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公开(公告)号:US20240227354A1
公开(公告)日:2024-07-11
申请号:US18288208
申请日:2021-04-27
Applicant: NIPPON STEEL CORPORATION
Inventor: Takuya MITSUNOBU , Keitaro MATSUDA , Jun MAKI , Takehiro TAKAHASHI , Hiroshi TAKEBAYASHI
CPC classification number: B32B15/011 , B32B7/14 , B32B37/0084 , C22C38/02 , C22C38/06 , B32B2255/06 , B32B2255/205
Abstract: A steel welded member comprising a plurality of Zn-based plated steel materials, each having a Zn-based plating layer on a surface of a steel material, joined together through at least one spot weld, wherein the steel material contains, by mass %, C: 0.05 to 0.40%, Si: 0.2 to 3.0%, and Mn: 0.1 to 5.0%, the steel welded member includes, by area ratio, 20 to 80% of a Γ phase (Fe3 Zn1 0) and at least one oxide with a long axis of 0.5 μm or more in a region up to 0.5 mm from an end part of a pressure weld of the spot weld.
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公开(公告)号:US20240002991A1
公开(公告)日:2024-01-04
申请号:US18041919
申请日:2021-08-19
Applicant: NIPPON STEEL CORPORATION
Inventor: Takuya MITSUNOBU , Makoto AKAHOSHI , Hiroshi TAKEBAYASHI , Takehiro TAKAHASHI
IPC: C23C2/06 , C22C18/04 , C22C38/02 , C22C38/04 , C22F1/16 , C22F1/02 , C21D9/46 , C21D6/00 , C21D1/84 , C21D1/74 , B32B15/01 , C23C2/28
CPC classification number: C23C2/06 , C22C18/04 , C22C38/02 , C22C38/04 , C22F1/165 , C22F1/02 , C21D9/46 , C21D6/005 , C21D6/008 , C21D1/84 , C21D1/74 , B32B15/013 , C23C2/29
Abstract: This hot-dip Zn-based plated steel sheet includes a steel sheet and a plating layer formed on at least part of a surface of the steel sheet, in which the plating layer has a chemical composition that includes, by mass %, Al: 6.00% to 35.00%, Mg: 2.00% to 12.00%, Ca: 0.005% to 2.00%, Si: 0% to 2.00%, Fe: 0% to 2.00%, Sb: 0% to 0.50%, Sr: 0% to 0.50%, Pb: 0% to 0.50%, Sn: 0% to 1.00%, Cu: 0% to 1.00%, Ti: 0% to 1.00%, Ni: 0% to 1.00%, Mn: 0% to 1.00%, Cr: 0% to 1.00%, and a remainder: Zn and impurities, the plating layer has an area ratio of a MgZn2 phase in a range of 15% to 60% in a cross section in a thickness direction, and the MgZn2 phase includes a Ca-based intermetallic compound having a circle equivalent diameter of 0.10 μm or smaller.
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公开(公告)号:US20240001423A1
公开(公告)日:2024-01-04
申请号:US18252541
申请日:2022-01-14
Applicant: NIPPON STEEL CORPORATION
Inventor: Takuya MITSUNOBU , Hiroshi TAKEBAYASHI , Takehiro TAKAHASHI
CPC classification number: B21D22/022 , C23C2/04 , C22C38/002 , C22C38/02 , C22C30/06
Abstract: This hot stamped member includes: a steel; and a plating layer formed on the steel, in which the plating layer has a predetermined chemical composition, the plating layer contains a Zn-based oxide including one or two of a Zn oxide and a Zn—Mg oxide having a size of 1.0 μm or more and 10.0 μm or less in a thickness direction of the plating layer and 0.1 μm or more in a direction perpendicular to the thickness direction, and in a cross section of the plating layer in the thickness direction, when a length of an interface between the plating layer and the steel is indicated as Le, a sum of lengths of the Zn-based oxide projected onto the interface from an upper surface of the plating layer is indicated as ΣLi, and a sum of lengths of portions of the Zn-based oxide in contact with the plating layer projected onto the interface from the upper surface of the plating layer is indicated as ΣLai, ΣLi/Le≥0.10 and ΣLai/ΣLi≥0.50 are satisfied.
