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公开(公告)号：US07309798B2
公开(公告)日：2007-12-18
申请号：US11417415
申请日：2006-05-03
IPC分类号： C07C67/36
摘要： A product comprising a lower alkyl ester of a lower aliphatic carboxylic acid is produced by a process comprising reacting a lower alkyl ether with carbon monoxide in the presence of a catalyst comprising mordenite and/or ferrierite, optionally including an additional framework metal such as gallium, boron and/or iron, under substantially anhydrous conditions. More specifically, methyl acetate is selectively produced by reaction of dimethyl ether with carbon monoxide in the presence of a catalyst comprising mordenite or ferrierite, under substantially anhydrous conditions.
摘要翻译： 包含低级脂族羧酸的低级烷基酯的产物是通过包括在包含丝光沸石和/或镁碱沸石的催化剂存在下使低级烷基醚与一氧化碳反应的方法制备的，任选地包括另外的骨架金属如镓， 硼和/或铁。 更具体地说，在基本上无水条件下，在包含丝光沸石或镁碱沸石的催化剂的存在下，通过二甲醚与一氧化碳反应选择性地生产乙酸甲酯。
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公开(公告)号：US07465822B2
公开(公告)日：2008-12-16
申请号：US11639420
申请日：2006-12-15
摘要： A product comprising a lower alkyl ester of a lower aliphatic carboxylic acid is produced by a process comprising reacting under substantially anhydrous conditions a lower alkyl ether with carbon monoxide in the presence of a zeolite catalyst having an 8-member ring channel which is interconnected with a channel defined by a ring with greater than or equal to 8 members, the 8-member ring having a window size of at least 2.5 Angstroms×at least 3.6 Angstroms and at least one Brønsted acid site and the zeolite having a silica:X2O3 ratio of at least 5, wherein X is selected from aluminum, boron, iron, gallium and mixtures thereof.
摘要翻译： 包含低级脂族羧酸的低级烷基酯的产物是通过包括在基本上无水条件下使低级烷基醚与一氧化碳在具有8元环通道的沸石催化剂存在下反应的方法制得的，所述沸石催化剂与 通道由大于或等于8个构件的环限定，8元环的窗口尺寸至少为2.5埃至少为3.6埃和至少一个布朗斯台德酸位点，并且具有至少二氧化硅：X 2 O 3比的沸石 5，其中X选自铝，硼，铁，镓及其混合物。
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3.发明授权Process for carbonylation of aliphatic alcohols and/or ester derivatives thereof 失效脂肪族醇和/或其酯衍生物的羰基化方法公开(公告)号：US07507855B2
公开(公告)日：2009-03-24
申请号：US11639437
申请日：2006-12-15
IPC分类号： C07C67/36
CPC分类号： C07C51/12 , B01J29/06 , B01J29/50 , B01J29/70 , C07C67/36 , C07C53/122 , C07C53/124 , C07C53/08 , C07C69/14
摘要： A product comprising a C1-C3 aliphatic carboxylic acid or corresponding ester is produced by a process comprising carbonylating a C1-C3 aliphatic alcohol or a corresponding ester with carbon monoxide in the presence of a.zeolite catalyst having an 8-member ring channel which is interconnected with a channel defined by a ring with greater than or equal to 8 members, the 8-member ring having a window size of at least 2.5 Angstroms×at least 3.6 Angstroms and at least one Brønsted acid site and the zeolite having a silica:X2O3 ratio of at least 5, wherein X is selected from aluminium, boron, iron, gallium and mixtures thereof with the proviso that the zeolite is not mordenite or ferrierite.
摘要翻译： 包含C 1 -C 3脂族羧酸或相应的酯的产物通过包括在具有8元环通道的沸石催化剂存在下将C1-C3脂族醇或相应的酯与一氧化碳羰基化的方法来制备 与由具有大于或等于8个构件的环限定的通道相互连接，所述8元环的窗口尺寸至少为2.5埃至少为3.6埃和至少一个布朗斯台德酸位点，并且具有二氧化硅：X 2 O 3比例的沸石 至少为5，其中X选自铝，硼，铁，镓及其混合物，条件是沸石不是丝光沸石或镁碱沸石。
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4.发明申请PROCESS FOR CARBONYLATION OF ALIPHATIC ALCOHOLS AND/OR ESTER DERIVATIVES THEREOF 失效脂肪醇和/或酯衍生物的羰基化方法公开(公告)号：US20080146833A1
公开(公告)日：2008-06-19
申请号：US11639437
申请日：2006-12-15
CPC分类号： C07C51/12 , B01J29/06 , B01J29/50 , B01J29/70 , C07C67/36 , C07C53/122 , C07C53/124 , C07C53/08 , C07C69/14
摘要： A product comprising a C1-C3 aliphatic carboxylic acid or corresponding ester is produced by a process comprising carbonylating a C1-C3 aliphatic alcohol or a corresponding ester with carbon monoxide in the presence of a zeolite catalyst having an 8-member ring channel which is interconnected with a channel defined by a ring with greater than or equal to 8 members, the 8-member ring having a window size of at least 2.5 Angstroms×at least 3.6 Angstroms and at least one Brønsted acid site and the zeolite having a silica:X2O3 ratio of at least 5, wherein X is selected from aluminium, boron, iron, gallium and mixtures thereof with the proviso that the zeolite is not mordenite or ferrierite.
