Tire compounds containing syndiotactic-1,2-polybutadiene
    1.
    发明授权
    Tire compounds containing syndiotactic-1,2-polybutadiene 失效
    含间同立构1,2-聚丁二烯的轮胎化合物

    公开(公告)号:US4790365A

    公开(公告)日:1988-12-13

    申请号:US95205

    申请日:1987-09-11

    CPC classification number: C08L9/00 B60C1/0008 C09J123/283 C08L15/02 Y10S152/16

    Abstract: The subject invention discloses the use of syndiotactic-1,2-polybutadiene in the supporting carcass and/or innerliner of a tire. The incorporation of syndiotactic-1,2-polybutadiene into rubber compositions which are utilized in the supporting carcass or innerliner of tires greatly improves the green strength of those compositions. The incorporation of syndiotactic-1,2-polybutadiene into halogenated butyl rubbers which are utilized as innerliner compositions also greatly improves the scorch safety of such compositions. The subject invention more specifically discloses a pneumatic rubber tire which comprises a circumferential rubber tread, a supporting carcass therefor, two spaced beads, two rubber sidewalls connecting said beads and an innerliner; wherein said supporting carcass is comprised of from 1 to 25 phr of syndiotactic-1,2-polybutadiene having a melting point which is within the range of 120.degree. C. to 190.degree. C. and at least one rubber selected from the group consisting of polyisoprene, styrene-butadiene rubber, and polybutadiene rubber.

    Tire with tread of elastomer composition
    4.
    发明授权
    Tire with tread of elastomer composition 失效
    轮胎与弹性体组成的胎面

    公开(公告)号:US5504140A

    公开(公告)日:1996-04-02

    申请号:US315476

    申请日:1994-09-30

    CPC classification number: C08L9/00 B60C1/0016 C08L9/06 C08L7/00 Y02T10/862

    Abstract: Pneumatic rubber tire with a tread composed of a rubber blend of a base of at least two synthetic elastomers composed of (i) specialized isoprene/butadiene copolymer elastomer having a low Tg in a range of about -70.degree. to about -100.degree. C. and (ii) a diene based elastomer having a Tg in a range of about -5.degree. to about -30.degree. C. together with a minor amount of natural cis 1,4-polyisoprene rubber. Selection of the base of the said two synthetic elastomers having spaced apart, or spatially defined, Tg's of at least 40.degree. C. is an important feature of the tread rubber blend. Representative examples of contemplated elastomers with Tg's in a range of about -5.degree. to about -30.degree. C. are 3,4-polyisoprene elastomer, styrene/isoprene copolymer elastomer and high vinyl polybutadiene elastomers.In one aspect, the tread rubber blend is reinforced with reinforcing filler composed of carbon black or a combination of carbon black and silica accompanied by a coupling agent.

    Abstract translation: 具有胎面的气动橡胶轮胎,其由至少两种合成弹性体的基底的橡胶共混物组成,所述合成弹性体由(i)具有约-70℃至约-100℃范围内的低Tg的特殊异戊二烯/丁二烯共聚物弹性体组成。 和(ii)Tg在约-5℃至约-30℃范围内的二烯基弹性体以及少量天然顺式1,4-聚异戊二烯橡胶。 具有至少40℃的间隔或空间限定的Tg的所述两种合成弹性体的基底的选择是胎面橡胶共混物的重要特征。 具有Tg在约-5℃至约-30℃范围内的预期弹性体的代表性实例是3,4-聚异戊二烯弹性体,苯乙烯/异戊二烯共聚物弹性体和高乙烯基聚丁二烯弹性体。 在一个方面,胎面橡胶共混物用伴随着偶联剂的炭黑或炭黑和二氧化硅的组合的增强填料增强。

    Sulfur cured rubber composition containing epoxidized natural rubber and
carboxylated nitrile rubber
    5.
    发明授权
    Sulfur cured rubber composition containing epoxidized natural rubber and carboxylated nitrile rubber 失效
    硫化橡胶组合物含有环氧化天然橡胶和羧化丁腈橡胶

    公开(公告)号:US5488077A

    公开(公告)日:1996-01-30

    申请号:US452929

    申请日:1995-05-30

    CPC classification number: C08K3/36 B60C1/0016 C08L21/00 Y10S152/905

    Abstract: The present invention relates to a sulfur cured rubber composition particularly suited for use in tire treads. The sulfur cured rubber composition is composed of based on 100 parts by weight of rubber, from about 1.0 to 15 parts by weight of epoxidized rubber; from about 1.0 to 15 parts by weight of a carboxylated nitrile rubber; and 98 to 70 parts by weight of a rubber selected from the group consisting of medium vinyl polybutadiene, styrene-butadiene rubber, synthetic cis-1,4-polyisoprene, synthetic 3,4-polyisoprene, natural rubber, cis-polybutadiene, styrene-isoprene rubber, styrene-isoprene-butadiene rubber, acrylonitrile-butadiene rubber and mixtures thereof.

