公开(公告)号：US6020410A

公开(公告)日：2000-02-01

申请号：US955802

申请日：1997-10-22

申请人： Nigel P. Hacker ,  Todd Krajewski ,  Scott Lefferts ,  Gary Davis

发明人： Nigel P. Hacker ,  Todd Krajewski ,  Scott Lefferts ,  Gary Davis

IPC分类号： C08K5/5415 ,  C08J3/09 ,  C08L83/05 ,  C09D183/04 ,  C09D183/05 ,  C08K5/54

CPC分类号： C08J3/098 ,  C08J3/091 ,  C08J2383/04

摘要： Storage solutions of silsesquioxane and siloxane polymers are obtained by means of a silicon containing solvent composition. The solution has at least one polymer having a formula of [(HSiO.sub.1.5).sub.x O.sub.y ].sub.n, (HSiO.sub.1.5).sub.n, [(HSiO.sub.1.5).sub.x O.sub.y (RSiO.sub.1.5).sub.z ].sub.n, [(HSiO.sub.1.5).sub.x (RSiO.sub.1.5).sub.y ].sub.n or [(HSiO.sub.1.5).sub.x O.sub.y (RSiO.sub.1.5).sub.z ].sub.n wherein x=about 6 to about 20, y=1 to about 3, z=about 6 to about 20, n=1 to about 4,000, and each R is independently H, C.sub.1 to C.sub.8 alkyl or C.sub.6 to C.sub.12 aryl. The solvent has the formula of (CH.sub.3).sub.3 Si--O--[Si(CH.sub.3).sub.2 ].sub.a --Si(CH.sub.3).sub.3, (CH.sub.3 CH.sub.2)Si--O--[Si(CH.sub.3 CH.sub.2).sub.2 ].sub.a --SiCH.sub.3 CH.sub.2).sub.3, R.sub.3 Si--O--[SiR'.sub.2 ].sub.a --SiR.sub.3, [O--Si(CH.sub.3).sub.2 ].sub.b, [O--Si(CH.sub.3 CH.sub.2).sub.2 ].sub.b or [O--SiR'.sub.2 ].sub.n wherein a=0-5, b=3-5, and each R' is independently H or C.sub.1 to C.sub.8 alkyl.

摘要翻译： 通过含硅溶剂组合物获得倍半硅氧烷和硅氧烷聚合物的储存溶液。 该溶液具有至少一种具有式[（HSiO 1.5）x O y] n，（HSiO 1.5）n，[（HSiO 1.5）x O y（RSiO 1.5）]]，[（HSiO 1.5） x（RSiO1.5）y] n或[（HSiO1.5）xOy（RSiO1.5）z] n其中x =约6至约20，y = 1至约3，z =约6至约20，n = 1至约4,000，并且每个R独立地为H，C 1至C 8烷基或C 6至C 12芳基。 溶剂具有式（CH3）3Si-O- [Si（CH3）2] a-Si（CH3）3，（CH3CH2）Si-O- [Si（CH3CH2）2] a-SiCH3CH2）3，R3Si- O- [SiR'2] a-SiR3，[O-Si（CH3）2] b，[O-Si（CH3CH2）2] b或[O-SiR'2] n，其中a = 0-5，b = 3-5，每个R'独立地为H或C 1至C 8烷基。

公开(公告)号：US5973095A

公开(公告)日：1999-10-26

申请号：US55516

申请日：1998-04-06

申请人： Nigel P. Hacker ,  Todd Krajewski ,  Scott Lefferts

发明人： Nigel P. Hacker ,  Todd Krajewski ,  Scott Lefferts

IPC分类号： C08G77/08 ,  C08G77/12 ,  C09D183/05

CPC分类号： C08G77/12

摘要： Novel processes for preparing hydridosiloxane and organohydridosiloxane resins are disclosed. The processes of the invention broadly provide for the steps of contacting a silane monomer with a solid state catalyst in the presence of a reaction mixture that includes a nonpolar, e.g., hydrocarbon, solvent, and a polar solvent, e.g., alcohol and water. The process is conducted under conditions effective to catalytically convert said silane monomer into hydridosiloxanes and organohydridosiloxanes. Recovery of the products is advantageously aided by the ease of separating the solid state catalyst from the reaction mixture. Hydridosiloxanes and organohydridosiloxanes resins produced by the processes of the invention are also provided.

