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公开(公告)号：US20130202895A1
公开(公告)日：2013-08-08
申请号：US13805159
申请日：2011-06-17
IPC分类号： C09D1/00
CPC分类号： C09D1/00 , C03C17/007 , C03C2217/42 , C03C2217/425 , C03C2217/732 , C08G77/58 , C09D183/14 , G02B1/113 , H01L31/02168 , Y02E10/50
摘要： The invention relates to a coating composition comprising an inorganic oxide precursor AMOx based on at least one inorganic element A selected from the group consisting of aluminum, silicium, titanium, zirconium, niobium, indium, tin, antimony, tantalum, and bismuth; and an inorganic oxide precursor BMOx based on at least one inorganic element B selected from the group consisting of scandium, yttrium, lanthanum, and the lanthanoids; wherein AMOx and BMOx are capable of forming a mixed inorganic oxide. A coating made from this composition shows enhanced resistance to hydrolysis. The invention also relates to a process for applying a coating on a substrate using such composition, more specifically to a liquid coating composition for use in a process of applying an anti-reflective coating on transparent substrate; to a coated substrate obtained with such process, and to an article, like a solar panel, comprising such coated substrate.
摘要翻译： 本发明涉及包含基于选自铝，硅，钛，锆，铌，铟，锡，锑，钽和铋中的至少一种无机元素A的无机氧化物前体AMOx的涂料组合物; 和基于至少一种选自钪，钇，镧和镧系元素的无机元素B的无机氧化物前体BMOx; 其中AMOx和BMOx能够形成混合的无机氧化物。 由该组合物制成的涂层显示出增强的抗水解性。 本发明还涉及使用这种组合物涂覆在基材上的方法，更具体地说涉及用于在透明基材上施加抗反射涂层的方法中的液体涂料组合物; 涉及由这种方法获得的涂布基材，以及包含这种涂布的基材的诸如太阳能电池板的制品。
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公开(公告)号：US09605156B2
公开(公告)日：2017-03-28
申请号：US13805159
申请日：2011-06-17
IPC分类号： C09D1/00 , C03C17/00 , C08G77/58 , C09D183/14 , G02B1/113 , H01L31/0216
CPC分类号： C09D1/00 , C03C17/007 , C03C2217/42 , C03C2217/425 , C03C2217/732 , C08G77/58 , C09D183/14 , G02B1/113 , H01L31/02168 , Y02E10/50
摘要： The invention relates to a coating composition comprising an inorganic oxide precursor AMOx based on at least one inorganic element A selected from the group consisting of aluminum, silicium, titanium, zirconium, niobium, indium, tin, antimony, tantalum, and bismuth; and an inorganic oxide precursor BMOx based on at least one inorganic element B selected from the group consisting of scandium, yttrium, lanthanum, and the lanthanoids; wherein AMOx and BMOx are capable of forming a mixed inorganic oxide. A coating made from this composition shows enhanced resistance to hydrolysis. The invention also relates to a process for applying a coating on a substrate using such composition, more specifically to a liquid coating composition for use in a process of applying an anti-reflective coating on transparent substrate; to a coated substrate obtained with such process, and to an article, like a solar panel, comprising such coated substrate.
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公开(公告)号：US20110002831A1
公开(公告)日：2011-01-06
申请号：US12808014
申请日：2008-12-15
IPC分类号： C01F17/00 , C01B13/00 , C01F11/02 , C01F7/00 , C01G23/04 , C01G19/02 , C01G25/02 , C01G31/02 , C01G33/00 , C01G35/00 , C01G37/02 , C01G39/02 , C01G41/02 , C01G45/02 , C01G49/02 , C01G51/04 , C01G53/04 , C01G9/02 , C01G11/00
CPC分类号： C03C1/008 , C03C17/009 , C03C23/0005 , C04B35/624 , C08K3/22 , C08L33/14 , C08L2207/53 , C09D7/61 , C09D7/65
摘要： A sol-gel process for preparing a mixture of metal-oxide-metal compounds wherein at least one metal oxide precursor is subjected to a hydrolysis treatment to obtain one or more corresponding metal oxide hydroxides, the metal oxide hydroxides so obtained are subjected to a condensation treatment to form the metal-oxide-metal compounds, which process is carried out in the presence of an encapsulated catalyst, whereby the catalytically active species is released from the encapsulating unit by exposure to an external stimulus, and wherein the catalytically active species released after exposure to such external stimulus is capable of catalyzing the condensation of the metal-hydroxide groups that are present in the metal oxide hydroxides so obtained.