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公开(公告)号:US20240084833A1
公开(公告)日:2024-03-14
申请号:US18271402
申请日:2021-12-24
Applicant: NIPPON STEEL CORPORATION
Inventor: Takuya MITSUNOBU , Hiroshi TAKEBAYASHI , Takehiro TAKAHASHI
Abstract: The present disclosure inhibits liquid metal embrittlement (LME) cracking and improves corrosion resistance in a welded joint obtained by spot welding a first steel sheet and a second steel sheet. In the welded joint of the present disclosure, a first plating layer is provided on a surface of the first steel sheet facing the second steel sheet, no plating layer is present on or a second plating layer is provided on a surface of the second steel sheet facing the first steel sheet, a boundary plating layer is provided between the first steel sheet and the second steel sheet in a range of 0.5 mm from an end part of the corona bond of the spot welded part toward an outside of the spot welded part, and a Zn penetrated part is present at least at one of the first steel sheet and the second steel sheet adjoining the boundary plating layer. The Zn penetrated part advances from the boundary plating layer along the steel grain boundary, an Mg concentration at a front end of the Zn penetrated part at a location where a Zn concentration is 0.1 mass % is 0.20 mass % or less, and the first plating layer and the second plating layer satisfy a predetermined Relation I.
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公开(公告)号:US20230407448A1
公开(公告)日:2023-12-21
申请号:US18251629
申请日:2022-01-14
Applicant: NIPPON STEEL CORPORATION
Inventor: Takuya MITSUNOBU , Hiroshi TAKEBAYASHI , Takehiro TAKAHASHI
IPC: C23C2/06 , C22C21/10 , C22C38/02 , C22C38/04 , C21D9/46 , C21D1/74 , C21D1/84 , C21D8/02 , C22C21/02 , C22C21/00 , B32B15/01
CPC classification number: C23C2/06 , C22C21/10 , C22C38/02 , C22C38/04 , C21D9/46 , C21D1/74 , C21D1/84 , C21D8/0205 , C21D8/0278 , C22C21/02 , C22C21/00 , B32B15/011 , C21D2251/02 , C21D2261/00 , B23K11/11
Abstract: This plated steel includes: a steel; and a plating layer formed on the steel, in which the plating layer contains, as a chemical composition, by mass %, Zn: 1.0% to 30.0%, Mg: 0% to 10.0%, Si: 0.05% to 10.0%, Fe: 0 to 10.0%, 0% to 5.00% in total of one or two or more selected from Ca: 0% to 3.00%, Sb: 0% to 0.50%, Pb: 0% to 0.50%, Sr: 0% to 0.50%, Sn: 0% to 1.00%, Cu: 0% to 1.00%, Ti: 0% to 1.00%, Ni: 0% to 1.00%, Mn: 0% to 1.00%, Cr: 0% to 1.00%, La: 0% to 1.00%, Ce: 0% to 1.00%, Zr: 0% to 1.00%, and Hf: 0% to 1.00%, and a remainder of Al and impurities, a microstructure of the plating layer contains an α phase which is a solid solution of Al and Zn, and the α phase contains a Zn phase having a grain size of 10 to 200 nm in a number density of 10/100 μm2 or more.
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公开(公告)号:US20220403539A1
公开(公告)日:2022-12-22
申请号:US17776465
申请日:2019-12-20
Applicant: NIPPON STEEL CORPORATION
Inventor: Yasuto GOTO , Kiyokazu ISHIZUKA , Takehiro TAKAHASHI
Abstract: A Ni-plated steel sheet includes a base steel sheet and a Ni-based coating layer that is disposed on a surface of the base steel sheet. The distribution of carbon concentration in a depth direction obtained by performing GDS analysis on the Ni-plated steel sheet has a peak indicating the carbon concentration that is equal to or more than twice the carbon concentration of a thickness middle portion of the base steel sheet in the vicinity of an interface between the base steel sheet and the Ni-based coating layer.
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公开(公告)号:US20220213607A1
公开(公告)日:2022-07-07
申请号:US17606974
申请日:2020-05-29
Applicant: NIPPON STEEL CORPORATION
Inventor: Akinobu KOBAYASHI , Takehiro TAKAHASHI , Yasuaki KAWAMURA
Abstract: The present invention relates to a hot stamped body comprising a steel sheet and a plating layer formed on at least one surface of the steel sheet, wherein the plating layer is comprised of a. ZnO region present on a surface side of the plating layer and having an oxygen concentration of 10 mass % or more and an Ni—Fe—Zn alloy region present on a steel sheet side of the plating layer and having an oxygen concentration of less than 10 mass %, and an average concentration of a total of Fe, Mn and Si in the ZnO region is more than 0 mass % and less than 5 mass %.
