公开(公告)号：US09570700B2

公开(公告)日：2017-02-14

申请号：US14431972

申请日：2012-09-28

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/52 ,  H01L51/50 ,  H01L51/56 ,  H01L51/00

CPC分类号： H01L51/5221 ,  H01L51/0021 ,  H01L51/0078 ,  H01L51/0091 ,  H01L51/0092 ,  H01L51/5092 ,  H01L51/5231 ,  H01L51/5234 ,  H01L51/56 ,  H01L2251/305 ,  H01L2251/5315 ,  H01L2251/5353 ,  H01L2251/5369

摘要： Disclosed are an organic electroluminescent device and a preparation method thereof. The organic electroluminescent device is a top-emitting organic electroluminescent device having a reversed structure, and the preparation method is: dissolving zinc oxide with acetic acid to obtain a zinc oxide solution with a concentration of 0.3 g/ml-0.6 g/ml, adding a phthalocyanine substance in a mass of 1%-10% of the mass of the zinc oxide to obtain a mixture, spin-coating the mixture on a glass substrate (1) and then drying to obtain a cathode (2), and then preparing by vapor deposition, an electron injection layer (3), an electron transport layer (4), a luminescent layer (5), a hole transport layer (6), a hole injection layer (7) and an anode (8), successively, so as to obtain the organic electroluminescent device.

摘要翻译： 公开了一种有机电致发光器件及其制备方法。 有机电致发光器件是具有相反结构的顶发光有机电致发光器件，其制备方法是：用乙酸溶解氧化锌，得到浓度为0.3g / ml-0.6g / ml的氧化锌溶液，加入 得到质量为氧化锌质量的1％-10％的酞菁物质以获得混合物，将该混合物旋涂在玻璃基板（1）上，然后干燥以获得阴极（2），然后制备 通过气相沉积，电子注入层（3），电子传输层（4），发光层（5），空穴传输层（6），空穴注入层（7）和阳极（8） ，以获得有机电致发光器件。

公开(公告)号：US20130334688A1

公开(公告)日：2013-12-19

申请号：US14002589

申请日：2011-03-25

申请人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Hui Huang

发明人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Hui Huang

IPC分类号： H01B1/08 ,  H01L21/02 ,  H01L23/48

CPC分类号： H01B1/08 ,  C04B35/453 ,  C04B2235/3217 ,  C04B2235/3286 ,  C04B2235/3418 ,  C23C14/0057 ,  C23C14/086 ,  C23C14/3414 ,  C23C14/35 ,  H01L21/02697 ,  H01L23/48 ,  H01L2924/0002 ,  H01L2924/00

摘要： The invention relates to the semiconductor material manufacturing technical field. A multi-elements-doped zinc oxide film as well as manufacturing method and application in photo-electric devices thereof are provided. The manufacturing method comprises the following steps: (1) mixing the powder of Ga2O3, Al2O3, SiO2 and ZnO according to the following percentage by mass: 0.5%˜10% of Ga2O3, 0.5%˜5% of Al2O3, 0.5%˜1.5% of SiO2, and the residue of ZnO; (2) sintering the powder mixture as target material; (3) putting the target material into a magnetic sputtering chamber, evacuating, setting-up work pressure of 0.2 Pa-5 Pa, introducing mixed gas of inert gas and hydrogen with a flow rate of 15 sccm˜25 sccm, adopting a sputtering power of 40 W˜200 W, and sputtering on the substrate to obtain the multi-elements-doped zinc oxide film.

摘要翻译： 本发明涉及半导体材料制造技术领域。 提供多元素掺杂的氧化锌膜以及其光电装置中的制造方法和应用。 制造方法包括以下步骤：（1）按照以下的质量百分比混合Ga2O3，Al2O3，SiO2和ZnO的粉末：Ga2O3的0.5％〜10％，Al2O3的0.5％〜5％，Al2O3的0.5％〜1.5 ％的SiO 2，和ZnO的残留物; （2）将粉末混合物烧结成目标材料; （3）将目标材料放入磁性溅射室，抽真空，设定工作压力为0.2Pa-5Pa，引入惰性气体和氢气的混合气体，流速为15sccm〜25sccm，采用溅射功率 为40W〜200W，在基板上溅射，得到多元素掺杂的氧化锌膜。

公开(公告)号：US20130306951A1

公开(公告)日：2013-11-21

申请号：US13981416

申请日：2011-03-22

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/52

CPC分类号： H01L51/5218 ,  H01L51/5215 ,  H01L51/5275 ,  Y10T428/24942

摘要： An organic electroluminescent device and a conductive substrate thereof are provided. Said conductive substrate includes a glass substrate, an indium tin oxide (ITO) layer and a metal oxide layer located between said glass substrate and said ITO layer. The refractive index of said metal oxide layer ranges between that of said glass substrate and said ITO layer. Due to the metal oxide layer, the refractive index of which ranges between that of the glass substrate and the ITO layer, is inserted into said conductive substrate, when the light extracts between the ITO/metal oxide layer and the metal oxide layer/glass, the critical angle of total reflection increases compared with that without the inserted metal oxide layer. Most part of light extracts out of the interface after refraction, and only small part of light is totally reflected, thus the light extraction enhances.

