公开(公告)号：US4769457A

公开(公告)日：1988-09-06

申请号：US895934

申请日：1986-08-13

申请人： Reinhard Helwig ,  Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

发明人： Reinhard Helwig ,  Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

IPC分类号： C07C20060101 ,  C07D20060101 ,  C07D487/22 ,  C07D519/00 ,  C08F20060101 ,  C08G12/26 ,  C08K20060101 ,  C08K5/00 ,  C08K5/34 ,  C08K5/3477 ,  C08K5/3492 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L61/20 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00 ,  C07D251/00

CPC分类号： C07D487/22 ,  C07D519/00 ,  C08G12/263 ,  C08K5/34

摘要： The novel compounds of the general formula I ##STR1## where n is from 1 to 70,R.sup.1 and R.sup.2 independently of one another are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.7 -C.sub.12 -aralkyl, aryl or a carboxylic ester group, orR.sup.1 and R.sup.2 together may form a tetramethylene or pentamethylene group,R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each alkyl, the radicalsX independently of one another are each a direct bond or a bridge member,Y and Z are each oxygen, sulfur or NR.sup.8,R.sup.7 is hydrogen, chlorine, bromine, hydroxyl, alkoxy, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl and R.sup.8 is hydrogen or unsubstituted or substituted alkyl, and the ammonium salts of these compounds, are very useful as light stabilizers.

摘要翻译： 通式Ⅰ的新化合物，其中n为1至70，R 1和R 2彼此独立地为氢，C 1 -C 6 - 烷基，C 7 -C 12 - 芳烷基，芳基或 羧酸酯基或R 1和R 2可以一起形成四亚甲基或五亚甲基，R 3，R 4，R 5和R 6各自为烷基，基团X彼此独立地各自为直接键或桥状部分，Y和Z为 每个氧，硫或NR8，R7是氢，氯，溴，羟基，烷氧基，羧基，羧酸酯基或未取代或取代的氨基甲酰基，R8是氢或未取代或取代的烷基，这些化合物的铵盐是非常 用作光稳定剂。

公开(公告)号：US5072034A

公开(公告)日：1991-12-10

申请号：US627895

申请日：1990-12-13

申请人： Peter Neumann ,  Heinz Eilingsfeld ,  Alexander Aumueller

发明人： Peter Neumann ,  Heinz Eilingsfeld ,  Alexander Aumueller

IPC分类号： C07C309/42 ,  C07C303/08 ,  C07C309/44 ,  C07C309/59

CPC分类号： C07C303/08

摘要： 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by halogen, cyanao, hydroxyl, C.sub.1 -C.sub.20 -alkoxy, C.sub.2 -C.sub.20 -alkoxycarbonyl, acyloxy and/or phenyl which is unsubstituted or substituted by C.sub.1 -c.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and/or halogen, R.sup.2 and R.sup.3 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.4 -C.sub.12 -cycloalkylalkyl, cyano, hydroxyl or hydroxyethyl or are each phenoxy, C.sub.7 -C.sub.10 -phenalkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and/or halogen, and R.sup.4 is hydrogen or sulfo, are prepared by reacting a 4-alkoxy-2-hydroxybenzophenone of the general formula II ##STR2## with chlorosulfonic acid at from -20.degree. to +100.degree. C., by a novel and improved process in which the reaction is carried out in an aliphatic, cycloaliphatic and/or aromatic carboxylate as solvent.

