摘要:
A method of producing hydrogen in which oxygen is separated from an oxygen containing stream to produce an oxygen permeate which is mixed with a hydrocarbon containing stream and steam. Steam, one or more hydrocarbons and permeated oxygen is reacted to produce a synthesis gas. Hydrogen is separated from the synthesis gas by a hydrogen transport membrane to produce a hydrogen permeate which after cooling is used to form a hydrogen product stream. The hydrogen-depleted crude synthesis gas is then combusted to heat the incoming oxygen containing feed.
摘要:
An oxygen separator and method for separating oxygen from a heated oxygen containing gas that employs oxygen-selective ceramic membranes of elongated, tubular configuration within a duct for separation of oxygen from a heated gas. The duct can be attached between the exhaust of a gas turbine and a power generator driven by the exhaust or can be connected to one or more burners of a gas turbine. Supplementary compressed feed air may be added at a flow rate at least equal to that of the permeated oxygen for cooling and flow balancing purposes. A purge stream can also be introduced. Additionally, combustor tubes fabricated from an oxygen-selective ceramic membrane material may also be provided to produce combustion products that in turn can be used as a purge for downstream oxygen-selective ceramic membranes.
摘要:
An oxygen separator and method for separating oxygen from a heated oxygen containing gas that employs oxygen-selective ceramic membranes of elongated, tubular configuration within a duct for separation of oxygen from a heated gas. The duct can be attached between the exhaust of a gas turbine and a power generator driven by the exhaust or can be connected to one or more burners of a gas turbine. Supplementary compressed feed air may be added at a flow rate at least equal to that of the permeated oxygen for cooling and flow balancing purposes. A purge stream can also be introduced. Additionally, combustor tubes fabricated from an oxygen-selective ceramic membrane material may also be provided to produce combustion products that in turn can be used as a purge for downstream oxygen-selective ceramic membranes.
摘要:
A method of separating oxygen from an oxygen containing gas with a composite membrane capable of conducting oxygen ions and electrons. In accordance with the method, the composite membrane is subjected to an operational temperature and the oxygen containing gas at a cathode side thereof. The composite membrane has a dense layer, at least one active porous layer contiguous to the dense layer, and at least one porous support layer. The active porous layer has a thickness and a distribution of pore radii. The distribution of pore radii has a standard deviation from a theoretical radius that would produce a maximum operation flux through the thickness when the thickness is about equal to a product of a constant and the square root of the theoretical radius. The constant is a function of a material used to fabricate the active porous layer, the operational temperature and an oxygen partial pressure within the active porous layer, and a porosity and a tortuosity produced by the pore radii. The standard deviation of the log of the theoretical radius is equal to a product of 1.45 and a shape factor, the shape factor being greater than 0 and no greater than about 0.5.
摘要:
An ion transport reactor and process for using same having at least one ion transport membrane with a retentate side and a permeate side, for extracting oxygen from a feed gas stream as it flows along the retentate side. A reactant gas stream is flowed along the permeate side of the ion transport tubes to react with the oxygen transported therethrough. Heat is transferred to a fluid stream flowing through the ion transport reactor while the temperature of the membrane is maintained within its operating range.
摘要:
A method of firing a heat consuming device such as a boiler or furnace in which an oxygen transport membrane is integrated with the device such that part of the permeated oxygen supports an initial combustion to heat the incoming air to the oxygen transport membrane system. A remaining portion of the oxygen after having been diluted with flue gases from the boiler supports a secondary combustion of fuel within the heat consuming device.
摘要:
A process for producing an oxidized product in conjunction with a turbine for generating power. This process comprises contacting a compressed and heated oxygen-containing gas stream with at least one solid electrolyte oxygen selective ion transport membrane in a membrane reactor. A reactant is passed into the reactor to generate an oxidized product therefrom. Oxygen-depleted retentate stream from the reactor is added to a gas turbine combustor and expanded in a gas turbine to generate power.
摘要:
A process for separating a feed gas stream into an oxygen-enriched gas stream which is used in a combustor and an oxygen-depleted gas stream. The feed gas stream is compressed, and oxygen is separated from the compressed feed gas stream using an ion transport module including an ion transport membrane having a retentate side and a permeate side. The permeate side of the ion transport membrane is purged with at least a portion of a combustion product gas stream obtained from the combustion in the combustor of the gas stream exiting the permeate side of the ion transport module.
摘要:
A compressed, oxygen-containing gas stream is combusted and then contacted with a solid electrolyte membrane to produce an oxygen-depleted, compressed gas stream and product oxygen. Preferably, the oxygen-depleted gas stream is further combusted, used to produce steam, and/or used to preheat the oxygen-containing gas stream prior to expansion in a gas turbine.
摘要:
A process for inhibiting the formation of carbon and/or coke from a carbon-containing reactive gas stream on the permeate side of an oxygen ion transport membrane, or for increasing the oxygen partial pressure thereon, by separating a feed gas stream to form an oxygen-depleted gas stream on the retentate side and a gas stream containing oxygen reaction products on the permeate side. The permeate side is purged with the carbon-containing reactive gas stream, and at least a portion of the exhaust gas stream formed from the reaction of the reactive gas stream with the separated oxygen is recirculated to purge the permeate side.