摘要翻译： 公开了制备氢硅氧烷和有机氢硅氧烷树脂的新方法。 本发明的方法广泛地提供了在包括非极性例如烃，溶剂和极性溶剂如醇和水的反应混合物存在下使硅烷单体与固态催化剂接触的步骤。 该方法在有效地将所述硅烷单体催化转化成氢硅氧烷和有机羟基硅氧烷的条件下进行。 通过将固体催化剂与反应混合物分离的容易性有利于辅助产物的回收。 还提供了通过本发明的方法制备的羟基硅氧烷和有机氢硅氧烷树脂。

公开(公告)号：US08618409B2

公开(公告)日：2013-12-31

申请号：US12824662

申请日：2010-06-28

申请人： Todd Krajewski ,  Kedar Hardikar

发明人： Todd Krajewski ,  Kedar Hardikar

IPC分类号： H02N6/00 ,  H01L31/042 ,  H01L31/00 ,  H01L21/00

CPC分类号： H01L31/05 ,  H01L31/02167 ,  H01L31/0481 ,  Y02E10/50

摘要： A photovoltaic device includes at least one photovoltaic cell, a flexible glass layer formed over the at least one photovoltaic cell and a transparent and abrasion resistant film which includes an organic-inorganic hybrid material formed over the glass layer.

摘要翻译： 光伏器件包括至少一个光伏电池，形成在所述至少一个光伏电池上的柔性玻璃层和透明耐磨膜，该膜包括形成在所述玻璃层上的有机 - 无机杂化材料。

公开(公告)号：US20120080065A1

公开(公告)日：2012-04-05

申请号：US12894736

申请日：2010-09-30

申请人： Todd Krajewski ,  Donald S. Nelson

发明人： Todd Krajewski ,  Donald S. Nelson

IPC分类号： H01L31/042 ,  H01L21/98

CPC分类号： H01L31/048 ,  Y02E10/50

摘要： Provided are novel photovoltaic module structures and related fabrication techniques. According to various embodiments, the structures include a structural bond related between two sealing sheets of the photovoltaic module configured to support one sealing sheet with respect to the other and, in certain embodiments, to support photovoltaic cells with respect to both sealing sheets. In certain embodiments, a photovoltaic module is fabricated without a back encapsulant layer, and the back sealing sheet is supported by the structural bond. The structural bond may also be used as a moisture barrier in addition or instead of an edge seal. The structural bond material can include a silicone-based polymer, which provides good adhesive and UV resistance properties. The structural bond may be formed by a structural bonding material that is dispensed around the photovoltaic cells.

摘要翻译： 提供了新型光伏模块结构和相关制造技术。 根据各种实施例，结构包括在光伏模块的两个密封片之间相关的结构粘合，该密封片构造成相对于彼此支撑一个密封片，并且在某些实施例中相对于两个密封片支撑光伏电池。 在某些实施例中，制造光伏模块而没有后封装层，并且后密封片由结构键支撑。 另外还可以使用结构粘合剂作为防潮层，或代替边缘密封。 结构键合材料可以包括提供良好的粘合剂和抗紫外线性质的硅氧烷基聚合物。 结构键可以由分布在光伏电池周围的结构接合材料形成。

公开(公告)号：US20110139224A1

公开(公告)日：2011-06-16

申请号：US12639346

申请日：2009-12-16

申请人： Todd Krajewski

发明人： Todd Krajewski

IPC分类号： H01L31/048 ,  H01L31/0203

CPC分类号： H01L31/048 ,  Y02E10/50

摘要： A frameless photovoltaic module retains the required load rating by incorporation of an oriented fibrous reinforcement (e.g., fibers, scrim or mesh) in the back side encapsulant, in the back sheet, or as a separate sheet between the encapsulant and the back sheet to increase the overall stiffness of the module. The reinforcement is compatible with the materials around it, in particular having good wet out, and may be freestanding or anchored to outer edges of the module, for example to the front glass, by means of an adhesive in order to further enhance the stiffness conferred to the module.

