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公开(公告)号:US06783750B2
公开(公告)日:2004-08-31
申请号:US09933901
申请日:2001-08-22
申请人: Minish Mahendra Shah , Raymond Francis Drnevich , Christian Friedrich Gottzmann , Bart Antonie van Hassel
发明人: Minish Mahendra Shah , Raymond Francis Drnevich , Christian Friedrich Gottzmann , Bart Antonie van Hassel
IPC分类号: C01B324
CPC分类号: C01B3/38 , C01B13/0251 , C01B2203/0205 , C01B2203/0244 , C01B2203/0405 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2210/0046 , Y02P20/128 , Y02P20/129
摘要: A method of producing hydrogen in which oxygen is separated from an oxygen containing stream to produce an oxygen permeate which is mixed with a hydrocarbon containing stream and steam. Steam, one or more hydrocarbons and permeated oxygen is reacted to produce a synthesis gas. Hydrogen is separated from the synthesis gas by a hydrogen transport membrane to produce a hydrogen permeate which after cooling is used to form a hydrogen product stream. The hydrogen-depleted crude synthesis gas is then combusted to heat the incoming oxygen containing feed.
摘要翻译: 一种生产氢的方法,其中将氧与含氧流分离以产生与含烃流和蒸汽混合的氧气渗透物。 蒸汽,一种或多种烃和渗透的氧反应产生合成气。 通过氢输送膜将氢气与合成气分离以产生氢气渗透物,其在冷却用于形成氢产物流之后。 然后将贫氢粗合成气燃烧以加热进入的含氧进料。
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公开(公告)号:US07856829B2
公开(公告)日:2010-12-28
申请号:US11639459
申请日:2006-12-15
申请人: Minish Mahendra Shah , Aqil Jamal , Raymond Francis Drnevich , Bart Antonie van Hassel , Gervase Maxwell Christie , Hisashi Kobayashi , Lawrence E. Bool, III
发明人: Minish Mahendra Shah , Aqil Jamal , Raymond Francis Drnevich , Bart Antonie van Hassel , Gervase Maxwell Christie , Hisashi Kobayashi , Lawrence E. Bool, III
IPC分类号: F02C6/18
CPC分类号: B01D53/75 , B01D53/77 , B01D2256/22 , B01D2257/302 , B01D2257/80 , B01D2259/40 , C01B13/0251 , C01B2210/0046 , C10J3/06 , C10J3/466 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/1606 , C10J2300/1671 , C10J2300/1675 , C10J2300/1678 , C10J2300/1687 , C10J2300/1838 , C10J2300/1876 , C10J2300/1892 , C10K1/004 , C10K1/024 , C10K3/005 , F01K23/068 , F23J2215/20 , F23J2215/50 , F23L2900/07005 , Y02C10/06 , Y02E20/18 , Y02E20/344
摘要: A method of generating electrical power in which a synthesis gas stream generated in a gasifier is combusted in an oxygen transport membrane system of a boiler. The combustion generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.
摘要翻译: 一种产生电力的方法,其中在气化器中产生的合成气流在锅炉的氧输送膜系统中燃烧。 燃烧产生热量以升高蒸汽,从而通过耦合到蒸汽轮机的发电机产生电力。 所得烟道气可以被纯化以产生二氧化碳产物。
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公开(公告)号:US06623714B2
公开(公告)日:2003-09-23
申请号:US09871956
申请日:2001-06-04
申请人: Eric Hunter Shreiber , Edward Paul Eardley , Vijayaraghavan Srinivasan , Bart Antonie van Hassel , Minish Mahendra Shah
发明人: Eric Hunter Shreiber , Edward Paul Eardley , Vijayaraghavan Srinivasan , Bart Antonie van Hassel , Minish Mahendra Shah
IPC分类号: B01D5322
CPC分类号: B01D53/228 , B01D53/22 , C01B13/0251 , C01B2210/0046 , C01B2210/0062 , Y02P20/129
摘要: A method of separating oxygen using a ceramic membrane unit having one or more ceramic membranes, preferably formed of a mixed conducting ceramic, for instance, a perovskite, capable of conducting both oxygen ions and electrons. Oxygen is separated within the ceramic membrane unit under impetus of compressing an incoming oxygen containing feed. The compressor used in the compression is powered by the work of expansion produced by expanding a process stream composed of at least a portion of the retentate produced in the ceramic membrane unit. Prior to expansion, the process stream is cooled to allow the use of less expensive materials in expanders used in the expansion. As a result, expansion of the process stream alone is insufficient to meet the power requirements involved in the compression. Interstage expansion with reheating is used to make up for the power deficit.