摘要翻译： 其中R 1是未被取代或被卤素，氰基，羟基，C 1 -C 20烷氧基，C 2 -C 20烷氧基取代的C 1 -C 20烷基的4-烷氧基-2-羟基二苯甲酮-5-磺酸 -C 20 - 烷氧基羰基，未被取代或被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基和/或卤素取代的酰氧基和/或苯基，R 2和R 3彼此独立地为氢，卤素，C 1 -C 12 - 烷基 C 1 -C 12烷氧基，C 1 -C 4卤代烷基，C 3 -C 8环烷基，C 4 -C 12环烷基烷基，氰基，羟基或羟乙基，或各自为苯氧基，未取代或被C1- C4-烷基，C1-C4-烷氧基和/或卤素，R4是氢或磺基，是通过使通式II的4-烷氧基-2-羟基二苯甲酮与（II）的4-磺酰基-2- 通过一种新的改进的方法，其中反应在脂族，脂环族和/或芳族羧酸酯作为溶剂中进行。

公开(公告)号：US4990680A

公开(公告)日：1991-02-05

申请号：US463365

申请日：1990-01-11

申请人： Peter Neumann ,  Alexander Aumueller

发明人： Peter Neumann ,  Alexander Aumueller

IPC分类号： C07C45/45 ,  C07C45/00 ,  C07C49/83

CPC分类号： C07C45/008

摘要： A process for the preparation of 2,4-dihydroxybenzophenone by reacting resorcinol with benzotrichloride in water, wherein the reaction mixture contains a surfactant or a dispersing or emulsifying agent in a concentration of from 0.05 to 5%, by weight of the water.The product is obtained in high yield and good purity.

摘要翻译： 一种通过使间苯二酚与苯并三氯在水中反应制备2,4-二羟基二苯甲酮的方法，其中反应混合物含有浓度为0.05至5重量％水的表面活性剂或分散或乳化剂。 得到产物，产率高，纯度高。

公开(公告)号：US4943391A

公开(公告)日：1990-07-24

申请号：US286295

申请日：1988-12-10

申请人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

发明人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

IPC分类号： C07D471/08 ,  C08K5/34 ,  C08K5/3412 ,  C08K5/3442 ,  C09D7/12 ,  C09K15/18

CPC分类号： C07D471/08

摘要： Bicyclo[3.3.1]nonane derivatives of the general formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1 is hydrogen,R.sup.2 is hydrogen or hydroxyl, or the radical ##STR2## R.sup.3 and R.sup.4 are each independently of the other phenyl or 1- or 2-naphthyl, which phenyl or naphthyl may each be substituted by 1, 2 or 3 C.sub.1 -C.sub.12 -alkyls, C.sub.1 -C.sub.12 -alkoxys, chlorines, bromines, fluorines, trifluoromethyls or cyanos, in the case of 2 or 3 substituents these substituents being identical or different,A and B are each independently of the other a chemical bond, C.sub.1 -C.sub.22 -alkylene, cycloalkylene ##STR3## where m and o are each from 1 to 20 andR.sup.10 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a radical of the formula ##STR4## which may be bonded to A not only via the nitrogen atom but also via the carbon atom, andR.sup.11, R.sup.12, R.sup.13 and R.sup.14 are each independently of the others C.sub.1 -C.sub.4 -alkyl, orR.sup.11 and R.sup.12 and/or R.sup.13 and R.sup.14 are each together tetramethylene or pentamethylene,R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.15 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.5 -C.sub.16 -phenylalkyl or a 5- or 6-membered heterocycle, or, when n is 1, --M--B--R.sup.5 is a radical of the formula ##STR6## where R.sup.16 is C.sub.1 -C.sub.4 -alkyl,R.sub.17 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sub.18 is hydrogen or C.sub.1 -C.sub.12 -alkyl, have remarkably good stabilizing properties in respect of plastics, are colorless, are highly compatible with organic polymers and are stable to thermal decomposition.

