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    STYRENE/ANHYDRIDE POLYMERIC MATERIAL AND GRAFT HAVING ENHANCED PROPERTIES
    1.
    发明申请
    STYRENE/ANHYDRIDE POLYMERIC MATERIAL AND GRAFT HAVING ENHANCED PROPERTIES 有权
    苯乙烯/无水聚合材料和具有增强性能的树脂

    公开(公告)号：US20100120983A1

    公开(公告)日：2010-05-13

    申请号：US12526102

    申请日：2008-02-01

    申请人： Nicolas Dufaure ,  Sandra Grimaldi ,  Manuel Hidalgo ,  Ludwik Leibler ,  Francois-Genes Tournilhac

    发明人： Nicolas Dufaure ,  Sandra Grimaldi ,  Manuel Hidalgo ,  Ludwik Leibler ,  Francois-Genes Tournilhac

    IPC分类号： C08F222/06

    CPC分类号： C08F8/34 ,  C08F8/14 ,  C08F8/32 ,  C08F222/06 ,  C08F2800/20 ,  C08F2810/10 ,  C08L51/06 ,  C08L2205/08 ,  C08F212/08

    摘要： A polymeric material from the styrene family, consisting of macromolecular chains grafted by nitrogen-containing heterocyclic groups; wherein the macromolecular chains consist of a polymeric backbone to which a grafted agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The mean number of imidazolidone groups to be inserted into the macromolecular chains is dependent both on the mean mass of said chains and on the final properties to be imparted to the material. The polymeric material of the invention can be extruded, coextruded, injected, blow-moulded, moulded, overmoulded, calendered or thermoformed. Objects such as tubes, films, plates, stiffenerss, bottles and containers can be made. The polymeric material of the invention can also be blended with other materials such as other polymers, and can thus be modified by elastomeric phases that enhance the impact strength thereof. The polymeric material of the invention can be a component of masterbatches of additives such as pigments and fillers. The present invention further relates to the use of said polymeric material as a compatibilization agent in a composition including, inter alia, at least two polymers belonging to different polymeric classes.”

    摘要翻译： 来自苯乙烯家族的聚合物材料，由含氮杂环基团接枝的大分子链组成; 其中所述大分子链由接枝剂通过至少一个共价键连接的聚合物主链组成，所述接枝剂在单个分子中包含一个或多个能够被氢键结合的缔合基团，以及一个或多个 能够与聚合物主链形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑烷酮杂环。 插入大分子链中的咪唑烷酮基团的平均数目取决于所述链的平均质量和赋予材料的最终性能。 本发明的聚合物材料可以挤出，共挤出，注塑，吹塑，模制，包覆成型，压延或热成型。 可以制造诸如管，膜，板，扶强材，瓶和容器的物体。 本发明的聚合物材料还可以与其它材料如其它聚合物共混，并且因此可以通过增强其冲击强度的弹性体相改性。 本发明的聚合物材料可以是颜料和填料等添加剂母料的成分。 本发明还涉及所述聚合物材料在组合物中的相容剂的用途，所述组合物尤其包括属于不同聚合物类别的至少两种聚合物。

    Styrene/anhydride polymeric material and graft having enhanced properties
    2.
    发明授权
    Styrene/anhydride polymeric material and graft having enhanced properties 有权
    具有增强性能的苯乙烯/酸酐聚合物材料和接枝物

    公开(公告)号：US08609765B2

    公开(公告)日：2013-12-17

    申请号：US13541064

    申请日：2012-07-03

    申请人： Nicolas Dufaure ,  Sandra Grimaldi ,  Manuel Hidalgo ,  Ludwik Leibler ,  Francois-Genes Tournilhac

    发明人： Nicolas Dufaure ,  Sandra Grimaldi ,  Manuel Hidalgo ,  Ludwik Leibler ,  Francois-Genes Tournilhac

    IPC分类号： C08L51/00 ,  C08F20/08

    CPC分类号： C08F8/34 ,  C08F8/14 ,  C08F8/32 ,  C08F222/06 ,  C08F2800/20 ,  C08F2810/10 ,  C08L51/06 ,  C08L2205/08 ,  C08F212/08

    摘要： A polymeric material from the styrene family comprises macromolecular chains grafted by nitrogen-containing heterocyclic groups; wherein the macromolecular chains comprise a polymeric backbone to which a grafted agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The mean number of imidazolidone groups to be inserted into the macromolecular chains is dependent both on the mean mass of said chains and on the final properties to be imparted to the material. Objects such as tubes, films, plates, stiffeners, bottles and containers can be made.