摘要翻译: 使用具有一个或多个陶瓷膜的陶瓷膜单元的分离方法,该陶瓷膜优选由能够导电氧离子和电子的混合导电陶瓷,例如钙钛矿形成。 在压缩进入含氧进料的动力下,陶瓷膜单元内的氧气分离。 在压缩机中使用的压缩机由通过膨胀由陶瓷膜单元中产生的至少一部分滞留物组成的工艺流而产生的膨胀作用来提供动力。 在膨胀之前,将工艺流冷却以允许在膨胀器中使用的膨胀器中使用较便宜的材料。 因此,单独的工艺流的扩展不足以满足压缩中涉及的功率要求。 再加热阶段的扩张用来弥补电力赤字。
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公开(公告)号:US08196387B2
公开(公告)日:2012-06-12
申请号:US12948128
申请日:2010-11-17
申请人: Minish Mahendra Shah , Aqil Jamal , Raymond Francis Dmevich , Bart Antonie van Hassel , Gervase Maxwell Christie , Hisashi Kobayashi , Lawrence E. Bool, III
发明人: Minish Mahendra Shah , Aqil Jamal , Raymond Francis Dmevich , Bart Antonie van Hassel , Gervase Maxwell Christie , Hisashi Kobayashi , Lawrence E. Bool, III
IPC分类号: F02C3/26
CPC分类号: B01D53/75 , B01D53/77 , B01D2256/22 , B01D2257/302 , B01D2257/80 , B01D2259/40 , C01B13/0251 , C01B2210/0046 , C10J3/06 , C10J3/466 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/1606 , C10J2300/1671 , C10J2300/1675 , C10J2300/1678 , C10J2300/1687 , C10J2300/1838 , C10J2300/1876 , C10J2300/1892 , C10K1/004 , C10K1/024 , C10K3/005 , F01K23/068 , F23J2215/20 , F23J2215/50 , F23L2900/07005 , Y02C10/06 , Y02E20/18 , Y02E20/344
摘要: An apparatus for generating electrical power in which a synthesis gas stream generated in a gasifier is partially oxidized, expanded and thereafter, is combusted in an oxygen transport membrane system of a boiler. The combustion generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.
摘要翻译: 一种用于产生电力的装置,其中在气化器中产生的合成气流被部分氧化,膨胀,然后在锅炉的氧输送膜系统中燃烧。 燃烧产生热量以升高蒸汽,从而通过耦合到蒸汽轮机的发电机产生电力。 所得烟道气可以被纯化以产生二氧化碳产物。
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公开(公告)号:US20080141672A1
公开(公告)日:2008-06-19
申请号:US11639459
申请日:2006-12-15
申请人: Minish Mahendra Shah , Aqil Jamal , Raymond Francis Dmevich , Bart Antonie van Hassel , Gervase Maxwell Christie , Hisashi Kobayashi , Lawrence E. Bool
发明人: Minish Mahendra Shah , Aqil Jamal , Raymond Francis Dmevich , Bart Antonie van Hassel , Gervase Maxwell Christie , Hisashi Kobayashi , Lawrence E. Bool
CPC分类号: B01D53/75 , B01D53/77 , B01D2256/22 , B01D2257/302 , B01D2257/80 , B01D2259/40 , C01B13/0251 , C01B2210/0046 , C10J3/06 , C10J3/466 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/1606 , C10J2300/1671 , C10J2300/1675 , C10J2300/1678 , C10J2300/1687 , C10J2300/1838 , C10J2300/1876 , C10J2300/1892 , C10K1/004 , C10K1/024 , C10K3/005 , F01K23/068 , F23J2215/20 , F23J2215/50 , F23L2900/07005 , Y02C10/06 , Y02E20/18 , Y02E20/344
摘要: A method of generating electrical power in which a synthesis gas stream generated in a gasifier is combusted in an oxygen transport membrane system of a boiler. The combustion generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.
摘要翻译: 一种产生电力的方法,其中在气化器中产生的合成气流在锅炉的氧输送膜系统中燃烧。 燃烧产生热量以升高蒸汽,从而通过耦合到蒸汽轮机的发电机产生电力。 所得烟道气可以被纯化以产生二氧化碳产物。
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公开(公告)号:US20110061361A1
公开(公告)日:2011-03-17
申请号:US12948128
申请日:2010-11-17
申请人: Minish Mahendra SHAH , Aqil Jamal , Raymond Francis Dmevich , Bart Antonie van Hassel , Gervase Maxwell Christie , Hisashi Kobayashi , Lawrence E. Bool, III
发明人: Minish Mahendra SHAH , Aqil Jamal , Raymond Francis Dmevich , Bart Antonie van Hassel , Gervase Maxwell Christie , Hisashi Kobayashi , Lawrence E. Bool, III
IPC分类号: F02G3/00
CPC分类号: B01D53/75 , B01D53/77 , B01D2256/22 , B01D2257/302 , B01D2257/80 , B01D2259/40 , C01B13/0251 , C01B2210/0046 , C10J3/06 , C10J3/466 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/1606 , C10J2300/1671 , C10J2300/1675 , C10J2300/1678 , C10J2300/1687 , C10J2300/1838 , C10J2300/1876 , C10J2300/1892 , C10K1/004 , C10K1/024 , C10K3/005 , F01K23/068 , F23J2215/20 , F23J2215/50 , F23L2900/07005 , Y02C10/06 , Y02E20/18 , Y02E20/344
摘要: An apparatus for generating electrical power in which a synthesis gas stream generated in a gasifier is partially oxidized, expanded and thereafter, is combusted in an oxygen transport membrane system of a boiler. The combustion generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.
