： Michael John Cyr ,  Max Allen Weaver ,  Gerry Foust Rhodes ,  Jason Clay Pearson ,  Phillip Michael Cook

IPC分类号： C07C229/48 ,  C07D207/40

CPC分类号： C09B69/109 ,  C08F246/00 ,  C08F290/06 ,  C08F290/14 ,  C09B69/101 ,  C09B69/105 ,  C09B69/106

摘要： Disclosed are novel colorant compounds which contain one or more ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be copolymewrized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic coatings and polymers, e.g., coatings and polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for the preparation of certain of the photopolymerizable colorant compounds.