摘要翻译： 提供有机电致发光器件及其导电衬底。 所述导电衬底包括玻璃衬底，氧化铟锡（ITO）层和位于所述玻璃衬底和所述ITO层之间的金属氧化物层。 所述金属氧化物层的折射率在所述玻璃基板和所述ITO层的折射率之间。 由于在ITO /金属氧化物层和金属氧化物层/玻璃之间的光提取时，由于金属氧化物层的折射率在玻璃基板和ITO层的折射率之间插入到所述导电基板中， 与没有插入的金属氧化物层的临界角相比，全反射的临界角增加。 大部分光线在折射后从界面中提取出来，只有一小部分光被全部反射，从而提高了光的提取。

公开(公告)号：US20150263285A1

公开(公告)日：2015-09-17

申请号：US14431993

申请日：2012-09-28

申请人： Mingjie ZHOU ,  Ping WANG ,  Hui HUANG ,  Jixing CHEN

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/00

CPC分类号： H01L51/0007 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/4273 ,  H01L51/441 ,  H01L51/442 ,  H01L2251/305 ,  Y02E10/549 ,  Y02P70/521

摘要： Disclosed are a polymer solar cell and a preparation method thereof. The preparation method comprises: successively preparing on a clean glass substrate (1), a cathode (2), an electronic buffer layer (3) and an active layer (4) by the steps of dissolving poly(3,4-ethylenedioxythiophene) and polymerized p-styrene sulphonic acid, dissolving zinc oxide into acetic acid to obtain a zinc oxide solution, mixing the zinc oxide solution with the solution of poly(3,4-ethylenedioxythiophene) and polymerized p-styrene sulphonic acid to obtain a mixed solution, spin-coating the mixed solution on the active layer (4) and then by drying to obtain the anode (5), and finally obtain the polymer solar cell.

摘要翻译： 公开了一种聚合物太阳能电池及其制备方法。 该制备方法包括：通过以下步骤，在干净的玻璃基板（1），阴极（2），电子缓冲层（3）和活性层（4）上依次制备聚（3,4-亚乙基二氧噻吩）和 聚合的对苯乙烯磺酸，将氧化锌溶解在乙酸中以得到氧化锌溶液，将氧化锌溶液与聚（3,4-亚乙基二氧噻吩）和聚合的对苯乙烯磺酸的溶液混合，得到混合溶液， 将混合溶液旋涂在活性层（4）上，然后通过干燥得到阳极（5），最后得到聚合物太阳能电池。

公开(公告)号：US20140326986A1

公开(公告)日：2014-11-06

申请号：US14361005

申请日：2011-11-28

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/50 ,  H01L51/00 ,  H01L51/56

CPC分类号： H01L51/5096 ,  H01L51/0035 ,  H01L51/004 ,  H01L51/0085 ,  H01L51/5012 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5268 ,  H01L51/56 ,  H01L2251/308 ,  H05B33/22

摘要： Disclosed are a polymeric electroluminescent device and a method for preparing the same. The polymeric electroluminescent device includes an anode (20), a hole injecting layer (30), a hole transportation layer (40), a light-emitting layer (50), a hole barrier layer (60), an electron transportation layer (70), an electron injecting layer (80) and a cathode (90) laminated in succession, and the material for the hole barrier layer (60) is zinc oxide, magnesium oxide, zinc sulphide or cadmium sulphide. In the polymeric electroluminescent device, zinc oxide, magnesium oxide, zinc sulphide or cadmium sulphide has a large particle size, and can scatter the light to improve extraction efficiency; at the same time, zinc oxide, magnesium oxide, zinc sulphide or cadmium sulphide has a high work function, which can excellently prevent transition of the holes and increase the recombination possibility of excitons, thereby improving the light-emitting efficiency of the polymeric electroluminescent device.