摘要翻译: 一种用于产生电力的装置,其中在气化器中产生的合成气流被部分氧化,膨胀,然后在锅炉的氧输送膜系统中燃烧。 燃烧产生热量以升高蒸汽,从而通过耦合到蒸汽轮机的发电机产生电力。 所得烟道气可以被纯化以产生二氧化碳产物。
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公开(公告)号:US5820655A
公开(公告)日:1998-10-13
申请号:US848204
申请日:1997-04-29
申请人: Christian Friedrich Gottzmann , Ravi Prasad , Victor Emmanuel Bergsten , Nitin Ramesh Keskar , Bart Antonie van Hassel
发明人: Christian Friedrich Gottzmann , Ravi Prasad , Victor Emmanuel Bergsten , Nitin Ramesh Keskar , Bart Antonie van Hassel
CPC分类号: C01B13/0255 , B01D53/22 , B01D53/326 , B01D63/062 , B01J12/007 , B01J19/2425 , B01J19/2475 , C01B13/0251 , B01D2313/42 , B01J2219/00081 , B01J2219/00085 , B01J2219/0015 , B01J2219/00155 , C01B2210/0046 , C01B2210/0082
摘要: An ion transport reactor and process for using same having at least one ion transport membrane with a retentate side and a permeate side, for extracting oxygen from a feed gas stream as it flows along the retentate side. A reactant gas stream is flowed along the permeate side of the ion transport tubes to react with the oxygen transported therethrough. Heat is transferred to a fluid stream flowing through the ion transport reactor while the temperature of the membrane is maintained within its operating range.
摘要翻译: 离子迁移反应器及其使用方法,其具有至少一个具有滞留侧和渗透侧的离子迁移膜,用于当其沿着渗余物侧流动时从进料气流中提取氧气。 反应物气流沿离子输送管的渗透侧流动,以与从其中输送的氧气反应。 将热量转移到流过离子迁移反应器的流体流中,同时膜的温度保持在其工作范围内。
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公开(公告)号:US08323463B2
公开(公告)日:2012-12-04
申请号:US12968699
申请日:2010-12-15
CPC分类号: B01D71/024 , B01D53/228 , B01D69/12 , B01D2325/021 , B01D2325/10 , C01B13/0255 , C01B2210/0046
摘要: A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
摘要翻译: 一种复合氧传输膜,其具有致密层,多孔载体层和位于致密层和多孔载体层之间的中间多孔层。 致密层和中间多孔层都由离子导电材料形成以导电氧离子和导电材料以导电。 多孔支撑层具有高渗透性,高孔隙率和高平均孔径,并且中间多孔层具有比多孔载体层更低的渗透性和更低的孔直径。 被选择用于促进可燃物质的氧化的催化剂颗粒位于中间多孔层和邻近中间多孔层的多孔载体中。 可以通过将催化剂前体的溶液通过多孔载体向中间多孔层芯吸而形成催化剂颗粒。
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公开(公告)号:US07556676B2
公开(公告)日:2009-07-07
申请号:US11507486
申请日:2006-08-22
申请人: Nagendra Nagabhushana , Jonathan Andrew Lane , Gervase Maxwell Christie , Bart Antonie van Hassel
发明人: Nagendra Nagabhushana , Jonathan Andrew Lane , Gervase Maxwell Christie , Bart Antonie van Hassel
IPC分类号: B01D53/22
CPC分类号: H01M4/8621 , B01D53/228 , B01D69/12 , B01D69/141 , B01D71/02 , B01D2257/104 , B01D2323/12 , B01D2325/02 , B01D2325/04 , B01D2325/26 , C01B13/0255 , C04B35/42 , C04B35/486 , C04B35/488 , C04B35/636 , C04B38/00 , C04B2111/00612 , C04B2111/00801 , C04B2235/3213 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3239 , C04B2235/3243 , C04B2235/3246 , C04B2235/3262 , C04B2235/3275 , C04B2235/422 , C04B2235/5445 , C04B2235/77 , C04B2235/80 , H01M4/8657 , H01M4/9016 , H01M4/9025 , H01M8/1246 , H01M8/1253 , H01M8/126 , H01M2300/0074 , H01M2300/0077 , H01M2300/0094 , Y02E60/525 , Y02P70/56 , C04B35/48 , C04B38/0054 , C04B38/0074
摘要: A composite oxygen ion transport membrane having a dense layer, a porous support layer, an optional intermediate porous layer located between the porous support layer and the dense layer and an optional surface exchange layer, overlying the dense layer. The dense layer has electronic and ionic phases. The ionic phase is composed of scandia doped, yttrium or cerium stabilized zirconia. The electronic phase is composed of a metallic oxide containing lanthanum, strontium, chromium, manganese and vanadium and optionally cerium. The porous support layer is composed of zirconia partially stabilized with yttrium, scandium, aluminum or cerium or mixtures thereof. The intermediate porous layer, if used, contains the same ionic and electronic phases as the dense layer. The surface exchange layer is formed of an electronic phase of a metallic oxide of lanthanum and strontium that also contains either manganese or iron and an ionic phase of scandia doped zirconia stabilized with yttrium or cerium.
