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公开(公告)号:US08841227B2
公开(公告)日:2014-09-23
申请号:US12863467
申请日:2008-12-22
IPC分类号: B01J29/06 , B01J37/08 , C07C2/76 , B01J35/00 , B01J29/076 , B01J29/48 , B01J37/00 , B01J21/06
CPC分类号: B01J29/48 , B01J21/063 , B01J21/066 , B01J29/076 , B01J35/0006 , B01J35/002 , B01J37/0009 , B01J37/08 , B01J2229/20 , B01J2229/42 , C07C2/76 , C07C2529/48 , C10G2300/1025 , C10G2400/30 , C07C15/00
摘要: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises a support and molybdenum or a compound thereof dispersed on the support. The support comprises an aluminosilicate zeolite combined with a binder selected from silica, titania, zirconia and mixtures thereof. The catalyst is substantially free of aluminum external to the framework of the aluminosilicate zeolite.
摘要翻译: 用于将甲烷转化为包括芳烃的高级烃的催化剂包括分散在载体上的载体和钼或其化合物。 载体包括与选自二氧化硅,二氧化钛,氧化锆及其混合物的粘合剂组合的铝硅酸盐沸石。 催化剂基本上不含铝硅酸盐沸石骨架外的铝。
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公开(公告)号:US20100331592A1
公开(公告)日:2010-12-30
申请号:US12863467
申请日:2008-12-22
IPC分类号: B01J29/076 , B01J29/48 , C07C2/00
CPC分类号: B01J29/48 , B01J21/063 , B01J21/066 , B01J29/076 , B01J35/0006 , B01J35/002 , B01J37/0009 , B01J37/08 , B01J2229/20 , B01J2229/42 , C07C2/76 , C07C2529/48 , C10G2300/1025 , C10G2400/30 , C07C15/00
摘要: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises a support and molybdenum or a compound thereof dispersed on the support. The support comprises an aluminosilicate zeolite combined with a binder selected from silica, titania, zirconia and mixtures thereof. The catalyst is substantially free of aluminum external to the framework of the aluminosilicate zeolite.
摘要翻译: 用于将甲烷转化为包括芳烃的高级烃的催化剂包括分散在载体上的载体和钼或其化合物。 载体包括与选自二氧化硅,二氧化钛,氧化锆及其混合物的粘合剂组合的铝硅酸盐沸石。 催化剂基本上不含铝硅酸盐沸石骨架外的铝。
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公开(公告)号:US07589246B2
公开(公告)日:2009-09-15
申请号:US12041275
申请日:2008-03-03
申请人: Larry L. Iaccino , Teng Xu , J. Scott Buchanan , Neeraj Sangar , Jeremy J. Patt , Mark A. Nierode , Kenneth R. Clem , Mobae Afeworki
发明人: Larry L. Iaccino , Teng Xu , J. Scott Buchanan , Neeraj Sangar , Jeremy J. Patt , Mark A. Nierode , Kenneth R. Clem , Mobae Afeworki
CPC分类号: B01J38/10 , B01J23/92 , B01J29/405 , B01J29/48 , B01J29/90 , B01J37/0036 , C07C2/78 , C07C2529/48 , Y02P20/142 , Y02P20/584 , Y02P20/588 , Y10S585/943 , C07C15/02
摘要: In a process for converting methane to aromatic hydrocarbons, a feed containing methane and a particulate catalytic material are supplied to a reaction zone operating under reaction conditions effective to convert at least a portion of the methane to aromatic hydrocarbons and to deposit carbonaceous material on the particulate catalytic material causing catalyst deactivation. At least a portion of the deactivated particulate catalytic material is removed from the reaction zone and is heated to a temperature of about 700° C. to about 1200° C. by direct and/or indirect contact with combustion gases produced by combustion of a supplemental fuel. The heated particulate catalytic material is then regenerated with a hydrogen-containing gas under conditions effective to convert at least a portion of the carbonaceous material thereon to methane and the regenerated catalytic particulate material is recycled back to the reaction zone.