    摘要翻译： 来自苯乙烯系的聚合物材料包括由含氮杂环基团接枝的大分子链; 其中所述大分子链包含通过至少一个共价键连接的接枝剂的聚合物主链，所述接枝剂在单一分子中包含一个或多个能够被氢键结合的缔合基团，以及一个或多个反应性 能够与聚合物主链形成共价键的基团，改性剂的至少一个缔合基团是咪唑啉酮杂环。 插入大分子链中的咪唑烷酮基团的平均数目取决于所述链的平均质量和赋予材料的最终性能。 可以制造诸如管，膜，板，加强件，瓶和容器的物体。

    Styrene/anhydride polymeric material and graft having enhanced properties
    3.
    发明授权
    Styrene/anhydride polymeric material and graft having enhanced properties 有权
    具有增强性能的苯乙烯/酸酐聚合物材料和接枝物

    公开(公告)号：US08242207B2

    公开(公告)日：2012-08-14

    申请号：US12526102

    申请日：2008-02-01

    申请人： Nicolas Dufaure ,  Sandra Grimaldi ,  Manuel Hidalgo ,  Ludwik Leibler ,  Francois-Genes Tournilhac

    发明人： Nicolas Dufaure ,  Sandra Grimaldi ,  Manuel Hidalgo ,  Ludwik Leibler ,  Francois-Genes Tournilhac

    IPC分类号： C08L51/00 ,  C08K3/00

    CPC分类号： C08F8/34 ,  C08F8/14 ,  C08F8/32 ,  C08F222/06 ,  C08F2800/20 ,  C08F2810/10 ,  C08L51/06 ,  C08L2205/08 ,  C08F212/08

    摘要： A polymeric material from the styrene family, consisting of macromolecular chains grafted by nitrogen-containing heterocyclic groups; wherein the macromolecular chains consist of a polymeric backbone to which a grafted agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The polymeric material of the invention can also be blended with other materials such as other polymers, and can thus be modified by elastomeric phases that enhance the impact strength thereof.

    摘要翻译： 来自苯乙烯家族的聚合物材料，由含氮杂环基团接枝的大分子链组成; 其中所述大分子链由接枝剂通过至少一个共价键连接的聚合物主链组成，所述接枝剂在单个分子中包含一个或多个能够被氢键结合的缔合基团，以及一个或多个 能够与聚合物主链形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑烷酮杂环。 本发明的聚合物材料还可以与其它材料如其它聚合物共混，并且因此可以通过增强其冲击强度的弹性体相改性。

    Polymeric additives obtained by salification of copolymers
    6.
    发明授权
    Polymeric additives obtained by salification of copolymers 失效
    通过共聚物成盐获得的聚合物添加剂

    公开(公告)号：US08492495B2

    公开(公告)日：2013-07-23

    申请号：US12810037

    申请日：2008-12-09

    申请人： Manuel Hidalgo ,  Sandra Grimaldi

    发明人： Manuel Hidalgo ,  Sandra Grimaldi

    IPC分类号： C08F2/00 ,  C08L51/00

    CPC分类号： D21H19/58 ,  C08F8/32 ,  C08F8/44 ,  D21H19/22 ,  D21H21/16 ,  C08F220/06 ,  C08F222/08 ,  C08F212/08 ,  C08F220/08

    摘要： The present invention relates to a salified copolymer that can be obtained by salification, in an aqueous medium, using at least one amine containing at least one nitrogenous heterocyclic group, of a copolymer obtained from at least one cyclic anhydride-based or carboxylic acid-based monomer and from at least one styrene-based monomer, such as a styrene/maleic anhydride (SMA) copolymer. It also relates to the process for producing this salified copolymer, to a composition containing same, and also to the use of this composition for surface-treating, in particular coating, sizing and finishing, paper or cardboard.

