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1.
公开(公告)号:US20200255730A1
公开(公告)日:2020-08-13
申请号:US16733633
申请日:2020-01-03
Applicant: NICHIA CORPORATION
Inventor: Sadakazu WAKUI , Kazuya NISHIMATA , Shoji HOSOKAWA
Abstract: Disclosed are a production method for a nitride fluorescent material, a nitride fluorescent material and a light emitting device. The production method is for producing a nitride fluorescent material that has, as a fluorescent material core, a calcined body having a composition containing at least one element Ma selected from the group consisting of Sr, Ca, Ba and Mg, at least one element Mb selected from the group consisting of Li, Na and K, at least one element Mc selected from the group consisting of Eu, Ce, Tb and Mn, and Al, and optionally Si, and N, and the method includes preparing a calcined body having the above-mentioned composition, bringing the calcined body into contact with a fluorine-containing substance, and subjecting it to a first heat treatment at a temperature of 100° C. or higher and 500° C. or lower to form a fluoride-containing first film on the calcined body, and forming on the calcined body, a second film that contains a metal oxide containing at least one metal element M2 selected from the group consisting of Si, Al, Ti, Zr, Sn and Zn and subjecting it to a second heat treatment at a temperature in a range of higher than 250° C. and 500° C. or lower.
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2.
公开(公告)号:US20190062633A1
公开(公告)日:2019-02-28
申请号:US16117514
申请日:2018-08-30
Applicant: NICHIA CORPORATION
Inventor: Sadakazu WAKUI , Kazuya NISHIMATA , Shoji HOSOKAWA
CPC classification number: C09K11/7734 , H01L33/502 , H01L33/504 , H01L2933/0041
Abstract: Disclosed are a production method for a nitride fluorescent material, a nitride fluorescent material and a light emitting device. The production method is for producing a nitride fluorescent material that has, as a fluorescent material core, a calcined body having a composition containing at least one element Ma selected from the group consisting of Sr, Ca, Ba and Mg, at least one element Mb selected from the group consisting of Li, Na and K, at least one element Mc selected from the group consisting of Eu, Ce, Tb and Mn, and Al, and optionally Si, and N, and the method includes preparing a calcined body having the above-mentioned composition, bringing the calcined body into contact with a fluorine-containing substance, and subjecting it to a first heat treatment at a temperature of 100° C. or higher and 500° C. or lower to form a fluoride-containing first film on the calcined body, and forming on the calcined body, a second film that contains a metal oxide containing at least one metal element M2 selected from the group consisting of Si, Al, Ti, Zr, Sn and Zn and subjecting it to a second heat treatment at a temperature in a range of higher than 250° C. and 500° C. or lower.
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公开(公告)号:US20240209256A1
公开(公告)日:2024-06-27
申请号:US18394693
申请日:2023-12-22
Applicant: NICHIA CORPORATION
Inventor: Sadakazu WAKUI , Kohei KUNIMOTO , Hiroyuki WATANABE , Eishi KANAI
CPC classification number: C09K11/0883 , C09K11/77347
Abstract: A method of producing a nitride fluorescent material includes preparing a calcined product including a fluorescent material core, and a first film containing fluoride on a surface of the fluorescent material core, bringing the calcined product into contact with a solution containing a metal alkoxide containing an element M2 being at least one element selected from the group consisting of Si, Al, Ti, Zr, Sn, and Zn at a temperature equal to or lower than an ambient temperature and hydrolyzing and condensation-polymerizing the metal alkoxide to form a second film containing an oxide containing the element M2, and performing a heat-treatment at a temperature higher than 250° C. and equal to or lower than 500° C. The nitride fluorescent material includes the fluorescent material core having a composition containing an element Ma being at least one element selected from the group consisting of Sr, Ca, Ba, and Mg, an element Mb being at least one element selected from the group consisting of Li, Na, and K, an element Mc being at least one element selected from the group consisting of Eu, Ce, Tb, and Mn, Al, N, and optionally Si.
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公开(公告)号:US20210289711A1
公开(公告)日:2021-09-23
申请号:US17263608
申请日:2019-07-26
Applicant: NICHIA CORPORATION
Inventor: Mika MATSUMOTO , Kazushige FUJIO , Sadakazu WAKUI , Tomokazu SUZUKI , Masato FUJIWARA , Munetake FUKUNAGA
Abstract: An output of light suitable for growing plants is controlled using a white light source.
A growing system including a greenhouse and a plurality of lighting devices disposed above a plant to be grown in the greenhouse and utilizing natural light includes a plurality of white light sources, a plurality of auxiliary light sources each of which is configured to emit red light and far-red light, and an illumination controller configured to control a degree of emission of light from the white light sources or the auxiliary light sources of the plurality of lighting devices, the illumination controller configured to start or stop controlling emission of light from the white light sources or the auxiliary light sources according to sunrise or sunset.-
公开(公告)号:US20200287098A1
公开(公告)日:2020-09-10
申请号:US16880532
申请日:2020-05-21
Applicant: NICHIA CORPORATION
Inventor: Mika AMIYA , Kazushige FUJIO , Sadakazu WAKUI
IPC: H01L33/50 , A01G7/04 , H01L25/075
Abstract: A light emitting device includes a light emitting element having an emission peak wavelength in a range of 380 nm or more and 490 nm or less, and a red fluorescent material which is excited by the light from the light emitting element to emit light having at least one light emission peak wavelength in a range of 580 nm or more and 680 nm or less, wherein a ratio of the photon flux R of red light in a range of 620 nm or more and 700 nm or less to the photon flux B of blue light in a range of 400 nm or more and 490 nm or less, R/B, is in a range of more than 20 and 200 or less.
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6.
