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公开(公告)号:US20170297258A1
公开(公告)日:2017-10-19
申请号:US15446487
申请日:2017-03-01
申请人: Patrick Mather , Pine Yang , Xiaofan Luo , Andrew M. DiOrio
发明人: Patrick Mather , Pine Yang , Xiaofan Luo , Andrew M. DiOrio
IPC分类号: B29C61/06 , C08F220/12 , C08F220/14 , C08L71/02 , C08L63/00 , C08L75/04
CPC分类号: B29C61/06 , C08F220/12 , C08F220/14 , C08G2280/00 , C08L63/00 , C08L71/02 , C08L75/04 , C08L2205/05 , Y10T428/24479 , Y10T428/24628 , Y10T428/24983 , C08L33/04
摘要: A functionally graded shape memory polymer (SMP) that has a range of transition temperatures that are spatially distributed in a gradient fashion within one single article. The SMP is formed by post-curing a pre-cured glassy SMP in a linear temperature gradient that imposes different vitrification temperature limits at different positions along the gradient. Utilizing indentation-based surface shape memory coupled with optical measurements of photoelastic response, the capability of this material to respond over a wide range of thermal triggers is correlated with the graded glass transition behavior. This new class of SMP offers great potential for such applications as passive temperature sensing and precise control of shape evolution during a thermally triggered shape recovery.
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公开(公告)号:US20120213969A1
公开(公告)日:2012-08-23
申请号:US13401606
申请日:2012-02-21
申请人: Patrick Mather , Pine Yang , Xiaofan Luo , Andrew M. DiOrio
发明人: Patrick Mather , Pine Yang , Xiaofan Luo , Andrew M. DiOrio
IPC分类号: B32B7/02 , C08F220/14 , C08G65/08 , C08G63/127 , C08F12/08 , C08G18/06 , C08F14/06 , C08F220/12 , C08F2/48 , C08J3/28 , C08G63/78 , C08G18/08 , B32B27/08 , B32B15/08 , B32B33/00 , C08G65/34
CPC分类号: B29C61/06 , C08F220/12 , C08F220/14 , C08G2280/00 , C08L63/00 , C08L71/02 , C08L75/04 , C08L2205/05 , Y10T428/24479 , Y10T428/24628 , Y10T428/24983 , C08L33/04
摘要: A functionally graded shape memory polymer (SMP) that has a range of transition temperatures that are spatially distributed in a gradient fashion within one single article. The SMP is formed by post-curing a pre-cured glassy SMP in a linear temperature gradient that imposes different vitrification temperature limits at different positions along the gradient. Utilizing indentation-based surface shape memory coupled with optical measurements of photoelastic response, the capability of this material to respond over a wide range of thermal triggers is correlated with the graded glass transition behavior. This new class of SMP offers great potential for such applications as passive temperature sensing and precise control of shape evolution during a thermally triggered shape recovery.
摘要翻译: 功能梯度的形状记忆聚合物(SMP),其具有在一个单一制品内以梯度方式空间分布的转变温度范围。 SMP通过在线性温度梯度下固化预固化的玻璃状SMP而形成,该梯度在梯度的不同位置施加不同的玻璃化温度极限。 利用基于压痕的表面形状记忆耦合光弹性响应的光学测量,该材料在宽范围的热触发器上的响应能力与渐变玻璃化转变行为相关。 这种新型的SMP在热触发形状恢复期间为诸如被动温度感测和形状演化的精确控制等应用提供了巨大的潜力。
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公开(公告)号:US08683798B2
公开(公告)日:2014-04-01
申请号:US13006024
申请日:2011-01-13
申请人: Patrick Mather , Xiaofan Luo
发明人: Patrick Mather , Xiaofan Luo
CPC分类号: B29C70/882 , B82Y30/00
摘要: Embodiments of a product such as a stimuli-responsive product can comprise a shape memory component and a nanofiber component that forms a fibrous microstructure or network. The resulting product can be responsive to stimuli, such as electrical stimuli, in a manner that cause the product to deform, deflect, and rebound. In one embodiment, the product can comprise an epoxy and a continuous non-woven nanofiber, the combination of which provides a product with enhanced actuation speed.