摘要翻译： 包含C 1 -C 3脂族羧酸或相应的酯的产物通过包括羰基化C 1 -C 3 在具有8个环形通道的沸石催化剂存在下，使用大于3或大于3个脂肪族醇或相应的酯与一种一氧化碳反应，该沸石催化剂与由大于或等于8个成员的环形成的通道相互连接，8 - 窗口尺寸为至少2.5埃至少为3.6埃和至少一个布朗斯台德酸位的窗口尺寸，并且具有二氧化硅：X 2 O 3比率的沸石为at 至少5，其中X选自铝，硼，铁，镓及其混合物，条件是沸石不是丝光沸石或镁碱沸石。
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公开(公告)号：US20060287551A1
公开(公告)日：2006-12-21
申请号：US11417415
申请日：2006-05-03
申请人： Patricia Cheung , Enrique Iglesia , John Sunley , Aditya Bhan , David Law
发明人： Patricia Cheung , Enrique Iglesia , John Sunley , Aditya Bhan , David Law
IPC分类号： C07C67/36
摘要： A product comprising a lower alkyl ester of a lower aliphatic carboxylic acid is produced by a process comprising reacting a lower alkyl ether with carbon monoxide in the presence of a catalyst comprising mordenite and/or ferrierite, optionally including an additional framework metal such as gallium, boron and/or iron, under substantially anhydrous conditions. More specifically, methyl acetate is selectively produced by reaction of dimethyl ether with carbon monoxide in the presence of a catalyst comprising mordenite or ferrierite, under substantially anhydrous conditions.
摘要翻译： 包含低级脂族羧酸的低级烷基酯的产物是通过包括在包含丝光沸石和/或镁碱沸石的催化剂存在下使低级烷基醚与一氧化碳反应的方法制备的，任选地包括另外的骨架金属如镓， 硼和/或铁。 更具体地说，在基本上无水条件下，在包含丝光沸石或镁碱沸石的催化剂的存在下，通过二甲醚与一氧化碳反应选择性地生产乙酸甲酯。
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公开(公告)号：US20070238897A1
公开(公告)日：2007-10-11
申请号：US11639420
申请日：2006-12-15
申请人： Patricia Cheung , Enrique Iglesia , John Sunley , David Law , Aditya Bhan
发明人： Patricia Cheung , Enrique Iglesia , John Sunley , David Law , Aditya Bhan
IPC分类号： C07C67/00
摘要： A product comprising a lower alkyl ester of a lower aliphatic carboxylic acid is produced by a process comprising reacting under substantially anhydrous conditions a lower alkyl ether with carbon monoxide in the presence of a zeolite catalyst having an 8-member ring channel which is interconnected with a channel defined by a ring with greater than or equal to 8 members, the 8-member ring having a window size of at least 2.5 Angstroms×at least 3.6 Angstroms and at least one Brønsted acid site and the zeolite having a silica:X2O3 ratio of at least 5, wherein X is selected from aluminum, boron, iron, gallium and mixtures thereof.
摘要翻译： 包含低级脂族羧酸的低级烷基酯的产物是通过包括在基本上无水条件下使低级烷基醚与一氧化碳在具有8元环通道的沸石催化剂存在下反应的方法制得的，所述沸石催化剂与 通道由大于或等于8个构件的环限定，8元环的窗口尺寸至少为2.5埃至少为3.6埃和至少一个布朗斯台德酸位点，并且沸石具有二氧化硅：X 2 至少5，其中X选自铝，硼，铁，镓及其混合物。
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公开(公告)号：US20060252959A1
公开(公告)日：2006-11-09
申请号：US11123581
申请日：2005-05-05
申请人： Patricia Cheung , Enrique Iglesia , John Sunley
发明人： Patricia Cheung , Enrique Iglesia , John Sunley
IPC分类号： C07C67/36
摘要： A product comprising a lower alkyl ester of a lower aliphatic carboxylic acid is produced by a process comprising reacting a lower alkyl ether with carbon monoxide in the presence of a catalyst comprising mordenite and/or ferrierite, under substantially anhydrous conditions. More specifically, methyl acetate is selectively produced by reaction of dimethyl ether with carbon monoxide in the presence of a catalyst comprising mordenite or ferrierite, under substantially anhydrous conditions.