摘要翻译: 在将甲烷转化为芳族烃的方法中,将含有甲烷和颗粒催化材料的进料供应到在有效将甲烷的至少一部分转化为芳族烃的反应条件下运行的反应区,并将含碳材料沉积在颗粒上 催化材料引起催化剂失活。 将至少一部分失活的颗粒催化材料从反应区中除去,并通过与补充物的燃烧产生的燃烧气体的直接和/或间接接触将其加热至约700℃至约1200℃的温度 汽油。 然后在有效将其上的至少一部分碳质材料转化为甲烷的条件下,用含氢气体再生加热的颗粒催化材料,再生的催化颗粒材料再循环回到反应区。
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公开(公告)号:US20120083637A1
公开(公告)日:2012-04-05
申请号:US13218520
申请日:2011-08-26
申请人: Kenneth R. Clem , Larry L. Iaccino , Mobae Afeworki , Juan D. Henao , Neeraj Sangar , Xiaobo Zheng , Lorenzo C. DeCaul
发明人: Kenneth R. Clem , Larry L. Iaccino , Mobae Afeworki , Juan D. Henao , Neeraj Sangar , Xiaobo Zheng , Lorenzo C. DeCaul
CPC分类号: C07C2/76 , B01J29/48 , B01J29/90 , B01J38/02 , B01J38/10 , C07C1/12 , C07C2/66 , C07C2/864 , C07C2/865 , C07C5/10 , C07C5/11 , C07C2521/06 , C07C2523/02 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/20 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/22 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2601/14 , C07C2601/16 , C07C2602/26 , C07C2602/28 , C10G50/00 , C10G2300/708 , C10G2400/30 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/24 , C07C11/04 , C07C9/04 , C07C9/06 , C07C15/073 , C07C15/08 , C07C13/18 , C07C13/50 , C07C13/20 , C07C13/48
摘要: In a process for the regeneration of a coked metal-containing catalyst, the coked catalyst is contacted in a regeneration zone with an atmosphere which contains carbon dioxide and carbon monoxide at a temperature of at least 400° C.
摘要翻译: 在含焦炭金属催化剂的再生方法中,焦化催化剂在再生区与含有二氧化碳和一氧化碳的气氛在至少400℃的温度下接触。
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公开(公告)号:US08859835B2
公开(公告)日:2014-10-14
申请号:US13218520
申请日:2011-08-26
申请人: Kenneth R. Clem , Larry L. Iaccino , Mobae Afeworki , Juan D. Henao , Neeraj Sangar , Xiaobo Zheng , Lorenzo C. DeCaul
发明人: Kenneth R. Clem , Larry L. Iaccino , Mobae Afeworki , Juan D. Henao , Neeraj Sangar , Xiaobo Zheng , Lorenzo C. DeCaul
IPC分类号: C07C15/00
CPC分类号: C07C2/76 , B01J29/48 , B01J29/90 , B01J38/02 , B01J38/10 , C07C1/12 , C07C2/66 , C07C2/864 , C07C2/865 , C07C5/10 , C07C5/11 , C07C2521/06 , C07C2523/02 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/20 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/22 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2601/14 , C07C2601/16 , C07C2602/26 , C07C2602/28 , C10G50/00 , C10G2300/708 , C10G2400/30 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/24 , C07C11/04 , C07C9/04 , C07C9/06 , C07C15/073 , C07C15/08 , C07C13/18 , C07C13/50 , C07C13/20 , C07C13/48
摘要: In a process for the regeneration of a coked metal-containing catalyst, the coked catalyst is contacted in a regeneration zone with an atmosphere which contains carbon dioxide and carbon monoxide at a temperature of at least 400° C.
摘要翻译: 在含焦炭金属催化剂的再生方法中,焦化催化剂在再生区与含有二氧化碳和一氧化碳的气氛在至少400℃的温度下接触。
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公开(公告)号:US20080249342A1
公开(公告)日:2008-10-09
申请号:US12041275
申请日:2008-03-03
申请人: Larry L. Iaccino , Teng Xu , J. Scott Buchanan , Neeraj Sangar , Jeremy J. Patt , Mark A. Nierode , Kenneth R. Clem , Mobae Afeworki
发明人: Larry L. Iaccino , Teng Xu , J. Scott Buchanan , Neeraj Sangar , Jeremy J. Patt , Mark A. Nierode , Kenneth R. Clem , Mobae Afeworki
IPC分类号: C07C2/00
CPC分类号: B01J38/10 , B01J23/92 , B01J29/405 , B01J29/48 , B01J29/90 , B01J37/0036 , C07C2/78 , C07C2529/48 , Y02P20/142 , Y02P20/584 , Y02P20/588 , Y10S585/943 , C07C15/02
摘要: In a process for converting methane to aromatic hydrocarbons, a feed containing methane and a particulate catalytic material are supplied to a reaction zone operating under reaction conditions effective to convert at least a portion of the methane to aromatic hydrocarbons and to deposit carbonaceous material on the particulate catalytic material causing catalyst deactivation. At least a portion of the deactivated particulate catalytic material is removed from the reaction zone and is heated to a temperature of about 700° C. to about 1200° C. by direct and/or indirect contact with combustion gases produced by combustion of a supplemental fuel. The heated particulate catalytic material is then regenerated with a hydrogen-containing gas under conditions effective to convert at least a portion of the carbonaceous material thereon to methane and the regenerated catalytic particulate material is recycled back to the reaction zone.