摘要翻译: 诸如刺激响应产物的产品的实施方案可以包括形成记忆组分和形成纤维微结构或网络的纳米纤维组分。 所得到的产品可以以引起产品变形,偏转和回弹的方式对刺激(例如电刺激)起反应。 在一个实施方案中,产品可以包含环氧树脂和连续的无纺纳米纤维,其组合提供具有增强的致动速度的产品。
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公开(公告)号:US20110003159A1
公开(公告)日:2011-01-06
申请号:US12644766
申请日:2009-12-22
申请人: Patrick Mather , Xiaofan Luo
发明人: Patrick Mather , Xiaofan Luo
CPC分类号: B32B7/02 , B32B27/08 , B32B27/12 , B32B27/20 , B32B27/30 , B32B27/36 , B32B27/40 , B32B2262/02 , B32B2262/0269 , B32B2262/101 , B32B2262/106 , B32B2264/10 , B32B2307/302 , B32B2307/702 , B32B2307/704 , B32B2307/7163 , Y10T428/31601
摘要: Embodiments of a self-healing product comprise a shape memory component and a healing component interpenetrating the shape memory component to form a fibrous microstructure. This microstructure can facilitate healing and mending mechanisms, wherein in one embodiment the healing component is selected so as to diffuse into a defect when the area of the product with the defect is subject to a treatment. This treatment can vary the temperature of the self-healing product, with the temperatures in one example being at or above a melting temperature (Tm) and/or a glass transition temperature (Tg) for one or both of the shape memory component and the healing component. The self-healing product can also comprise a substrate so that deposition of one or more of the shape memory component and the healing component onto the substrate can form a coating or material layer the likes of which can protect the subjacent substrate while also providing the healing properties responsive to the treatment.
摘要翻译: 自修复产品的实施方案包括形状记忆组分和互穿形状记忆组分的愈合组分以形成纤维组织。 这种微观结构可以促进愈合和修补机制,其中在一个实施方案中,当具有缺陷的产品的面积经受治疗时,选择愈合组分以扩散到缺陷中。 这种处理可以改变自愈产品的温度,一个实例中的温度等于或高于形状记忆组分和/或形状记忆组分的一个或两个的熔融温度(Tm)和/或玻璃化转变温度(Tg) 治疗组件。 自修复产品还可以包括基底,使得形状记忆组分和愈合组分中的一种或多种沉积到基底上可以形成涂层或材料层,其中可以保护下面的底物同时还提供愈合 响应于治疗的性质。
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公开(公告)号:US09878487B2
公开(公告)日:2018-01-30
申请号:US13039757
申请日:2011-03-03
申请人: Patrick Mather , Xiaofan Luo
发明人: Patrick Mather , Xiaofan Luo
CPC分类号: B29C61/0633 , B29C61/003 , Y10T428/249921 , Y10T428/269
摘要: Multi-shape products of the present disclosure comprise two components: a matrix component and a fiber component that is embedded or otherwise disposed in the matrix component. The matrix component exhibits certain shape memory properties. The fiber component interpenetrates the matrix component to facilitate fixing of the multi-shape product in various temporary shapes.
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公开(公告)号:US09533469B2
公开(公告)日:2017-01-03
申请号:US12644766
申请日:2009-12-22
申请人: Patrick Mather , Xiaofan Luo
发明人: Patrick Mather , Xiaofan Luo
IPC分类号: B32B9/04 , B32B17/10 , C08L75/04 , B32B7/02 , B32B27/08 , B32B27/12 , B32B27/20 , B32B27/30 , B32B27/36 , B32B27/40
CPC分类号: B32B7/02 , B32B27/08 , B32B27/12 , B32B27/20 , B32B27/30 , B32B27/36 , B32B27/40 , B32B2262/02 , B32B2262/0269 , B32B2262/101 , B32B2262/106 , B32B2264/10 , B32B2307/302 , B32B2307/702 , B32B2307/704 , B32B2307/7163 , Y10T428/31601
摘要: A self-healing product having a shape memory component and a healing component interpenetrating the shape memory component to form a fibrous microstructure. The healing component is selected so as to diffuse into a defect when the area of the product with the defect is subject to a treatment. The components may be selected so that applying heat at a temperature at or above a melting temperature (Tm) and/or a glass transition temperature (Tg) for one or both of the shape memory component and the healing component causes shape memory transition and diffusion by the healing component. The self-healing product can form a coating or material layer to protect a substrate while also providing the healing properties responsive to the treatment.
