公开(公告)号：US08967888B2

公开(公告)日：2015-03-03

申请号：US13455990

申请日：2012-04-25

申请人： Otto Van Den Berg ,  Stephane J. G. Berghmans ,  Filip Du Prez

发明人： Otto Van Den Berg ,  Stephane J. G. Berghmans ,  Filip Du Prez

IPC分类号： G02B6/36 ,  G03G9/097

CPC分类号： C08G77/392 ,  C08G77/20 ,  C08L83/04 ,  G02B6/387 ,  G02B6/3897 ,  H01R13/5216 ,  H01R24/64 ,  C08L83/00

摘要： Methods and systems are provided for a dry silicone gel. The dry silicone gel comprises a base polymer having a vinyl-silicone group and a crosslinker having thiol groups. The dry silicone gel may be made without the use of a catalyst by reacting the base polymer and crosslinker in the presence of a photo or thermal initiator. In some embodiments, the gel also comprises a chain extender having thiol groups. In certain embodiments, the dry silicone gel may comprise: (1) a hardness between 100 g and 300 g, (2) a stress relaxation between 30% and 60% when subjected to a deformation of 50% of the original size of the gel, (3) a compression set between 4% and 20% after 50% strain has been applied to the gel for 1000 hours at 70° C., and/or (4) less than 10% oil bleed out under compression of 1.2 atm after 60 days at 60° C.

摘要翻译： 为干硅胶提供方法和系统。 干硅胶包含具有乙烯基硅氧烷基团和具有硫醇基团的交联剂的基础聚合物。 可以在光或热引发剂的存在下使基础聚合物和交联剂反应而不使用催化剂来制备干燥的硅凝胶。 在一些实施方案中，凝胶还包含具有硫醇基的扩链剂。 在某些实施方案中，干硅氧烷凝胶可以包括：（1）100g和300g之间的硬度，（2）当经受凝胶原始尺寸的50％的变形时，应力松弛在30％和60％之间 ，（3）在70℃下在凝胶上施加50％应变后的压缩永久变形率在4％至20％之间，和/或（4）在1.2atm压缩下少于10％的油渗出 60°C后60°C

公开(公告)号：US20140039081A1

公开(公告)日：2014-02-06

申请号：US14111578

申请日：2012-04-13

申请人： Otto Van Den Berg ,  Filip Du Prez ,  Sam Verbrugghe

发明人： Otto Van Den Berg ,  Filip Du Prez ,  Sam Verbrugghe

IPC分类号： C08F128/04 ,  C08L41/00

CPC分类号： C08F128/04 ,  C07C303/28 ,  C07C319/02 ,  C07C327/22 ,  C08G75/02 ,  C08G75/0295 ,  C08G75/045 ,  C08L41/00 ,  C08L81/02 ,  C07C309/66 ,  C07C321/08

摘要： A process For the production of a thermoplastic polymer including carbon and sulphur in an atomic ration of C:S of at least 4 and at most 36 using thiol-ene addition polymerization, preferably with feedstocks obtained from renewable resources such as fatty acids from vegetable origin. The product is preferably aliphatic, meaning that at most 70% of the protons are present as aromatic hydrogen atoms and, if oxygen atoms are present in ester functions, the atomic ratio of the oxygen atoms present in ester functions relative to the number of sulphur atoms in the polymer is less than 1.0. The polymer may be used to produce a shaped article.

摘要翻译： 一种方法使用硫醇 - 烯加成聚合制备包含碳和硫的C：S原子比至少为4且最多36的热塑性聚合物，优选使用从可再生资源获得的原料，例如来自植物来源的脂肪酸 。 该产物优选是脂肪族的，这意味着至多70％的质子作为芳族氢原子存在，并且如果在酯官能团中存在氧原子，则酯官能团中存在的氧原子的原子比相对于硫原子数 在聚合物中小于1.0。 聚合物可用于制造成型制品。

公开(公告)号：US20080262160A1

公开(公告)日：2008-10-23

申请号：US11571508

申请日：2005-06-30

申请人： Filip Du Prez ,  Wim Van Camp ,  Stefan A. F. Bon

发明人： Filip Du Prez ,  Wim Van Camp ,  Stefan A. F. Bon

IPC分类号： C08F20/26 ,  C08F2/38

CPC分类号： C08F122/105 ,  C08F220/26 ,  C08F220/38 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/02 ,  C08F2438/03

摘要： This invention relates to monodisperse or nearly monodisperse (co)polymers containing acrylic or (α-substituted)acrylic acid moieties, polymeric precursors thereof as well as methods for making them by at least partial hydrolysis of said polymeric precursors. The invention also relates to compositions comprising such (co)polymers optionally in combination with polymer processing additives for use in various fields of technology including imaging applications.