摘要翻译： 包含低级脂族羧酸的低级烷基酯的产物是通过包括在基本上无水条件下在包含丝光沸石和/或镁碱沸石的催化剂存在下使低级烷基醚与一氧化碳反应的方法制备的。 更具体地说，在基本上无水条件下，在包含丝光沸石或镁碱沸石的催化剂的存在下，通过二甲醚与一氧化碳反应选择性地生产乙酸甲酯。
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8.发明申请Novel immobilized calixarenes and related compounds and process for their production 审中-公开新型固定化杯芳烃及相关化合物及其生产工艺公开(公告)号：US20050255332A1
公开(公告)日：2005-11-17
申请号：US11187195
申请日：2005-07-21
CPC分类号： B01J31/2295 , B01J20/3204 , B01J20/3219 , B01J20/3248 , B01J20/3253 , B01J31/066 , B01J31/1633 , B01J2231/321 , B01J2231/50 , B01J2231/60 , B01J2531/16 , Y10T428/31663 , Y10T428/31942
摘要： Immobilized calixarenes and calixarene-related compounds are produced by a process comprising either: (a) contacting the calixarene or calixarene-related compound with a substrate containing one or more metallic or non-metallic oxides that has been surface modified by reaction with one or more polyhalides and/or polyalkoxides of an element capable of forming a stable aryloxide species with the substrate, or (b) reaction of such a substrate with a calixarene or calixarene-related compound that has been previously modified or derivatized by reaction with said polyhalides and/or polyalkoxides.
摘要翻译： 固定化的杯芳烃和杯芳烃相关化合物通过以下方法制备，该方法包括：（a）将杯芳烃或杯芳烃相关化合物与含有一种或多种金属或非金属氧化物的基质接触，所述金属或非金属氧化物通过与一种或多种 能够与底物形成稳定的芳氧基物质的元素的多卤化物和/或多烷氧化物，或（b）这种底物与杯芳烃或杯芳烃相关化合物的反应，其已经通过与所述多卤化物和/ 或多烷氧化物。
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9.发明授权Immobilized calixarenes and related compounds and process for their production 有权固定的杯芳烃和相关化合物及其生产方法公开(公告)号：US06951690B2
公开(公告)日：2005-10-04
申请号：US10394904
申请日：2003-03-21
CPC分类号： B01J31/2295 , B01J20/3204 , B01J20/3219 , B01J20/3248 , B01J20/3253 , B01J31/066 , B01J31/1633 , B01J2231/321 , B01J2231/50 , B01J2231/60 , B01J2531/16 , Y10T428/31663 , Y10T428/31942
摘要： Immobilized calixarenes and calixarene-related compounds are produced by a process comprising either: (a) contacting the calixarene or calixarene-related compound with a substrate containing one or more metallic or non-metallic oxides that has been surface modified by reaction with one or more polyhalides and/or polyalkoxides of an element capable of forming a stable aryloxide species with the substrate, or (b) reaction of such a substrate with a calixarene or calixarene-related compound that has been previously modified or derivatized by reaction with said polyhalides and/or polyalkoxides.
摘要翻译： 固定化的杯芳烃和杯芳烃相关化合物通过以下方法制备，该方法包括：（a）将杯芳烃或杯芳烃相关化合物与含有一种或多种金属或非金属氧化物的基质接触，所述金属或非金属氧化物通过与一种或多种 能够与底物形成稳定的芳氧基物质的元素的多卤化物和/或多烷氧化物，或（b）这种底物与杯芳烃或杯芳烃相关化合物的反应，其已经通过与所述多卤化物和/ 或多烷氧化物。
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公开(公告)号：US06763309B2
公开(公告)日：2004-07-13
申请号：US10068244
申请日：2002-02-05
IPC分类号： G01N3100
CPC分类号： B01J19/0046 , B01J2219/00274 , B01J2219/00286 , B01J2219/00391 , B01J2219/00423 , B01J2219/00495 , B01J2219/00587 , B01J2219/00596 , B01J2219/007 , B01J2219/00745 , B01J2219/00747 , C40B30/02 , C40B30/08 , C40B40/18 , C40B50/02 , C40B60/14 , G06F19/706 , G06F19/707
摘要： A catalyst development engine (CDE) provides a rapid approach to the rational development of scalable heterogeneous catalysts and of high-performance solid materials. The CDE includes three main components: the testing cycle, the knowledge cycle, and the knowledge repository or database. The knowledge cycle generates working hypotheses relating performance to key catalyst properties via machine learning methods, computation chemistry and micro-kinetic modeling. Such an approach accelerates development and scale-up of new materials without the impediments introduced by conventional combinatorial approaches based on randomly selected materials.
摘要翻译： 催化剂开发引擎（CDE）为可扩展的非均相催化剂和高性能固体材料的合理开发提供了快速的方法。 CDE包括三个主要组成部分：测试周期，知识周期以及知识库或数据库。 知识循环通过机器学习方法，计算化学和微动力学建模产生了关键催化剂性能的工作假说。 这种方法加速了新材料的开发和扩大，而没有基于随机选择的材料的常规组合方法引入的障碍。
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