Oxygen separation method using a ceramic membrane unit
    3.
    发明授权
    Oxygen separation method using a ceramic membrane unit 失效
    氧分离法采用陶瓷膜单元

    公开(公告)号:US06623714B2

    公开(公告)日:2003-09-23

    申请号:US09871956

    申请日:2001-06-04

    IPC分类号: B01D5322

    摘要: A method of separating oxygen using a ceramic membrane unit having one or more ceramic membranes, preferably formed of a mixed conducting ceramic, for instance, a perovskite, capable of conducting both oxygen ions and electrons. Oxygen is separated within the ceramic membrane unit under impetus of compressing an incoming oxygen containing feed. The compressor used in the compression is powered by the work of expansion produced by expanding a process stream composed of at least a portion of the retentate produced in the ceramic membrane unit. Prior to expansion, the process stream is cooled to allow the use of less expensive materials in expanders used in the expansion. As a result, expansion of the process stream alone is insufficient to meet the power requirements involved in the compression. Interstage expansion with reheating is used to make up for the power deficit.

    摘要翻译: 使用具有一个或多个陶瓷膜的陶瓷膜单元的分离方法,该陶瓷膜优选由能够导电氧离子和电子的混合导电陶瓷,例如钙钛矿形成。 在压缩进入含氧进料的动力下,陶瓷膜单元内的氧气分离。 在压缩机中使用的压缩机由通过膨胀由陶瓷膜单元中产生的至少一部分滞留物组成的工艺流而产生的膨胀作用来提供动力。 在膨胀之前,将工艺流冷却以允许在膨胀器中使用的膨胀器中使用较便宜的材料。 因此,单独的工艺流的扩展不足以满足压缩中涉及的功率要求。 再加热阶段的扩张用来弥补电力赤字。

    Catalyst containing oxygen transport membrane
    8.
    发明授权
    Catalyst containing oxygen transport membrane 有权
    含氧传输膜的催化剂

    公开(公告)号:US08323463B2

    公开(公告)日:2012-12-04

    申请号:US12968699

    申请日:2010-12-15

    摘要: A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

    摘要翻译: 一种复合氧传输膜,其具有致密层,多孔载体层和位于致密层和多孔载体层之间的中间多孔层。 致密层和中间多孔层都由离子导电材料形成以导电氧离子和导电材料以导电。 多孔支撑层具有高渗透性,高孔隙率和高平均孔径,并且中间多孔层具有比多孔载体层更低的渗透性和更低的孔直径。 被选择用于促进可燃物质的氧化的催化剂颗粒位于中间多孔层和邻近中间多孔层的多孔载体中。 可以通过将催化剂前体的溶液通过多孔载体向中间多孔层芯吸而形成催化剂颗粒。