摘要翻译： 用于制备金属氧化物 - 金属化合物的混合物的溶胶 - 凝胶法，其中至少一种金属氧化物前体进行水解处理以获得一种或多种相应的金属氧化物氢氧化物，所得金属氧化物氢氧化物经过冷凝 处理以形成金属氧化物 - 金属化合物，该方法在包封的催化剂的存在下进行，其中催化活性物质通过暴露于外部刺激从包封单元中释放，并且其中催化活性物质在 暴露于这种外部刺激能够催化如此获得的金属氧化物氢氧化物中存在的金属氢氧根基团的缩合。
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公开(公告)号：US20100015433A1
公开(公告)日：2010-01-21
申请号：US12438596
申请日：2007-09-05
申请人： Nanning Joerg Arfsten , Steven Armes , Pascal Jozef Paul Buskens , Jens Christoph Thies , Patrick Wilhelmus Antonius Vrijaldenhoven
发明人： Nanning Joerg Arfsten , Steven Armes , Pascal Jozef Paul Buskens , Jens Christoph Thies , Patrick Wilhelmus Antonius Vrijaldenhoven
CPC分类号： A61K9/5089 , A61K9/501 , C08K3/36 , C08K9/00 , C08K9/02 , C08K9/10 , C08K9/12 , C08K2201/011 , C08K2201/013 , C08L53/00 , C08L2207/53 , C09D7/70 , G02B1/111 , Y10T428/254 , Y10T428/2998
摘要： The present invention relates to a composition suitable for forming an optical coating, the composition comprising core-shell nanoparticles, wherein said nanoparticles comprise: (a) core material comprising polymer; and (b) shell material comprising metal oxide.
摘要翻译： 本发明涉及一种适用于形成光学涂层的组合物，该组合物包含核 - 壳纳米颗粒，其中所述纳米颗粒包含：（a）包含聚合物的芯材; 和（b）包含金属氧化物的壳材料。
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公开(公告)号：US09855219B2
公开(公告)日：2018-01-02
申请号：US12438596
申请日：2007-09-05
申请人： Nanning Joerg Arfsten , Steven Armes , Pascal Jozef Paul Buskens , Jens Christoph Thies , Patrick Wilhelmus Antonius Vrijaldenhoven
发明人： Nanning Joerg Arfsten , Steven Armes , Pascal Jozef Paul Buskens , Jens Christoph Thies , Patrick Wilhelmus Antonius Vrijaldenhoven
CPC分类号： A61K9/5089 , A61K9/501 , C08K3/36 , C08K9/00 , C08K9/02 , C08K9/10 , C08K9/12 , C08K2201/011 , C08K2201/013 , C08L53/00 , C08L2207/53 , C09D7/70 , G02B1/111 , Y10T428/254 , Y10T428/2998
摘要： The present invention relates to a composition suitable for forming an optical coating, the composition comprising core-shell nanoparticles, wherein said nanoparticles comprise: (a) core material comprising polymer; and (b) shell material comprising metal oxide.
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公开(公告)号：US20110262734A1
公开(公告)日：2011-10-27
申请号：US13123911
申请日：2009-10-14
CPC分类号： G02B1/111 , B05D3/007 , C08K7/22 , C09D1/00 , C09D5/006 , C09D133/00 , C09D183/04 , G02B1/18 , G02B2207/107 , Y10T428/249972 , C08L2666/54
摘要： The present invention relates to a particle having a core and a shell, said core being hollow or comprising an organic polymer composition and said shell comprising an inorganic oxide. The shell has a thickness in the range from 2 to 75 nm and has at least one and no more than five enlarged pores, each enlarged pore having a diameter of between 5 nm and 300 nm.