摘要翻译: 具有致密层的复合氧离子传输膜,多孔载体层,位于多孔载体层和致密层之间的任选的中间多孔层和覆盖致密层的任选的表面交换层。 致密层具有电子和离子相。 离子相由掺杂钪,钇或铈稳定的氧化锆组成。 电子相由含有镧,锶,铬,锰和钒的金属氧化物和任选的铈组成。 多孔支撑层由用钇,钪,铝或铈部分稳定的氧化锆或其混合物组成。 如果使用中间多孔层,则包含与致密层相同的离子和电子相。 表面交换层由还含有锰或铁的镧和锶金属氧化物的电子相以及用钇或铈稳定的掺杂氧化钪的离子相形成。
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公开(公告)号:US20080047431A1
公开(公告)日:2008-02-28
申请号:US11507486
申请日:2006-08-22
申请人: Nagendra Nagabhushana , Jonathan Andrew Lane , Gervase Maxwell Christie , Bart Antonie van Hassel
发明人: Nagendra Nagabhushana , Jonathan Andrew Lane , Gervase Maxwell Christie , Bart Antonie van Hassel
IPC分类号: B01D53/22
CPC分类号: H01M4/8621 , B01D53/228 , B01D69/12 , B01D69/141 , B01D71/02 , B01D2257/104 , B01D2323/12 , B01D2325/02 , B01D2325/04 , B01D2325/26 , C01B13/0255 , C04B35/42 , C04B35/486 , C04B35/488 , C04B35/636 , C04B38/00 , C04B2111/00612 , C04B2111/00801 , C04B2235/3213 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3239 , C04B2235/3243 , C04B2235/3246 , C04B2235/3262 , C04B2235/3275 , C04B2235/422 , C04B2235/5445 , C04B2235/77 , C04B2235/80 , H01M4/8657 , H01M4/9016 , H01M4/9025 , H01M8/1246 , H01M8/1253 , H01M8/126 , H01M2300/0074 , H01M2300/0077 , H01M2300/0094 , Y02E60/525 , Y02P70/56 , C04B35/48 , C04B38/0054 , C04B38/0074
摘要: A composite oxygen ion transport membrane having a dense layer, a porous support layer, an optional intermediate porous layer located between the porous support layer and the dense layer and an optional surface exchange layer, overlying the dense layer. The dense layer has electronic and ionic phases. The ionic phase is composed of scandia doped, yttrium or cerium stabilized zirconia. The electronic phase is composed of a metallic oxide containing lanthanum, strontium, chromium, manganese and vanadium and optionally cerium. The porous support layer is composed of zirconia partially stabilized with yttrium, scandium, aluminum or cerium or mixtures thereof. The intermediate porous layer, if used, contains the same ionic and electronic phases as the dense layer. The surface exchange layer is formed of an electronic phase of a metallic oxide of lanthanum and strontium that also contains either manganese or iron and an ionic phase of scandia doped zirconia stabilized with yttrium or cerium.
摘要翻译: 具有致密层的复合氧离子传输膜,多孔载体层,位于多孔载体层和致密层之间的任选的中间多孔层和覆盖致密层的任选的表面交换层。 致密层具有电子和离子相。 离子相由掺杂钪,钇或铈稳定的氧化锆组成。 电子相由含有镧,锶,铬,锰和钒的金属氧化物和任选的铈组成。 多孔支撑层由用钇,钪,铝或铈部分稳定的氧化锆或其混合物组成。 如果使用中间多孔层,则包含与致密层相同的离子和电子相。 表面交换层由还含有锰或铁的镧和锶金属氧化物的电子相以及用钇或铈稳定的掺杂氧化钪的离子相形成。
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