摘要翻译： 双环[3.3.1]通式（I）的壬烷衍生物其中n是1至70的整数，R 1是氢，R 2是氢或羟基，或者基团R 3和R 4 各自独立地为其它苯基或1-或2-萘基，该苯基或萘基各自可被1,2或3个C 1 -C 12烷基，C 1 -C 12烷氧基，氯，溴，氟，三氟甲基或氰基取代 在2或3个取代基的情况下，这些取代基相同或不同，A和B各自独立地为化学键，C 1 -C 22 - 亚烷基，亚环烷基，其中m和o分别为 1至20，R 10为氢，C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 7 -C 18 - 苯基烷基，苯基或C 2 -C 22 - 氰基烷基，M为式 A不仅通过氮原子而且通过碳原子，并且R 11，R 12，R 13和R 14各自独立地为C 1 -C 4 - 烷基，或者R 11和R 12和/或R 13和R 14分别为四甲基 烯或五亚甲基，R 5是氢，氰基，羟基，R 15是氢，C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 5 -C 16 - 苯基烷基或5-或6-元杂环 或者当n为1时，-MB-R 5为式（VI）的基团，其中R 16为C 1 -C 4 - 烷基，R 17为氢，C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基 和R18是氢或C1-C12烷基，在塑料方面具有非常好的稳定性，是无色的，与有机聚合物高度相容并且对热分解是稳定的。

公开(公告)号：US4897289A

公开(公告)日：1990-01-30

申请号：US312310

申请日：1989-02-17

申请人： Alexander Aumueller ,  Peter Neumann ,  Gerd Blinne ,  Gerhard Lindenschmidt

发明人： Alexander Aumueller ,  Peter Neumann ,  Gerd Blinne ,  Gerhard Lindenschmidt

IPC分类号： H05F1/02 ,  C08J7/02 ,  C09K3/16 ,  H01B1/12 ,  H01B13/00

CPC分类号： H01B1/121

摘要： An electrically conductive surface layer is produced on moldings consisting of plastics which are soluble or swellable in organic solvents, the conductivity of the said layer being based on a system, incorporated therein, oforganic electron acceptors (I) on the one hand andorganic electron donors (II), iodides (III) or a mixture of (II) and (III) as electron donors, on the other hand,by a process in which the moldings are treated with organic solutions of these components.The products have a surface resistance of from 10.sup.8 to 10.sup.2 ohm and have the advantage that the remaining properties of the moldings are virtually unaffected by the agents (I) to (III).

摘要翻译： 导电表面层在由塑料制成的成型体上产生，该塑料在有机溶剂中是可溶的或可溶胀的，所述层的导电性基于其中并入有机电子受体（I）的系统和有机电子 供体（II），碘化物（III）或作为电子给体的（II）和（III）的混合物，另一方面，通过这些成分用这些组分的有机溶液处理的方法。 产品具有108至102欧姆的表面电阻，并且具有的优点是模制品的剩余性能几乎不受试剂（I）至（III）的影响。

公开(公告)号：US5017702A

公开(公告)日：1991-05-21

申请号：US375874

申请日：1989-07-06

申请人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

发明人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

IPC分类号： C07D211/58 ,  C07D401/12 ,  C07D405/12 ,  C08K5/34 ,  C08K5/3412 ,  C08K5/3435 ,  C08K5/43 ,  C08L23/02 ,  C08L75/00 ,  C08L75/04 ,  C08L77/00 ,  C09D7/12 ,  C09K3/00

CPC分类号： C07D401/12 ,  C07D211/58 ,  C07D405/12 ,  C08K5/3435

摘要： Useful stabilizers for organic material, in particular plastics and paints, and metal ion deactivators are amides of the formula ##STR1## where R.sup.1 and R.sup.2 are singly methyl or together tetramethylene or pentamethylene, R.sup.3 is hydrogen, alkyl, alkoxycarbonyl, alkanoyl, benzyl, hydroxyethyl, cyanomethyl or aminomethyl, n is 1, 2 or 3 and--when n is 1--R.sup.4 is hydrogen and R.sup.5 is --CO--R.sup.6 is H, alkyl, cycloalkyl, aralkyl, phenoxyalkyl, aryl, a 5- or 6-membered heterocycle, alkoxy, aryloxy, cycloalkyloxy, phenylalkoxy, carbamoyl or --SO.sub.2 --R.sup.8 where R.sup.8 is alkyl or phenyl or ##STR2## is a phthalimide group or--when n is 2--R.sup.4 is H and R.sup.5 is --CO--Z--CO-- where Z is a chemical bond, C.sub.1 -C.sub.8 -alkylene, oxaalkylene, phenylene, cyclohexylene, biphenylene, biphenylene oxide, dioxyphenylene, diaminophenylene, diaminocyclohexylene, 1-.OMEGA.-diiminoalkylene or a 2-valent heterocycle or ##STR3## is a pyromellimide group or--when n is 3--R.sup.4 is H and R.sup.5 is ##STR4## where R.sup.10 is a trivalent alkyl or 3-valent aryl, or acid addition salts and hydrates thereof.

