摘要:
The present invention relates to a method of preparing an ethylene polymerization catalyst, which comprises reacting a solid reaction product of magnesium halide (such as magnesium chloride), alcohol, an organic magnesium compound, and a halogen compound with a transition metal compound and an electron donor. When ethylene and a-olefin are co-polymerized by slurry polymerization in the presence of the above catalyst, the amount of wax component extracted by the polymerization solvent is very low, and the polymer particles do not agglomerate. The catalyst is prepared in the form of so uniform particles that the resultant polymer has uniform particle morphology, thus increasing bulk density.
摘要:
Disclosed are an ethylene polymerization process, a catalyst for use in the process, a production method employing the catalyst, and a product produced thereby. More specifically, disclosed is a process of producing an ethylene copolymer from ethylene and an alpha-olefin comonomer, in which the produced ethylene copolymer has a multimodal molecular weight distribution and excellent processability and physical properties, and thus can increase the value and productivity of products, including pipes and films. Particularly, the produced ethylene copolymer has a trimodal or higher molecular weight distribution or density distribution, and thus, when it is a linear low-density copolymer, it has an excellent effect of improving the impact strength of films, and when it is a medium-density ethylene copolymer, it can be produced into pipes, which have slow crack growth rate and can be used even at high temperature.
摘要:
Disclosed are an ethylene polymerization process, a catalyst for use in the process, a production method employing the catalyst, and a product produced thereby. More specifically, disclosed is a process of producing an ethylene copolymer from ethylene and an alpha-olefin comonomer, in which the produced ethylene copolymer has a multimodal molecular weight distribution and excellent processability and physical properties, and thus can increase the value and productivity of products, including pipes and films. Particularly, the produced ethylene copolymer has a trimodal or higher molecular weight distribution or density distribution, and thus, when it is a linear low-density copolymer, it has an excellent effect of improving the impact strength of films, and when it is a medium-density ethylene copolymer, it can be produced into pipes, which have slow crack growth rate and can be used even at high temperature.
摘要:
Disclosed are an ethylene polymerization process, a catalyst for use in the process, a production method employing the catalyst, and a product produced thereby. More specifically, disclosed is a process of producing an ethylene copolymer from ethylene and an alpha-olefin comonomer, in which the produced ethylene copolymer has a multimodal molecular weight distribution and excellent processability and physical properties, and thus can increase the value and productivity of products, including pipes and films. Particularly, the produced ethylene copolymer has a trimodal or higher molecular weight distribution or density distribution, and thus, when it is a linear low-density copolymer, it has an excellent effect of improving the impact strength of films, and when it is a medium-density ethylene copolymer, it can be produced into pipes, which have slow crack growth rate and can be used even at high temperature.
摘要:
Disclosed herein is a group IV transition metal catalyst for producing an ethylene homopolymer or an ethylene-olefin copolymers, having high catalytic activity, which includes a cyclopentadiene derivative and one or more anionic ligands having an aryl group substituted with an aryl derivative at an ortho-position thereof around a transition metal, the ligands not being crosslinked to each other, a catalyst system including the group IV transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst, and a method of producing ethylene homopolymers or ethylene-olefin copolymers using the catalyst system.
摘要:
Disclosed herein is a group IV transition metal catalyst for producing an ethylene homopolymer or an ethylene-olefin copolymers, having high catalytic activity, which includes a cyclopentadiene derivative and one or more anionic ligands having an aryl group substituted with an aryl derivative at an ortho-position thereof around a transition metal, the ligands not being crosslinked to each other, a catalyst system including the group IV transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst, and a method of producing ethylene homopolymers or ethylene-olefin copolymers using the catalyst system.
摘要:
Disclosed are an ethylene polymerization process, a catalyst for use in the process, a production method employing the catalyst, and a product produced thereby. More specifically, disclosed is a process of producing an ethylene copolymer from ethylene and an alpha-olefin comonomer, in which the produced ethylene copolymer has a multimodal molecular weight distribution and excellent processability and physical properties, and thus can increase the value and productivity of products, including pipes and films. Particularly, the produced ethylene copolymer has a trimodal or higher molecular weight distribution or density distribution, and thus, when it is a linear low-density copolymer, it has an excellent effect of improving the impact strength of films, and when it is a medium-density ethylene copolymer, it can be produced into pipes, which have slow crack growth rate and can be used even at high temperature.
摘要:
Provided is a method for improving thermal stability of polypropylene carbonate and, more particularly, a method of end capping a molecular chain of polypropylene carbonate using a urethane group by adding isocyanates or diisocyanates to a polypropylene carbonate resin, which may optionally be a mixture containing tertiary polyol, so as to delay thermal degradation of the polypropylene carbonate at a high temperature, thereby securing desired thermal stability. Especially, the method capable of being easily applied to reactive extrusion after preparing the polypropylene carbonate has been proposed, thus simplifying production processes and ensuring economical advantages. Moreover, the above method does not deteriorate transparency and specific smoke density characteristics at combustion, which are advantages of the polypropylene carbonate.
摘要:
Provided is an eco-friendly poly(propylene carbonate) resin composition for a sheet, which is characterized by using a poly(alkylene carbonate) resin developed by efficiently utilizing carbon dioxide, which is a major contributor to global warding, as a main material, and including appropriate additives, such as, a strength modifier, and a flexibilizer, thereby completely solving environmental hazards controversy of the existing polyvinyl chloride resin products; exhibiting excellent mechanical and thermal properties, processability, post processability (printability, embossing and surface treatment, laminating characteristics) and superior anti-flaming property (low smoke density) and elongation characteristics as compared with the existing polyvinyl chloride resin products; and overcoming an extruding production method which is a small-sized production manner, corresponding to a big defect in thermoplastic plastics emerged as substitutes for polyvinyl chloride resin products and thus applying a calendering process method which is a mass production manner.
摘要:
Provided is an eco-friendly rotogravure hot melt ink composition. More specifically, the present invention provides the rotogravure hot melt ink composition meeting requirements of a carbon footprint system by using, as a vehicle, poly propylene carbonate prepared using carbon dioxide as a raw material. The rotogravure hot melt ink prepared by the composition of the present invention has a higher printing density and more easily performs printing at low temperature than a poly vinyl acetate based hot melt ink according to the related art.