摘要翻译： 本发明涉及含有丙烯酸或（α-取代的）丙烯酸部分的单分散或几乎单分散（共）聚合物，其聚合物前体以及通过至少部分水解所述聚合物前体制备它们的方法。 本发明还涉及包含任选与聚合物加工添加剂组合的这种（共）聚合物的组合物，其用于各种技术领域，包括成像应用。

公开(公告)号：US11028454B2

公开(公告)日：2021-06-08

申请号：US13120908

申请日：2009-09-24

申请人： Johan Mertens ,  Lynda Beladjal ,  Frank Devlieghere ,  Sam Verbrugghe ,  Benedikt Sas ,  Filip Du Prez ,  Tom Anthierens ,  Assia Ouchchen

发明人： Johan Mertens ,  Lynda Beladjal ,  Frank Devlieghere ,  Sam Verbrugghe ,  Benedikt Sas ,  Filip Du Prez ,  Tom Anthierens ,  Assia Ouchchen

IPC分类号： C12N11/08 ,  C12R1/07

摘要： The present application relates to methods for producing materials having viable micro-organisms incorporated therein. More particularly, the materials are produced under high temperature and/or high pressure conditions, and the micro-organisms are incorporated in the material before or during these conditions. Also provided are micro-organisms that remain viable under these conditions and have different applications, depending on the nature of the material.

公开(公告)号：US08889799B2

公开(公告)日：2014-11-18

申请号：US12666764

申请日：2008-06-26

申请人： Filip Du Prez ,  David Fournier ,  Peter Spanhove

发明人： Filip Du Prez ,  David Fournier ,  Peter Spanhove

IPC分类号： C08G18/00 ,  C08F283/04 ,  C08G18/73 ,  C08G18/32 ,  C08G18/67 ,  C08G101/00

CPC分类号： C08G18/73 ,  C08G18/3206 ,  C08G18/679 ,  C08G2101/005 ,  C08G2101/0083

摘要： The present invention relates to a method for producing an isocyanate-based polymeric material by polymerizing a reaction mixture which comprises different reaction components, including at least one polyisocyanate component and at least one component which is reactive towards said polyisocyanate component. The reaction components comprise at least one anchor component which has at least one anchor group which enables to bond a functional component covalently to the polymeric material. The anchor group is a reactive unsaturated group which does not react during the polymerization process so that the polymerization process is not interfered. The anchor group is selected to that it can bind the functional component by a click chemistry reaction to the polymeric material. It is more particularly selected so that it can participate in a catalyzed Huisgen 1,3-dipolar cycloaddition reaction or in a Diels-Alder cycloaddition reaction The invention also relates to the obtained isocyanate-based polymeric material, to the use thereof to produce a functionalized polymeric material and to this functionalized polymeric material.

摘要翻译： 本发明涉及通过聚合包含不同反应组分的反应混合物来生产异氰酸酯基聚合物材料的方法，所述反应混合物包括至少一种多异氰酸酯组分和至少一种对所述多异氰酸酯组分具有反应性的组分。 反应组分包含至少一种具有至少一个锚定基团的锚固组分，该锚定基团能够将功能性组分共价结合到聚合物材料上。 锚定基团是在聚合过程中不反应的反应性不饱和基团，使得聚合过程不受干扰。 锚定组被选择为可以通过点击化学反应将功能组分结合到聚合物材料上。 更具体地选择它，使得其可以参与催化的Huisgen 1,3-偶极环加成反应或Diels-Alder环加成反应。本发明还涉及所获得的异氰酸酯基聚合物材料，其用途是制备官能化 聚合物材料和该官能化聚合物材料。

公开(公告)号：US08901180B2

公开(公告)日：2014-12-02

申请号：US13470567

申请日：2012-05-14

申请人： Laura Jonckheere ,  Filip Du Prez ,  Thu Nguyen

发明人： Laura Jonckheere ,  Filip Du Prez ,  Thu Nguyen

IPC分类号： C08F8/34 ,  C08F281/00 ,  C08F283/00 ,  C08G18/82 ,  C08J9/04

CPC分类号： C08G18/835 ,  C08G18/6745 ,  C08G18/675 ,  C08G18/679

摘要： The invention relates to a method for functionalizing a thermoset, crosslinked isocyanate-based polymeric solid material which is made of isocyanate and isocyanate reactive components, at least one of which comprises an anchor component which has at least one anchor group. The anchor groups on the solid material are formed by terminal alkene and/or alkyne groups. To functionalize this polymeric solid material it is brought in contact with a solution which contains at least one functional component. This functional component comprises at least one thiol group and is allowed to bind covalently to the polymeric solid material by a free-radical addition reaction between the thiol groups on the functional component and the terminal alkene and/or alkyne anchor groups on the undissolved solid material. An effective functionalization of the polymeric material can thus be achieved notwithstanding the heterogeneous reaction conditions.