    摘要翻译： 本发明涉及通过使用至少一种含有至少一个含氮杂环基的胺在含水介质中通过成盐获得的盐化共聚物，其由至少一种环状酸酐类或羧酸类获得的共聚物 单体和至少一种基于苯乙烯的单体，例如苯乙烯/马来酸酐（SMA）共聚物。 它还涉及生产该盐化共聚物的方法，含有该组合物的方法，以及该组合物用于表面处理，特别是涂料，上浆和整理，纸或纸板的用途。

    POLYMERIC ADDITIVES OBTAINED BY SALIFICATION OF COPOLYMERS
    7.
    发明申请
    POLYMERIC ADDITIVES OBTAINED BY SALIFICATION OF COPOLYMERS 失效
    由共聚物分解获得的聚合添加剂

    公开(公告)号：US20100273965A1

    公开(公告)日：2010-10-28

    申请号：US12810037

    申请日：2008-12-09

    申请人： Manuel Hidalgo ,  Sandra Grimaldi

    发明人： Manuel Hidalgo ,  Sandra Grimaldi

    IPC分类号： C08F22/06

    CPC分类号： D21H19/58 ,  C08F8/32 ,  C08F8/44 ,  D21H19/22 ,  D21H21/16 ,  C08F220/06 ,  C08F222/08 ,  C08F212/08 ,  C08F220/08

    摘要： The present invention relates to a salified copolymer that can be obtained by salification, in an aqueous medium, using at least one amine containing at least one nitrogenous heterocyclic group, of a copolymer obtained from at least one cyclic anhydride-based or carboxylic acid-based monomer and from at least one styrene-based monomer, such as a styrene/maleic anhydride (SMA) copolymer. It also relates to the process for producing this salified copolymer, to a composition containing same, and also to the use of this composition for surface-treating, in particular coating, sizing and finishing, paper or cardboard.

    摘要翻译： 本发明涉及通过使用至少一种含有至少一个含氮杂环基的胺在含水介质中通过成盐获得的盐化共聚物，其由至少一种环状酸酐类或羧酸类获得的共聚物 单体和至少一种基于苯乙烯的单体，例如苯乙烯/马来酸酐（SMA）共聚物。 它还涉及生产该盐化共聚物的方法，含有该组合物的方法，以及该组合物用于表面处理，特别是涂料，上浆和整理，纸或纸板的用途。

    USE OF GRAFTED SMA COPOLYMERS IN LIQUID COMPOSITIONS
    8.
    发明申请
    USE OF GRAFTED SMA COPOLYMERS IN LIQUID COMPOSITIONS 失效
    在液体组合物中使用接枝的SMA共聚物

    公开(公告)号：US20100249281A1

    公开(公告)日：2010-09-30

    申请号：US12667256

    申请日：2008-06-23

    申请人： Manuel Hidalgo ,  Sandra Grimaldi

    发明人： Manuel Hidalgo ,  Sandra Grimaldi

    IPC分类号： C08K3/00 ,  C08L79/04 ,  C08K3/26 ,  C08K3/34

    CPC分类号： C08F257/02 ,  C08F8/32 ,  C08F2800/10 ,  C08F2800/20 ,  C08F2810/50 ,  C08L51/003 ,  C09D151/003 ,  D21H11/08 ,  D21H11/14 ,  D21H19/58 ,  D21H21/18 ,  C08L2666/02 ,  C08F8/48 ,  C08F220/08 ,  C08F212/08 ,  C08F222/06

    摘要： The subject of the invention is the use of a grafted copolymer derived from the grafting: —of an SMA copolymer (II) derived from the copolymerization of at least two monomers, (i) the first monomer being chosen from styrene and its derivatives and (ii) the second monomer including at least one anhydride function, —with either (iii) M-R—X molecules (I) including at least one pattern (M) chosen from patterns (1) to (4): formula (I), with A=oxygen, sulfur or NH; and including at least one chemical function (X) chosen from among halogen, a primary or secondary amine function, an alcohol function, a thiol function, a carboxylic acid function or a derivative of said function and an epoxy function, the pattern (M) and said function (X) being connected by a rigid or flexible chain (R); namely (iv) molecules belonging to the family of triazoles; used as the majority composition or additive of liquid compositions intended to be applied in or on sheets of paper or cardboard, onto hard surfaces, on leather or on textiles.

    摘要翻译： 本发明的主题是使用衍生自衍生自至少两种单体的共聚合的SMA共聚物（II）的接枝共聚物：（i）第一单体选自苯乙烯及其衍生物和（ ii）包含至少一个酸酐官能团的第二单体， - （iii）包含选自图案（1）至（4）中的至少一种图案（M）的MR-X分子（I）：式（I），与 A =氧，硫或NH; 并且包括至少一种选自卤素，伯胺或仲胺官能团，醇官能团，硫醇官能团，羧酸官能团或所述官能团的衍生物和环氧官能团的化学官能团（X），所述模式（M） 并且所述功能（X）通过刚性或柔性链（R）连接; 即（iv）属于三唑族的分子; 用作要用于纸或纸板上或纸张上的液体组合物的大多数组合物或添加剂，在硬表面上，皮革上或纺织品上。