摘要翻译： 本发明涉及具有芯和壳的颗粒，所述芯是中空的或包含有机聚合物组合物，所述壳包含无机氧化物。 壳体的厚度在2至75nm的范围内，并且具有至少一个且不超过五个扩大的孔，每个扩大的孔具有5nm至300nm的直径。
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公开(公告)号：US20110021335A1
公开(公告)日：2011-01-27
申请号：US12747975
申请日：2008-12-15
CPC分类号： C04B41/4537 , C03C1/008 , C03C17/009 , C03C23/0005 , C03C2218/111 , C03C2218/113 , C04B41/009 , C04B41/81 , C08K3/22 , C08K5/0008 , C09D7/61 , C09D7/63 , C04B35/00
摘要： The invention provides a sol-gel process for preparing a mixture of metal-oxide-metal compounds wherein at least one metal oxide precursor is subjected to a hydrolysis treatment to obtain one or more corresponding metal oxide hydroxides, the metal oxide hydroxides so obtained are subjected to a condensation treatment to form the metal-oxide-metal compounds, which process is carried out in the presence of a catalyst which comprises a labile protecting group (P9) and a base (B) which are covalently linked, whereby the covalent link between the protecting group and the base is cleavable by exposure to an external stimulus, and wherein the base released after exposure to such external stimulus is capable of catalyzing the condensation of the metal-hydroxide groups that are present in the metal oxide hydroxides so obtained.
摘要翻译： 本发明提供了一种用于制备金属氧化物 - 金属化合物的混合物的溶胶 - 凝胶法，其中至少一种金属氧化物前体进行水解处理以获得一种或多种相应的金属氧化物氢氧化物，所得到的金属氧化物氢氧化物 进行缩合处理以形成金属氧化物 - 金属化合物，该方法在包含不稳定保护基（P9）和共价连接的碱（B）的催化剂的存在下进行，由此共价连接 保护基和碱可以通过暴露于外部刺激而被切割，并且其中在暴露于这种外部刺激之后释放的碱能够催化如此获得的金属氧化物氢氧化物中存在的金属氢氧根的缩合。
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公开(公告)号：US20140058042A1
公开(公告)日：2014-02-27
申请号：US14008310
申请日：2012-03-29
IPC分类号： C08F8/16
CPC分类号： C08F8/16 , C08F283/01 , C08K5/0025 , C08K5/098 , C08K5/14 , C08K5/1535 , C08L67/06
摘要： The present invention relates to an unsaturated polyester resin composition comprising (a) an unsaturated polyester, (b) a vinyl group containing organic compound as reactive diluent and (c) a transition metal compound, wherein the resin composition comprises (d) a compound according to formula (1) as reactive diluent whereby n=0-3; R1 and R2 each individually represent H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl or C7-C20 arylalkyl; X=O, S or NR3 whereby R3=H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl, C7-C20 arylalkyl, part of a polymer chain or attached to a polymer chain, and the composition comprises at least one transition metal compound (c) selected from the group consisting of Co, Cu, Mn and Fe compounds; and the resin composition comprises, as vinyl group containing organic compound (b), styrene, a styrene derivative, a vinyl ether, a vinyl amine, a vinyl amide or a mixture of at least two of these compounds
摘要翻译： 本发明涉及不饱和聚酯树脂组合物，其包含（a）不饱和聚酯，（b）含乙烯基的有机化合物作为反应性稀释剂和（c）过渡金属化合物，其中树脂组合物包含（d） （1）作为反应性稀释剂，由此n = 0-3; R1和R2各自独立地表示H，C1-C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基或C7-C20芳基烷基; X = O，S或NR 3，其中R3 = H，C1-C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基，C7-C20芳基烷基，或连接到聚合物链的聚合物链的一部分， 所述组合物包含至少一种选自Co，Cu，Mn和Fe化合物的过渡金属化合物（c）; 并且树脂组合物包含作为含乙烯基的有机化合物（b），苯乙烯，苯乙烯衍生物，乙烯基醚，乙烯基胺，乙烯基酰胺或这些化合物中的至少两种的混合物