摘要翻译： 无框光伏模块通过在背面密封剂，背板中引入取向的纤维增强材料（例如，纤维，稀松布或网状物）或作为密封剂和背板之间的单独片材来保持所需的额定载荷，以增加 模块的总体刚度。 加强件与其周围的材料相容，特别是具有良好的润湿性，并且可以通过粘合剂独立地或锚固到模块的外边缘，例如到前玻璃，以进一步增强赋予的刚度 到模块。

公开(公告)号：US07960643B2

公开(公告)日：2011-06-14

申请号：US12556460

申请日：2009-09-09

申请人： Todd Krajewski ,  Jason Corneille ,  Shefali Jaiswal ,  Anil Vijayendran

发明人： Todd Krajewski ,  Jason Corneille ,  Shefali Jaiswal ,  Anil Vijayendran

IPC分类号： H01L31/0203 ,  H01L31/048

CPC分类号： H01L31/049 ,  Y02E10/50

摘要： Provided are novel back sheets for solar module encapsulation. According to various embodiments, the back sheets are ungrounded and flexible. In certain embodiments, the back sheets include an integrated flexible and electrically isolated moisture barrier. The electrically isolated moisture barrier may be a thin metallic sheet, e.g., an aluminum foil. The electrically isolated, flexible moisture barrier eliminates the need for grounding.

摘要翻译： 提供太阳能模块封装的新型背板。 根据各种实施例，底片是不接地且柔性的。 在某些实施例中，背板包括集成的柔性和电隔离的湿气屏障。 电隔离的防潮层可以是薄金属片，例如铝箔。 电气隔离，灵活的防潮层消除了对接地的需要。

公开(公告)号：US08251576B1

公开(公告)日：2012-08-28

申请号：US12455398

申请日：2009-05-30

申请人： Kedar Hardikar ,  Todd Krajewski

发明人： Kedar Hardikar ,  Todd Krajewski

IPC分类号： H01L31/0203 ,  H02K6/00 ,  G01N25/32 ,  G01N25/58 ,  G01N3/18

CPC分类号： G01N3/60 ,  G01M99/002 ,  H02S50/10

摘要： Multilayer articles such as thin-film solar cells can be effectively tested under thermal load in a mini-module that includes a chamber or enclosure in which one or more laminated multilayer articles are housed. The inner dimensions of the chamber, at least along the axis that is perpendicular to the plane defined by the laminated solar cells, are configured to remain substantially constant during testing. Cooling the laminated solar cells in the mini-module device causes the encapsulant material to shrink and thereby induces accelerated failures in the laminated solar cells and associated structures. A technique of detecting the presence of defects or failures is near infrared radiation thermography wherein NIR images of the laminated solar cells are taken during the cooling process. The color patterns manifested from the cooled laminated solar cells can reveal the location, nature and extent of the defect or failure.

摘要翻译： 可以在微型模块中在热负载下有效地测试诸如薄膜太阳能电池的多层制品，该微型模块包括其中容纳有一个或多个层压多层制品的室或外壳。 至少沿着垂直于由层叠太阳能电池限定的平面的轴线的腔室的内部尺寸构造成在测试期间保持基本恒定。 冷却微型模块装置中的层叠太阳能电池使得密封剂材料收缩，从而在叠层太阳能电池和相关结构中引起加速故障。 检测缺陷或故障的存在的技术是近红外辐射热成像仪，其中在冷却过程中采集层叠太阳能电池的NIR图像。 从冷却的层叠太阳能电池出现的颜色图案可以显示缺陷或故障的位置，性质和程度。

公开(公告)号：US20110036389A1

公开(公告)日：2011-02-17

申请号：US12539054

申请日：2009-08-11

申请人： Kedar Hardikar ,  Todd Krajewski ,  Kent Whitfield

发明人： Kedar Hardikar ,  Todd Krajewski ,  Kent Whitfield

IPC分类号： H01L31/048 ,  C03C27/12

CPC分类号： H01L31/048 ,  Y02E10/50

摘要： A photovoltaic module having a light transmissive front layer, a back layer, and a plurality of interconnected photovoltaic cells disposed between the light transmissive front layer and the back layer has a CTE-modified composite encapsulant is interposed between the plurality of solar cells and the light transmissive front layer. The composite encapsulant includes a bulk encapsulant transmissive to visible and near visible wavelengths of the solar spectrum and having a base coefficient of thermal (CTE) expansion, and an encapsulant CTE modifier in the bulk encapsulant. The encapsulant CTE modifier is substantially evenly distributed through the composite encapsulant thickness and interacts with the bulk encapsulant to reduce the effective CTE of the composite encapsulant below that of the bulk encapsulant.