摘要翻译： 本发明涉及用于官能化由异氰酸酯和异氰酸酯反应性组分制成的热固性交联的异氰酸酯基聚合物固体材料的方法，其中至少一种包括具有至少一个锚定基团的锚固组分。 固体材料上的锚定基团由末端烯烃和/或炔烃基团形成。 为了官能化该聚合物固体材料，其与含有至少一种官能组分的溶液接触。 该功能组分包含至少一个硫醇基团，并且通过功能组分上的硫醇基团与未溶解的固体材料上的末端烯烃和/或炔炔基团之间的自由基加成反应，使其与共聚物固体材料共价键合 。 因此，尽管有非均相的反应条件，也可以实现聚合物材料的有效功能化。

公开(公告)号：US20110217758A1

公开(公告)日：2011-09-08

申请号：US13120908

申请日：2009-09-24

申请人： Johan Mertens ,  Lynda Beladjal ,  Frank Devlieghere ,  Sam Verbrugghe ,  Benedikt Sas ,  Filip Du Prez ,  Tom Anthierens ,  Assia Ouchchen

发明人： Johan Mertens ,  Lynda Beladjal ,  Frank Devlieghere ,  Sam Verbrugghe ,  Benedikt Sas ,  Filip Du Prez ,  Tom Anthierens ,  Assia Ouchchen

IPC分类号： C12N1/20 ,  B29C45/00

CPC分类号： C12R1/07 ,  C12N11/08

摘要： The present application relates to methods for producing materials having viable micro-organisms incorporated therein. More particularly, the materials are produced under high temperature and/or high pressure conditions, and the microganisms are incorporated in the material before or during these conditions. Also provided are micro-organisms that remain viable under these conditions and have different applications, depending on the nature of the material.

摘要翻译： 本申请涉及用于生产具有并入其中的活微生物的材料的方法。 更具体地说，材料是在高温和/或高压条件下生产的，并且在这些条件之前或期间将微生物并入材料中。 还提供了在这些条件下保持存活并且具有不同应用的微生物，这取决于材料的性质。

公开(公告)号：US20100234482A1

公开(公告)日：2010-09-16

申请号：US12666764

申请日：2008-06-26

申请人： Filip Du Prez ,  David Fournier ,  Peter Spanhove

发明人： Filip Du Prez ,  David Fournier ,  Peter Spanhove

IPC分类号： C08G18/00 ,  C08G18/12 ,  C07C263/16

CPC分类号： C08G18/73 ,  C08G18/3206 ,  C08G18/679 ,  C08G2101/005 ,  C08G2101/0083

摘要： The present invention relates to a method for producing an isocyanate-based polymeric material by polymerizing a reaction mixture which comprises different reaction components, including at least one polyisocyanate component and at least one component which is reactive towards said polyisocyanate component. The reaction components comprise at least one anchor component which has at least one anchor group which enables to bond a functional component covalently to the polymeric material. The anchor group is a reactive unsaturated group which does not react during the polymerisation process so that the polymerisation process is not interfered. The anchor group is selected to that it can bind the functional component by a click chemistry reaction to the polymeric material. It is more particularly selected so that it can participate in a catalysed Huisgen 1,3-dipolar cycloaddition reaction or in a Diels-Alder cycloaddition reaction The invention also relates to the obtained isocyanate-based polymeric material, to the use thereof to produce a functionalised polymeric material and to this functionalised polymeric material.

摘要翻译： 本发明涉及通过聚合包含不同反应组分的反应混合物来生产异氰酸酯基聚合物材料的方法，所述反应混合物包括至少一种多异氰酸酯组分和至少一种对所述多异氰酸酯组分具有反应性的组分。 反应组分包含至少一种具有至少一个锚定基团的锚固组分，该锚定基团能够将功能性组分共价结合到聚合物材料上。 锚定基团是在聚合过程中不反应的反应性不饱和基团，使得聚合过程不受干扰。 锚定组被选择为可以通过点击化学反应将功能组分结合到聚合物材料上。 更具体地选择，使得其可以参与催化的Huisgen 1,3-偶极环加成反应或Diels-Alder环加成反应。本发明还涉及获得的异氰酸酯基聚合物材料，其用途是制备官能化的 聚合物材料和该官能化聚合物材料。