摘要翻译： 有机材料，特别是塑料和涂料以及金属离子失活剂的有用的稳定剂是式（I）的酰胺，其中R 1和R 2是单甲基或四亚甲基或五亚甲基，R 3是氢，烷基，烷氧基羰基，烷酰基， 苄基，羟乙基，氰甲基或氨基甲基，n为1,2或3，当n为1-R4为氢且R5为-CO-R6时，为H，烷基，环烷基，芳烷基，苯氧基烷基，芳基，5-或6 芳基氧基，环烷氧基，苯基烷氧基，氨基甲酰基或-SO2-R8，其中R8是烷基或苯基，或者是“邻苯二甲酰亚胺基”，或者当n是2-R 4是H且R 5是-CO-Z- CO-，其中Z是化学键，C1-C8-亚烷基，氧杂亚烷基，亚苯基，亚环己基，亚联苯基，亚联苯氧基，二氧亚苯基，二氨基亚苯基，二氨基环己烯，1-OMEGA-二亚氨基亚烷基或2价杂环或 基团或 - 当n是3-R 4是H且R 5是时，其中R 10是三价烷基或3价芳基或酸性 其盐及其水合物。

公开(公告)号：US4958022A

公开(公告)日：1990-09-18

申请号：US314146

申请日：1989-02-23

申请人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

发明人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

IPC分类号： C07D209/42 ,  C07D207/38 ,  C07D471/06 ,  C07D471/16 ,  C07D471/22 ,  C07D487/04 ,  C07D487/16 ,  C07D487/22 ,  C08K5/34 ,  C08K5/3435 ,  C08L23/02 ,  C08L75/00 ,  C08L75/04 ,  C09D7/12

CPC分类号： C07D471/06 ,  C08K5/34 ,  C08K5/3435

摘要： Polycyclic compounds of the general formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each hydrogen, alkyl, cycloalkyl, unsubstituted or substituted phenyl, pyridyl or phenylalkyl, or R.sup.1 and R.sup.2 together form a trimethylene or tetramethylene group, W, X, Y and Z independently of one another are each C--R.sup.6 or nitrogen, one or more of the radicals W, X, Y or Z being C--R.sup.6, R.sup.6 is hydrogen, --CO.sub.2 R.sup.7, --CONR.sup.7 R.sup.8, cyano or hydroxymethyl and R.sup.7 and R.sup.8 are each hydrogen, alkyl, unsubstituted or substituted phenyl, cycloalkyl, a 5-membered or 6-membered heterocyclic structure or phenylalkyl, R.sup.3 and R.sup.4 are each hydrogen or R.sup.3 and R.sup.4 together form a group of the formula ##STR2## A is a chemical bond, alkylene, ##STR3## or cycloalkylene, m and o are each from 1 to 20, R.sup.9 is alkyl, cycloalkyl, phenylalkyl or unsubstituted or substituted phenyl, M is a group of the formula ##STR4## and can be bonded to A both with the nitrogen atom and with the carbon atom, and R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each alkyl, or R.sup.10 and R.sup.11 or R.sup.12 and R.sup.13 together form a tetramethylene or pentamethylene group, B is a chemical bond, alkylene or phenylalkylene or is alkylene which is interrupted by carbonyl, carboxamide or a carboxylic ester group, R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.14 is hydrogen, alkyl, cycloalkyl, phenylalkyl, phenyl or a 5-membered or 6-membered heterocyclic structure, or M--B--R.sup.5 is a group of the formula ##STR6## in which case A must not be a chemical bond and R.sup.15 is alkyl, R.sup.16 is hydrogen, alkyl or alkoxy and R.sup.17 is hydrogen or alkyl, have extremely good stabilizing properties and no natural color and are very compatible with organic polymers. They also have a low vapor pressure and are stable to thermal decomposition.