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公开(公告)号：US20140073742A1
公开(公告)日：2014-03-13
申请号：US14008385
申请日：2012-03-29
IPC分类号： C08F283/01 , C08K5/14
CPC分类号： C08F283/01 , C08K5/0025 , C08K5/101 , C08K5/14 , C08K5/1535 , C08K5/18 , C08K5/3415 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin compositions comprising (a) an unsaturated polyester, (b) a vinyl group containing organic compound as reactive diluent and (c) a tertiary aromatic amine, wherein the resin composition further comprises (d) a compound according to formula (1) as reactive diluent whereby n=0-3; R1 and R2 each individually represent H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl or C7-C20 arylalkyl; X=O, S or NR3 whereby R3=H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl, C7-C20 arylalkyl, part of a polymer chain or attached to a polymer chain, and the resin composition comprises, as vinyl group containing organic compound (b), styrene, a styrene derivative, a vinyl ether, a vinyl amine or vinyl amide or a mixture of at least two of these compounds.
摘要翻译： 本发明涉及不饱和聚酯树脂组合物，其包含（a）不饱和聚酯，（b）含乙烯基的有机化合物作为反应性稀释剂和（c）叔芳香胺，其中树脂组合物还包含（d） （1）作为反应性稀释剂，由此n = 0-3; R1和R2各自独立地表示H，C1-C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基或C7-C20芳基烷基; X = O，S或NR 3，其中R3 = H，C1-C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基，C7-C20芳基烷基，或连接到聚合物链的聚合物链的一部分， 树脂组合物包含作为含乙烯基的有机化合物（b），苯乙烯，苯乙烯衍生物，乙烯基醚，乙烯胺或乙烯基酰胺或这些化合物中的至少两种的混合物。
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公开(公告)号：US20140066581A1
公开(公告)日：2014-03-06
申请号：US14007650
申请日：2012-03-29
IPC分类号： C08F224/00
CPC分类号： C08F224/00 , C08F220/00 , C08F283/01
摘要： The present invention relates to a process for radically curing a composition comprising a methacrylate containing compound (a1) and a monomer copolymerizable with said methacrylate containing compound in the presence of a 5 transition metal compound (c) and a peroxide, wherein the composition comprises a compound (b) according to formula (1) as monomer copolymerizable with said methacrylate containing compound whereby n=0-3; R1 and R2 each individually represent H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl or C7-C20 arylalkyl; X=O, S or NR3 whereby R3=H, C1C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl, C7-C20 arylalkyl, part of a polymer chain or attached to a polymer chain, and the composition comprises at least one transition metal compound (c) selected from the group consisting of Co, Cu, Mn and Fe compounds, and the curing is effected in the presence of a peroxide selected from the group consisting of hydroperoxides, perketals, peresters, percarbonates and mixtures thereof.
摘要翻译： 本发明涉及一种在5过渡金属化合物（c）和过氧化物的存在下自由基固化包含含甲基丙烯酸酯化合物（a1）和可与所述含甲基丙烯酸酯化合物共聚的单体的组合物的方法，其中组合物包含 作为可与所述含甲基丙烯酸酯化合物共聚的单体的根据式（1）的化合物（b），其中n = 0-3; R1和R2各自独立地表示H，C1-C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基或C7-C20芳基烷基; X = O，S或NR 3，由此R3 = H，C1C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基，C7-C20芳基烷基，或连接到聚合物链的聚合物链的一部分， 包含至少一种选自Co，Cu，Mn和Fe化合物的过渡金属化合物（c），并且在选自以下的过氧化物的存在下进行固化：选自氢过氧化物，庚酮，过酸酯，过碳酸盐和 其混合物。
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