摘要翻译: 具有形状记忆组分和愈合组分的自愈产物互穿形状记忆组分以形成纤维组织。 选择愈合组分,以便在具有缺陷的产品的面积经受治疗时扩散到缺陷中。 可以选择组分,使得在形状记忆组分和愈合组分中的一种或两种的熔解温度(Tm)和/或玻璃化转变温度(Tg)的温度下进行加热导致形状记忆转变和扩散 由愈合部件。 自愈产品可以形成涂层或材料层以保护基底,同时还提供响应于治疗的愈合特性。
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公开(公告)号:US10471648B2
公开(公告)日:2019-11-12
申请号:US15446487
申请日:2017-03-01
申请人: Patrick Mather , Xiaofan Luo , Andrew M. DiOrio , Kyung-Min Lee
发明人: Patrick Mather , Xiaofan Luo , Andrew M. DiOrio , Kyung-Min Lee
IPC分类号: B29C61/06 , C08F220/12 , C08F220/14 , C08L63/00 , C08L71/02 , C08L75/04
摘要: A functionally graded shape memory polymer (SMP) that has a range of transition temperatures that are spatially distributed in a gradient fashion within one single article. The SMP is formed by post-curing a pre-cured glassy SMP in a linear temperature gradient that imposes different vitrification temperature limits at different positions along the gradient. Utilizing indentation-based surface shape memory coupled with optical measurements of photoelastic response, the capability of this material to respond over a wide range of thermal triggers is correlated with the graded glass transition behavior. This new class of SMP offers great potential for such applications as passive temperature sensing and precise control of shape evolution during a thermally triggered shape recovery.
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公开(公告)号:US20110217547A1
公开(公告)日:2011-09-08
申请号:US13039757
申请日:2011-03-03
申请人: Patrick Mather , Xiaofan Luo
发明人: Patrick Mather , Xiaofan Luo
CPC分类号: B29C61/0633 , B29C61/003 , Y10T428/249921 , Y10T428/269
摘要: Multi-shape products of the present disclosure comprise two components: a matrix component and a fiber component that is embedded or otherwise disposed in the matrix component. The matrix component exhibits certain shape memory properties. The fiber component interpenetrates the matrix component to facilitate fixing of the multi-shape product in various temporary shapes.
摘要翻译: 本公开的多形状产品包括两个部件:嵌入或以其他方式设置在矩阵部件中的矩阵部件和纤维部件。 矩阵分量表现出一定的形状记忆特性。 纤维组分互穿基体组分以便于多种形状的产品以各种临时形状的固定。
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公开(公告)号:US20110173971A1
公开(公告)日:2011-07-21
申请号:US13006024
申请日:2011-01-13
申请人: Patrick Mather , Xiaofan Luo
发明人: Patrick Mather , Xiaofan Luo
CPC分类号: B29C70/882 , B82Y30/00
摘要: Embodiments of a product such as a stimuli-responsive product can comprise a shape memory component and a nanofiber component that forms a fibrous microstructure or network. The resulting product can be responsive to stimuli, such as electrical stimuli, in a manner that cause the product to deform, deflect, and rebound. In one embodiment, the product can comprise an epoxy and a continuous non-woven nanofiber, the combination of which provides a product with enhanced actuation speed.
摘要翻译: 诸如刺激响应产物的产品的实施方案可以包括形成记忆组分和形成纤维微结构或网络的纳米纤维组分。 所得到的产品可以以引起产品变形,偏转和回弹的方式对刺激(例如电刺激)起反应。 在一个实施方案中,产品可以包含环氧树脂和连续的无纺纳米纤维,其组合提供具有增强的致动速度的产品。
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公开(公告)号:US09249305B2
公开(公告)日:2016-02-02
申请号:US14506162
申请日:2014-10-03
申请人: Aaron S. Puhala , James W. Hoover , Xiaofan Luo
发明人: Aaron S. Puhala , James W. Hoover , Xiaofan Luo
摘要: This invention is based upon the discovery that activated carbon can be used to sequester polycyclic aromatic hydrocarbons that may be present in asphalt and creosote compositions. The treatment of asphalt and creosote compositions with activated carbon accordingly reduces the level of free polycyclic aromatic hydrocarbons in such compositions by sequestering them therein or removing them from the composition. After being sequestered the polycyclic aromatic hydrocarbons remain trapped in the asphalt or creosote composition, and are not available to the environment during normal processing into useful industrial products. This sequestration reduces the risk of exposing humans and the environment to the polycyclic aromatic hydrocarbons which would otherwise be free to migrate from the asphalt or creosote product during manufacturing and the service life of the product. In other words, the polycyclic aromatic hydrocarbons are absorbed onto the activated carbon and are not available for bioaccumulation from the environment.
摘要翻译: 本发明基于以下发现:活性炭可用于螯合可能存在于沥青和杂酚油组合物中的多环芳烃。 用活性炭处理沥青和杂酚油组合物相应地降低了这些组合物中游离多环芳烃的含量,其中将它们封存在其中或将其从组合物中除去。 被隔离后,多环芳烃被捕获在沥青或杂酚油组合物中,并且在正常加工成有用的工业产品期间不能被环境使用。 这种隔离降低了将人类和环境暴露于多环芳烃的风险,多环芳烃在制造过程中和产品的使用寿命期间可能会从沥青或杂酚油产品中自由迁移。 换句话说,多环芳烃被吸收到活性炭上,不能用于从环境的生物累积。
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