摘要:
The present invention relates to coating agents containingA) one or more polymers containing carboxyl groups and having a number-average molecular weight of 500 to 8,000 and an acid number of 15 to 200 mg of KOH/g as the essential binder component andB) one or more compounds containing epoxide groups as crosslinking agents,wherein the compound B containing epoxide groups is a copolymer containing epoxide groups, has a number-average molecular weight M.sub.n of 300 to 5,000, preferably 500 to 3,500, and a heterogeneity (M.sub.w /M.sub.n), measured by gel permeation chromatography, of .ltoreq.3, preferably of .ltoreq.2, and has been prepared by continuous bulk polymerization at temperatures between 130.degree. and 350.degree. C. and pressures above 1 bar.The invention also relates to processes for the preparation of the coating agent and the use of the coating agents in automobile refinishing.
摘要:
The present invention relates to a solution of a polyacrylate resin in one or more organic solvents, containing one or more phosphites, characterized in that the solution contains from 0.05 to 1.0% by weight, based on the solids content of the acrylate resin solution, of one or more phosphites and in that the phosphite has been added, either partially or entirely, after the polymerization reaction, at a temperature below the polymerization temperature.The present invention further relates to coating compositions which contain these polyacrylate resin solutions, their use in processes for producing a multilayer protective and/or decorative coating on a substrate surface, and the use of the coating compositions in the automotive refinishing sector.
摘要:
The invention relates to copolymers containing on average 1.25 to 30 functional groups per molecule and a number average molecular weight of 1500 to 6000, which copolymers can be prepared by free-radical solution polymerization at 130.degree. to 200.degree. C. from 5 to 25% by weight of vinyl ester, 10 to 50% by weight of vinyl aromatic, 10 to 40% by weight of functional, monomers and, if desired further monomers, in which the vinyl ester is initially introduced and the remaining monomers are metered in for all monomers over a monomer addition period which is of the same length in the following manner: The amount of acrylate monomers added per unit of time remains constant. The amount of vinyl aromatic added over the first third of the monomer addition period is 15 to 30% by weight, the amount added over the second third is 25 to 40% by weight, and the amount added over the last third is 35 to 60% by weight, each relative to the total amount of vinyl aromatic. The copolymer obtained is, if desired, reacted with compounds containing a group which is reactive towards the functional groups of the copolymer and at least one crosslinkable group.
摘要:
The present invention relates to coating agents based on hydroxyl-containing binders and isocyanate-containing crosslinking agents, in which coating agentsI.) the binder comprisesA1) 5 to 80% by weight of at least one polyester or one alkyd resin having an OH number from 0 to 200 mg of KOH/g and an acid number from 0 to 200 mg of KOH/g,A2) 95 to 20% by weight of at least one polyacrylate having an OH number from 30 to 250 mg of KOH/g and an acid number from 0 to 50 mg of KOH/g, the sum of the weight proportions of components (A1) and (A2) being in each case 100% by weight, andII.) the binder is obtainable from1.) at least one polycondensation resin whose acid component comprises 5 to 100 mol % of cycloaliphatic polycarboxylic acids and/or esterifiable derivatives thereof,2.) at least one polyacrylate, at least some of which has been prepared in the presence of the polycondensation resin obtained in the first process step and3.) if desired, at least one further Polyaddition and/or one further Polycondensation resin.
摘要:
The present invention relates to coating material compositions comprising at least one polyhydroxyl group-containing compound (A), at least one polyisocyanate group-containing compound (B) having free and/or blocked isocyanate groups, and at least one catalyst (D) based on a zinc-amidine complex which is preparable by reaction of 1.0 moles of at least one zinc(II) biscarboxylate with 2.0 moles of at least one amidine where R5=hydrogen and R1, R2, R3, and R4 are each identical or different radicals, R1 and R3 being hydrogen or an alkyl radical or an aryl radical, and R2 and R4 being an alkyl radical or an aryl radical, characterized in that the coating material composition further comprises at least one monomeric aromatic, optionally substituted carboxylic acid (S) whose carboxyl group is in conjugation with a π-electron system.
摘要:
The invention concerns a pharmaceutical preparation which improves penetration of active substances through the tissue membrane or barrier of the target organ.
摘要:
A cyclone separator (1) has a vertically extending housing (2) with an upper housing segment (3). A separator (6) with a separator wheel is located in the upper housing segment along with a carrier gas/product inlet (7), and a carrier gas/fines discharge (8). A lower housing segment (5) is equipped with a coarse grain discharge (14). In order to increase the operating range of the cyclone separator, the lower opening of the central built-in element (10) is located at the level of the conical middle housing segment (4) and that below the lower opening is disposed a conical built-in element (11), which has the shape of a cone expanding in downward direction.
摘要:
A cyclone separator (1) has an elongated vertical housing (2), whose upper section (3) is equipped with a carrier gas/product inlet (4), a separating wheel (6), and a carrier gas/fine product discharge (7). A lower section (9) of the housing defines an oversized product discharge (11). The housing (2) has a central axially extending built-in unit (12), which separates the cyclone carrier gas/particle flow stream, downwardly in a peripheral region, and upwardly in a central region. A lower built-in unit section (14) is joined to a cylindrical middle built-in unit section (15). An entry area of the middle section (15) is equipped with a constrictor (19) which with the built-in body forms a Venturi. Finally, a secondary air supply (24) enters into a lower inlet opening (9) of the lower built-in unit section (14) facing the constrictor (19). An injector effect is achieved which increases the suction, resulting in further improvement of the separating and sorting properties.
摘要:
For winding webs of material on cores winding machines have two support rollers on which the winding rolls are supported during winding. The web is guided from underneath through the gap between the support cylinders. When the winding rolls are exchanged, for the cutting of the web a cutting knife with a tear-off blade is raised through the gap between the support cylinders up to the cylinder bed. In order to reduce the bearing load of the winding rolls on the support cylinders in the lower wedge between the two support cylinders an air box extending over the work width and having a compressed air supply line is provided, which seals the gap between the support cylinders and has an air exit slot open towards this gap. The tear-off blade of the cutting knife is attached to a support arranged in the air box and can be moved up and down through the air exit slot into the cutting position in the cylinder bed and completely lowered into the air box.
摘要:
A carbon brush for a collector has a recess which is filled with a layer of galvanically applied, copper plating, in which at least one longitudinal wire is provided as a connecting conductor, which is mechanically and electrically linked with the brush through being embedded in and completely surrounded by the copper layer.