摘要翻译： 公开了一种聚合物电致发光器件及其制备方法。 聚合物电致发光器件包括阳极（20），空穴注入层（30），空穴传输层（40），发光层（50），空穴阻挡层（60），电子传输层 ），电子注入层（80）和阴极（90），空穴阻挡层（60）的材料是氧化锌，氧化镁，硫化锌或硫化镉。 在聚合物电致发光器件中，氧化锌，氧化镁，硫化锌或硫化镉具有较大的粒径，并可散射光以提高提取效率; 同时，氧化锌，氧化镁，硫化锌或硫化镉具有很高的功函数，可以极好地防止空穴的转变并增加激子的复合可能性，从而提高聚合物电致发光器件的发光效率 。

公开(公告)号：US20130186465A1

公开(公告)日：2013-07-25

申请号：US13824612

申请日：2010-09-27

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L31/0224

CPC分类号： H01L31/022425 ,  H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0035 ,  Y02E10/542 ,  Y02P70/521

摘要： The invention relates to a counter electrode for a dye-sensitized solar cell and a manufacturing method thereof. The counter electrode comprises a conductive substrate and an acid doped polyaniline layer coated on at least one surface of the conductive substrate. The conductivity of the counter electrode is increased, the recombination probability of I3− and a conduction band electron is decreased, the bond strength of the acid doped polyaniline layer and the conductive substrate is enhanced, the electronic transmission rate and the conductivity of the counter electrode for the external circuit are further increased, and the production cost is reduced. The manufacturing method can simplify the production process, produce the stable performance counter electrode, increase the production efficiency, and reduce the requirement for production equipment, thus suitable for industrial production.

摘要翻译： 本发明涉及染料敏化太阳能电池的对电极及其制造方法。 对电极包括导电衬底和涂覆在导电衬底的至少一个表面上的酸掺杂聚苯胺层。 相对电极的导电性增加，I3-和导带电子的复合概率降低，酸性聚苯胺层和导电性基体的结合强度提高，电极的透射率和电极的电导率 外部电路进一步增加，生产成本降低。 制造方法可以简化生产过程，生产稳定的对电极，提高生产效率，降低生产设备的要求，适合工业生产。

公开(公告)号：US20140319506A1

公开(公告)日：2014-10-30

申请号：US14347039

申请日：2011-11-28

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/50 ,  H01L51/00 ,  H01L51/56

CPC分类号： H01L51/506 ,  H01L51/0002 ,  H01L51/0061 ,  H01L51/0081 ,  H01L51/56

摘要： Disclosed are an organic electroluminescent device having ternary doped hole transportation layer and a preparation method therefor. The electroluminescent device comprises a conductive anode substrate (1), a ternary doped hole transportation layer (2), a light-emitting layer (3), an electron transportation layer (4), an electron injecting layer (5) and a cathode layer (6), wherein the material for the ternary doped hole transportation layer (2) is a mixed material made by doping a cerium salt and a hole transportation material into a metal compound. The electroluminescent device forms p-doping by doping the cerium salt and the hold transportation material into the metal compound, which improves the ability of injecting and transporting holes, and increases the efficiency of light emission. Since the material for the ternary doped hole transportation layer (2) is predominately a metal compound, the process difficulty and manufacturing costs are reduced, facilitating industrial production and commercial applications.

摘要翻译： 公开了具有三元掺杂孔输送层的有机电致发光器件及其制备方法。 电致发光器件包括导电阳极衬底（1），三元掺杂空穴传输层（2），发光层（3），电子传输层（4），电子注入层（5）和阴极层 （6），其中所述三元掺杂空穴传输层（2）的材料是通过将铈盐和空穴传输材料掺杂到金属化合物中而制成的混合材料。 电致发光器件通过将铈盐和保持输送材料掺杂到金属化合物中形成p掺杂，这提高了注入和传输空穴的能力，并且提高了发光效率。 由于三元掺杂孔输送层（2）的材料主要是金属化合物，所以工艺难度和制造成本降低，促进了工业生产和商业应用。

公开(公告)号：US20130240867A1

公开(公告)日：2013-09-19

申请号：US13989334

申请日：2010-11-26

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/52 ,  H01L51/56

CPC分类号： H01L51/5203 ,  H01L51/5088 ,  H01L51/5206 ,  H01L51/56

摘要： An organic electroluminescent device (OELD) and the fabrication method thereof are disclosed. The OELD comprises an anode(1), a cathode(2) opposite to the anode(1) and a light emission structure(3) between the anode(1) and the cathode(2).The OELD also comprises an insulation layer(4) between the anode(1) and the light emission structure(3) and the insulation layer(4) is attached to the anode(1).The material of the insulation layer(4) is a lithium salt compound and the thickness of the insulation layer(4) is 0.5-5 nm. The insulation layer is arranged on the anode(1) to block the velocity of holes injecting into the light emission structure(3) from the anode, thereby ensuring the consistency in the amount of holes and electrons of the light emission structure(3), highly increasing the recombination probability of electrons and holes and reducing the influence of excess holes to the emission property of the device. Therefore the emission property of the device is highly improved.