    Abstract translation: 本发明涉及一种特别适用于轮胎胎面的硫化橡胶组合物。 硫化橡胶组合物由100重量份橡胶,约1.0-15重量份环氧化橡胶组成, 约1.0至15重量份的羧化丁腈橡胶; 和98〜70重量份选自中等乙烯基聚丁二烯,苯乙烯 - 丁二烯橡胶,合成顺式-1,4-聚异戊二烯,合成3,4-聚异戊二烯,天然橡胶,顺式聚丁二烯,苯乙烯 - 异戊二烯橡胶,苯乙烯 - 异戊二烯 - 丁二烯橡胶,丙烯腈 - 丁二烯橡胶及其混合物。

    Tire with tread composition
    7.
    发明授权
    Tire with tread composition 失效
    轮胎与胎面组成

    公开(公告)号:US5341863A

    公开(公告)日:1994-08-30

    申请号:US062263

    申请日:1993-05-17

    CPC classification number: C08L21/00 Y10S152/905

    Abstract: A pneumatic tire having a sulfur cured tread is provided comprised of at least one diene rubber and a low density polyethylene having a crystalline melt point in a range of about 104.degree. C. to about 115.degree. C., wherein the said LDPE is mixed with the said rubber at a temperature of about 120.degree. C. to about 170.degree. C. prior to sulfur vulcanizing the blend.A process is also provided for producing a tire in which a hot cured tire is removed from its rigid mold where the tread is comprised of at least one diene rubber and a low density polyethylene (LDPE) having a crystalline melt point in a range of about 104.degree. C. to about 115.degree. C.; and wherein the said LDPE is mixed with the said unvulcanized rubber at a temperature of about 120.degree. C. to about 170.degree. C.

    Abstract translation: 提供了具有硫硫化胎面的充气轮胎,其由至少一种二烯橡胶和具有约104℃至约115℃范围内的结晶熔点的低密度聚乙烯组成,其中所述LDPE与 所述橡胶在硫化硫化混合物之前在约120℃至约170℃的温度下进行。 还提供了一种用于生产轮胎的方法,其中热硬化轮胎从其刚性模具中去除,其中胎面由至少一种二烯橡胶和低密度聚乙烯(LDPE)组成,其中结晶熔点在约 104℃至约115℃。 并且其中所述LDPE与所述未硫化橡胶在约120℃至约170℃的温度下混合。

    Secondary vulcanization accelerator
    10.
    发明授权
    Secondary vulcanization accelerator 失效
    二次硫化促进剂

    公开(公告)号:US4855364A

    公开(公告)日:1989-08-08

    申请号:US302521

    申请日:1989-01-27

    CPC classification number: C08K5/17

    Abstract: It is often desirable to utilize accelerators in the sulfur vulcanization of unsaturated rubbers. In many cases a primary accelerator is used in combination with another accelerator, called a secondary accelerator or activator, which further increases the rate of vulcanization. It has been determined that compounds having the structural formula:NH.sub.2 --A--NH--(CH.sub.2).sub.x NH].sub.n A--NH.sub.2wherein x is 2 or 3, wherein n is an integer from 1 to 100, and wherein A represents an alkylene group containing from 1 to 20 carbons atoms, act as secondary accelerators in the vulcanization of unsaturated rubbers. For example, it has been determined that 4,7-diaza-decane-1,10-diamine is a particularly desirable secondary accelerator.

    Abstract translation: 通常希望在不饱和橡胶的硫磺硫化中使用促进剂。 在许多情况下,主促进剂与另一促进剂(称为次级促进剂或活化剂)组合使用,这进一步提高了硫化速率。 已经确定具有以下结构式的化合物:NH 2 -A-NH-(CH2)xNH] nA-NH2其中x为2或3,其中n为1至100的整数,并且其中A表示含有 1〜20个碳原子,作为不饱和橡胶硫化的二次加速剂。 例如,已经确定4,7-二氮杂 - 癸烷-1,10-二胺是特别期望的二次加速剂。

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