公开(公告)号:US20180187075A1
公开(公告)日:2018-07-05
申请号:US15910735
申请日:2018-03-02
Applicant: NICHIA CORPORATION
Inventor: Tomokazu YOSHIDA , Shoji HOSOKAWA , Sadakazu WAKUI , Toshiyuki OKAZAKI
CPC classification number: C09K11/617 , H01L33/504 , H01L2224/32245 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2224/73265 , H01L2924/181 , H01L2924/00012 , H01L2924/00014 , H01L2924/00
Abstract: A method for producing a fluoride fluorescent material including: preparing a first solution containing manganese, a second solution containing at least one cation selected from the group consisting of K+, Li+, Na+, Rb+, Cs+, and NH4+, and a third solution containing at least one element selected from the group consisting of the elements from Groups 4 and 14 of the periodic table, and adding the first and third solutions dropwise, each at a rate of 0.3% or less of the total volume of the solution per minute to the second solution to obtain particles having a composition represented by formula (I): A2[M1-aMn4+aF6] (I) wherein A denotes at least one cation selected from the group consisting of K+, Li+, Na+, Rb+, Cs+, and NH4+; M denotes at least one element selected from the group consisting of the elements from Groups 4 and 14 of the periodic table; and a satisfies 0.04
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7.
公开(公告)号:US20180072948A9
公开(公告)日:2018-03-15
申请号:US15347038
申请日:2016-11-09
Applicant: NICHIA CORPORATION
Inventor: Sadakazu WAKUI , Shoji HOSOKAWA
CPC classification number: C09K11/7734 , C09K11/0883 , H01L33/32 , H01L33/486 , H01L33/504 , H01L33/56 , H01L33/62 , H01L2224/32245 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2224/73265 , H01L2924/181 , H01L2933/0041 , H01L2924/00014 , H01L2924/00012 , H01L2924/00
Abstract: A method of producing a nitride fluorescent material having a high light emission intensity and including a calcined product having a composition represented by formula MavMbwMcxMdyNz is provided. Ma is at least one element selected from Sr, Ca, Ba, and Mg; Mb is at least one element selected from Li, Na, and K; Mc is at least one element selected from Eu, Mn, Tb, and Ce; Md is at least one element selected from Al, B, Ga, and In; v, w, x, y, and z satisfy 0.8≦v≦1.1, 0.8≦w≦1.1, 0.001
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公开(公告)号:US20180057739A1
公开(公告)日:2018-03-01
申请号:US15683262
申请日:2017-08-22
Applicant: NICHIA CORPORATION
Inventor: Sadakazu WAKUI , Shoji HOSOKAWA
CPC classification number: C09K11/7734 , C09K11/025 , C09K11/0883 , H01L33/502 , H01L33/504 , H01L33/507
Abstract: A nitride fluorescent material containing at least one element selected from the group consisting of Ca, Sr, Ba and Mg, at least one element selected from the group consisting of Li, Na and K, at least one element selected from the group consisting of Eu, Ce, Tb and Mn, Al and N is provided, wherein when the maximum value of absorbance in 450 cm−1 or more and less than 900 cm−1 is taken as 1 in an FT-IR spectrum, an integrated value Z1 of a domain surrounded by a base line A connecting absorbance values at 1,200 cm−1 and 1,600 cm−1 and an absorbance spectrum of 1,200 cm−1 or more and less than 1,600 cm−1 is 4.0 or less, and/or an integrated value Z2 of a domain surrounded by a base line B connecting absorbance values at 2,700 cm−1 and 3,680 cm−1 and an absorbance spectrum of 2,700 cm−1 or more and less than 3,680 cm−1 is 5.0 or less.
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9.
公开(公告)号:US20170250320A1
公开(公告)日:2017-08-31
申请号:US15440479
申请日:2017-02-23
Applicant: NICHIA CORPORATION
Inventor: Sadakazu WAKUI , Tadayoshi YANAGIHARA , Shoji HOSOKAWA
CPC classification number: H01L33/502 , C09K11/0883 , C09K11/7734 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2224/73265 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
Abstract: A method of producing a nitride fluorescent material is provided. The nitride fluorescent material undergoes less change in chromaticity under a high-temperature and high-humidity condition and are excellent in durability. The nitride fluorescent material has a composition containing: at least one element selected from the group consisting of Ca, Sr, Ba, and Mg; at least one element selected from the group consisting of Li, Na, and K; at least one element selected from the group consisting of Eu, Ce, Tb, and Mn; Al; and N. The method includes: preparing a calcined product having the composition, bringing the calcined product in contact with a fluorine-containing substance, and heat-treating the calcined product at a temperature of 200° C. or more and 500° C. or less. A light emitting device using the nitride fluorescent material is also provided.
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10.
公开(公告)号:US20170130126A1
公开(公告)日:2017-05-11
申请号:US15347038
申请日:2016-11-09
Applicant: NICHIA CORPORATION
Inventor: Sadakazu WAKUI , Shoji HOSOKAWA
CPC classification number: C09K11/7734 , C09K11/0883 , H01L33/32 , H01L33/486 , H01L33/504 , H01L33/56 , H01L33/62 , H01L2224/32245 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2224/73265 , H01L2924/181 , H01L2933/0041 , H01L2924/00014 , H01L2924/00012 , H01L2924/00
Abstract: A method of producing a nitride fluorescent material having a high light emission intensity and including a calcined product having a composition represented by formula MavMbwMcxMdyNz is provided. Ma is at least one element selected from Sr, Ca, Ba, and Mg; Mb is at least one element selected from Li, Na, and K; Mc is at least one element selected from Eu, Mn, Tb, and Ce; Md is at least one element selected from Al, B, Ga, and In; v, w, x, y, and z satisfy 0.8≦v≦1.1, 0.8≦w≦1.1, 0.001
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