摘要翻译： 公开了一种有机电致发光器件（OELD）及其制造方法。 OELD包括阳极（1），与阳极（1）相对的阴极（2）和在阳极（1）和阴极（2）之间的发光结构（3）.OELD还包括绝缘层 4）阳极（1）和发光结构（3）之间，绝缘层（4）安装在阳极（1）上。绝缘层（4）的材料是锂盐化合物，其厚度 绝缘层（4）为0.5-5nm。 绝缘层布置在阳极（1）上以阻挡从阳极注入发光结构（3）的空穴的速度，从而确保发光结构（3）的空穴和电子的一致性， 高度增加电子和空穴的复合概率，并减少过量孔对器件发射性能的影响。 因此，器件的发射性能得到很大改善。

公开(公告)号：US20140326318A1

公开(公告)日：2014-11-06

申请号：US14361007

申请日：2011-11-28

申请人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

发明人： Mingjie Zhou ,  Ping Wang ,  Hui Huang ,  Jixing Chen

IPC分类号： H01L51/00 ,  H01L51/44

CPC分类号： H01L51/0037 ,  H01L51/0003 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/0047 ,  H01L51/0067 ,  H01L51/007 ,  H01L51/0072 ,  H01L51/4253 ,  H01L51/426 ,  H01L51/4273 ,  H01L51/44 ,  H01L2051/0063 ,  H01L2251/301 ,  Y02E10/549

摘要： Provided are a polymer solar cell (100) and a method for preparing the same. The solar cell (100) comprises the following structures: a conductive anode substrate (10), a hole buffer layer (20), an active layer (30), an electron transportation layer (40) and a cathode (50); and the material for the electron transportation layer (40) is an electron transportation material doped with a cerium salt and metal particles. The solar cell (100) effectively increases the rate of electron transportation, and decreases the potential barrier between the electron transportation layer (40) and the cathode (50).

摘要翻译： 提供聚合物太阳能电池（100）及其制备方法。 太阳能电池（100）包括以下结构：导电阳极基板（10），空穴缓冲层（20），有源层（30），电子传输层（40）和阴极（50） 并且电子传输层（40）的材料是掺杂有铈盐和金属颗粒的电子传输材料。 太阳能电池（100）有效地增加电子传输速率，并降低电子传输层（40）和阴极（50）之间的势垒。

公开(公告)号：US20140145114A1

公开(公告)日：2014-05-29

申请号：US14130228

申请日：2011-06-28

申请人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Hui Huang

发明人： Mingjie Zhou ,  Ping Wang ,  Jixing Chen ,  Hui Huang

IPC分类号： H01S5/30 ,  C23C14/35 ,  C23C14/08

CPC分类号： H01S5/3018 ,  C09K11/7718 ,  C09K11/7768 ,  C23C14/081 ,  C23C14/35 ,  H05B33/14

摘要： Cerium doped magnesium barium tungstate luminescent thin film, manufacturing method and application thereof are provided, said method for manufacturing cerium doped magnesium barium tungstate luminescent thin film comprises the following steps: mixing MgO, BaO, WO3 and Ce2O3, sintering for forming sputtering target, forming the precursor of cerium doped magnesium barium tungstate luminescent thin film by magnetron sputtering, annealing the precursor of cerium doped magnesium barium tungstate luminescent thin film, and then forming cerium doped magnesium barium tungstate luminescent thin film. Said cerium doped magnesium barium tungstate luminescent thin film exhibits high luminescence efficiency and high light emitting peaks in red and blue regions. Said method presents the advantages of simplified operation, less cost, and suitable for industrial preparation.

摘要翻译： 提供铈掺杂的钡钡钨酸盐发光薄膜，其制造方法和应用，所述制造铈掺杂的钡钡钨酸盐发光薄膜的方法包括以下步骤：将MgO，BaO，WO 3和Ce 2 O 3混合，烧结以形成溅射靶，形成 通过磁控溅射法铈铈掺杂镁钡钨酸盐发光薄膜的前体，对铈掺杂的钡钡钨酸盐发光薄膜进行退火，然后形成铈掺杂的钡钡钨酸盐发光薄膜。 所述铈掺杂的钡钡钨酸盐发光薄膜在红色和蓝色区域表现出高发光效率和高发光峰。 所述方法具有操作简单，成本低，适用于工业制备的优点。