摘要翻译： 具有透光性前层，背层和设置在透光性前层与背层之间的多个互连光伏电池的光伏组件具有CTE改性复合密封剂，其插入在多个太阳能电池和光 透射前层。 复合密封剂包括对太阳光谱的可见光和近可见波长透射并且具有基本热（CTE）膨胀系数的散装密封剂，以及散装密封剂中的密封剂CTE改性剂。 密封剂CTE改性剂基本上均匀地分布在复合材料密封剂厚度上并与体积密封剂相互作用，以将复合材料密封剂的有效CTE降低到体积密封剂的有效CTE。

公开(公告)号：US20100071756A1

公开(公告)日：2010-03-25

申请号：US12464721

申请日：2009-05-12

申请人： Todd Krajewski ,  Jason Corneille ,  Shefali Jaiswal

发明人： Todd Krajewski ,  Jason Corneille ,  Shefali Jaiswal

IPC分类号： H01L31/048

CPC分类号： B32B3/18 ,  B32B3/04 ,  B32B3/08 ,  B32B5/147 ,  B32B7/045 ,  B32B7/12 ,  B32B9/041 ,  B32B9/045 ,  B32B15/08 ,  B32B15/18 ,  B32B15/20 ,  B32B17/10018 ,  B32B25/04 ,  B32B27/08 ,  B32B27/283 ,  B32B27/286 ,  B32B27/302 ,  B32B27/304 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/322 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B27/38 ,  B32B27/40 ,  B32B27/42 ,  B32B2270/00 ,  B32B2274/00 ,  B32B2307/206 ,  B32B2307/306 ,  B32B2307/412 ,  B32B2307/546 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/7246 ,  B32B2327/12 ,  B32B2457/12 ,  H01L31/049 ,  Y02E10/50

摘要： Provided are novel back sheets for solar module encapsulation. According to various embodiments, the back sheets are ungrounded and flexible. In certain embodiments, the back sheets include an integrated flexible and electrically isolated moisture barrier and a seal around the edge of the moisture barrier. The electrically isolated moisture barrier may be a thin metallic sheet, e.g., an aluminum foil. The electrically isolated, flexible moisture barrier eliminates the need for grounding.

摘要翻译： 提供太阳能模块封装的新型背板。 根据各种实施例，底片是不接地且柔性的。 在某些实施例中，背板包括集成的柔性和电隔离的湿气屏障以及围绕防潮层的边缘的密封。 电隔离的防潮层可以是薄金属片，例如铝箔。 电气隔离，灵活的防潮层消除了对接地的需要。

公开(公告)号：US20070049155A1

公开(公告)日：2007-03-01

申请号：US11509837

申请日：2006-08-24

申请人： Lorenza Moro ,  Todd Krajewski

发明人： Lorenza Moro ,  Todd Krajewski

IPC分类号： H01J9/24 ,  H01J9/04 ,  H01J1/62

CPC分类号： H01L51/5256 ,  H01L51/448 ,  Y02E10/549

摘要： A method of encapsulating an environmentally sensitive device. The method includes providing a substrate; placing at least one environmentally sensitive device adjacent to the substrate; and depositing at least one barrier stack adjacent to the environmentally sensitive device, the at least one barrier stack comprising at least one barrier layer and at least one polymeric decoupling layer, wherein the at least one polymeric decoupling layer is made from at least one polymer precursor, and wherein the polymeric decoupling layer has at least one of: a reduced number of polar regions; a high packing density; a reduced number of regions that have bond energies weaker than a C—C covalent bond; a reduced number of ester moieties; increased Mw of the at least one polymer precursor; increased chain length of the at least one polymer precursor; or reduced conversion of C═C bonds. An encapsulated environmentally sensitive device is also described.

摘要翻译： 封装环境敏感设备的方法。 该方法包括提供基板; 将至少一个对环境敏感的装置放置在与基底相邻的位置; 至少一个阻挡层叠层包括至少一个阻挡层和至少一个聚合物去耦层，其中所述至少一个聚合物去耦层由至少一个聚合物前体制成， ，并且其中所述聚合物去耦层具有以下至少一种：极数区域数目的减少; 高填充密度; 具有比C-C共价键弱的键能的区域数量减少; 减少数量的酯部分; 增加所述至少一种聚合物前体的Mw; 增加所述至少一种聚合物前体的链长度; 或降低C-C键的转化率。 还描述了封装的环境敏感设备。