摘要翻译: 在将甲烷转化为芳香族烃的方法中,将含有甲烷和颗粒状催化材料的原料供给到在有效将甲烷的至少一部分转化为芳族烃并将含碳材料沉积在颗粒物上的反应条件下运行的反应区 催化材料引起催化剂失活。 将至少一部分失活的颗粒催化材料从反应区中除去,并通过与补充物的燃烧产生的燃烧气体的直接和/或间接接触将其加热至约700℃至约1200℃的温度 汽油。 然后在有效将其上的至少一部分碳质材料转化为甲烷的条件下,用含氢气体再生加热的颗粒催化材料,再生的催化颗粒材料再循环回到反应区。
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公开(公告)号:US07951985B2
公开(公告)日:2011-05-31
申请号:US12985789
申请日:2011-01-06
IPC分类号: C07C2/52
CPC分类号: C07C2/76 , C07C2521/04 , C07C2521/08 , C07C2523/06 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2529/40 , C10G50/00 , C10G2300/1025 , C10G2400/30
摘要: In a process for converting methane to aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst in a reaction zone under conditions effective to convert the methane to aromatic hydrocarbons. The reaction zone is contained within a reactor and the reactor or an internal component of the reactor has at least one surface that is chemically exposed to the feed and is formed from a refractory material that exhibits a carbon uptake (mass of carbon absorbed per unit of exposed metal surface area) of less than 25 g/m2 when exposed to mixture of 50 vol % methane and 50 vol % H2 at 900° C. for 168 hours.
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公开(公告)号:US20110054232A1
公开(公告)日:2011-03-03
申请号:US12865773
申请日:2009-02-05
申请人: Neeraj Sangar , Teng Xu , Larry L. Iaccino , Mobae Afeworki
发明人: Neeraj Sangar , Teng Xu , Larry L. Iaccino , Mobae Afeworki
IPC分类号: C07C2/76 , B01J29/076
CPC分类号: B01J29/48 , B01J29/076 , B01J29/90 , B01J35/002 , B01J38/06 , B01J38/14 , B01J2229/186 , B01J2229/36 , B01J2229/40 , C07C2/76 , C07C2529/48 , C10G50/00 , C10G2300/1025 , C10G2400/30 , Y02P20/584 , Y02P20/588 , C07C15/00
摘要: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises molybdenum or a compound thereof dispersed on an aluminosilicate zeolite, wherein the amount of aluminum present as aluminum molybdate in the catalyst is less than 2700 ppm by weight.
摘要翻译: 用于将甲烷转化为包括芳烃的高级烃的催化剂包括分散在铝硅酸盐沸石上的钼或其化合物,其中在催化剂中以钼酸铝存在的铝的量小于2700重量ppm。
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公开(公告)号:US20110040135A1
公开(公告)日:2011-02-17
申请号:US12701841
申请日:2010-02-08
IPC分类号: C07C2/76
CPC分类号: C07C2/76 , C07C2/78 , C10G2400/30 , Y10S585/943 , C07C15/02
摘要: In a process for converting methane to higher hydrocarbons including aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst in a reaction zone under conditions effective to convert said methane to aromatic hydrocarbons. A first portion of the catalyst is transferred from the reaction zone to a heating zone, where the first catalyst portion is heated by contacting the catalyst with hot combustion gases generated by burning a supplemental source of fuel. The heated first catalyst portion is then returned to the reaction zone.
摘要翻译: 在将甲烷转化为包括芳烃的高级烃的方法中,在有效将甲烷转化为芳族烃的条件下,含有甲烷的进料在反应区中与脱氢环化催化剂接触。 催化剂的第一部分从反应区转移到加热区,其中第一催化剂部分通过使催化剂与通过燃烧补充燃料源燃烧产生的热燃烧气体接触来加热。 然后将加热的第一催化剂部分返回到反应区。
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公开(公告)号:US07781636B2
公开(公告)日:2010-08-24
申请号:US11732039
申请日:2007-04-02
IPC分类号: C07C2/78
CPC分类号: C07C2/76 , C10G50/00 , C10G2300/1025 , C10G2400/30 , Y02P20/52 , Y10S585/943 , C07C15/02 , C07C15/04
摘要: A process for converting methane to higher hydrocarbon(s) including aromatic hydrocarbon(s) in a reaction zone comprises providing to a hydrocarbon feedstock containing methane and a catalytic particulate material to the reaction zone and contacting the catalytic particulate material and the hydrocarbon feedstock in a substantially countercurrent fashion in the reaction zone, while operating the reaction zone under reaction conditions sufficient to convert at least a portion of said methane to a first effluent having said higher hydrocarbon(s).
摘要翻译: 在反应区中将甲烷转化为高级烃(包括芳族烃)的方法包括向反应区提供含有甲烷和催化颗粒物质的烃原料,并使催化颗粒材料和烃原料接触 同时在足以将至少一部分甲烷转化为具有所述较高烃的第一流出物的反应条件下操作反应区。
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