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公开(公告)号:US20210269932A1
公开(公告)日:2021-09-02
申请号:US17254714
申请日:2019-07-05
Applicant: NIPPON STEEL CORPORATION
Inventor: Takehiro TAKAHASHI , Mamoru SAITO , Kiyokazu ISHIZUKA , Yasuto GOTO
IPC: C25D5/12 , C25D3/12 , C21D9/46 , C22C38/00 , C22C38/02 , C22C38/04 , C22C38/06 , H01M50/119 , H01M50/124
Abstract: A surface-treated steel sheet of the present invention includes a base steel sheet and a Ni—Co—Fe alloy-plated layer on at least one surface of the base steel sheet, in which, in the alloy-plated layer, a Ni coating weight is 7.1 to 18.5 g/m2, a Co coating weight is 0.65 to 3.6 g/m2, and a total of the Ni coating weight and the Co coating weight is in a range of 9.0 to 20.0 g/m2. In a surface layer of the alloy-plated layer, a Co concentration is in a range of 20 to 60 atom %, and a Fe concentration is in a range of 5 to 30 atom %. In the alloy-plated layer, a region having a thickness of 2 μm or more, in which a total of a Ni concentration and the Co concentration is 10 atom % or more and the Fe concentration is 5 atom % or more, is present. The base steel sheet has a predetermined chemical composition, and a ferrite grain size number is 10 or more.
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公开(公告)号:US20210025071A1
公开(公告)日:2021-01-28
申请号:US16968087
申请日:2019-02-06
Applicant: NIPPON STEEL CORPORATION
Inventor: Mamoru SAITO , Takehiro TAKAHASHI , Kiyokazu ISHIZUKA
Abstract: To provide a surface-treated steel sheet for battery containers excellent in workability while maintaining battery characteristics and liquid leakage resistance, and a manufacturing method thereof. A surface-treated steel sheet for battery containers according to the present invention includes a Ni—Co—Fe-based diffusion alloy plating layer on at least one surface of a base steel sheet, in which the diffusion alloy plating layer is consisted of a Ni—Fe alloy layer and a Ni—Co—Fe alloy layer, which are arranged sequentially from the base steel sheet side, the diffusion alloy plating layer has a Ni coating weight within a range of 3.0 g/m2 or more and less than 8.74 g/m2 and a Co coating weight within a range of 0.26 g/m2 or more and 1.6 g/m2 or less, with a total of the Ni coating weight and the Co coating weight being less than 9.0 g/m2, when a surface of the diffusion alloy plating layer is analyzed by an X-ray photoelectron spectroscopy, Co: 19.5 to 60%, Fe: 0.5 to 30%, and Co+Fe: 20 to 70% in atom % are satisfied, and a thickness of the Ni—Fe alloy layer is within a range of 0.3 to 1.3 μm.
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公开(公告)号:US20240326381A1
公开(公告)日:2024-10-03
申请号:US18702221
申请日:2022-11-11
Applicant: NIPPON STEEL CORPORATION
Inventor: Misaki ASADA , Hiroki FUJIMOTO , Takehiro TAKAHASHI
IPC: B32B15/01 , B23K9/23 , B23K26/00 , B23K103/04 , B23K103/08 , C25D3/12
CPC classification number: B32B15/015 , B23K9/23 , B23K26/0006 , B23K2103/04 , B23K2103/08 , C25D3/12
Abstract: To obtain a welded member using a steel sheet less expensive than a pure Ni sheet as a raw material and excellent in corrosion resistance. A welded member according to the present invention is made by connecting a Ni plated steel sheet having a Ni plating layer and a Fe—Ni diffusion alloy layer and another steel sheet via a welded part, wherein: a Ni concentration is 70 mass % or more and a Fe concentration is 30 mass % or less in a surface layer of each of a toe, a toe near area, and the welded part; and a thickness of the Fe—Ni diffusion alloy layer is 0.5 to 1.5 μm and a total thickness of the Ni plating layer and the Fe—Ni diffusion alloy layer is 2.7 to 14.0 μm at a non-welded part, and a total concentration of S and C in the Ni plating layer at the non-welded part is less than 20 ppm.
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