摘要翻译： 通式（I）的多环化合物其中R 1和R 2彼此独立地为氢，烷基，环烷基，未取代或取代的苯基，吡啶基或苯基烷基，或者R 1和R 2一起形成三亚甲基或四亚甲基 基团W，X，Y和Z各自独立地为C-R6或氮，基团W，X，Y或Z中的一个或多个为C-R6，R6为氢，-CO2R7，-CONR7R8，氰基 或羟甲基，R 7和R 8各自为氢，烷基，未取代或取代的苯基，环烷基，5元或6元杂环结构或苯基烷基，R 3和R 4各自为氢或R 3和R 4一起形成式 IMAGE> A是化学键，亚烷基，亚环烷基，亚环烷基，m和o各自为1-20，R9为烷基，环烷基，苯基烷基或未取代或取代的苯基，M为 并且可以与氮原子和碳原子键合至A，R10，R11，R12 和R 13彼此独立地为烷基，或R 10和R 11或R 12和R 13一起形成四亚甲基或五亚甲基，B为化学键，亚烷基或苯基亚烷基，或为被羰基，羧酰胺或羧酸酯基中断的亚烷基 R 5为氢，氰基，羟基，R 14为氢，烷基，环烷基，苯基烷基，苯基或5元或6元杂环结构，或MB-R5为式 SB，5 NHO + RE，其中A不能为化学键，R15为烷基，R16为氢，烷基或烷氧基，R17为氢或烷基，具有非常好的稳定性，无 天然色，与有机聚合物非常相容。 它们也具有低蒸气压，并且对热分解是稳定的。

公开(公告)号：US4940742A

公开(公告)日：1990-07-10

申请号：US392598

申请日：1989-08-11

申请人： Alexander Aumueller ,  Peter Spang ,  Peter Neumann ,  Hubert Trauth

发明人： Alexander Aumueller ,  Peter Spang ,  Peter Neumann ,  Hubert Trauth

IPC分类号： C07D401/12 ,  C08K5/3442 ,  C08K5/3447 ,  C09D7/12

CPC分类号： C07D401/12

摘要： Benzimidazolecarboxanilides of the formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each hydrogen, chlorine, bromine, alkyl, alkoxy, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl or phenylalkyl, R.sup.3 and R.sup.4 independently of one another are each hydrogen, alkyl, alkyl which is interrupted by one or more oxygen atoms, alkoxy, alkoxy which is interrupted by one or more oxygen atoms, unsubstituted or alkyl-substituted or alkoxy-substituted phenyl, phenylalkoxy, alkanoylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 0, 1, 2, 3, 4 or 5, X is oxygen, ##STR2## R.sup.5 is hydrogen, alkyl, phenylalkyl, cyanomethyl, aminoethyl, hydroxyethyl, alkylcarbonyl or benzoyl, R.sup.6 is hydrogen, alkyl, phenylalkyl or phennyl and m is from 2 to 8, and the acid addition salts and hydrates of these compounds are stabilizers for organic material, in particular for plastics, such as polyethylene, polypropylene and polyamide.

摘要翻译： 其中R 1和R 2彼此独立地为氢，氯，溴，烷基，烷氧基，未取代或烷基取代或烷氧基取代的苯基或苯基烷基，R3和R4独立地为（I）的苯并咪唑化合物酰胺 另一个为氢，烷基，被一个或多个氧原子间隔的烷基，烷氧基，被一个或多个氧原子间隔的烷氧基，未取代的或烷基取代的或烷氧基取代的苯基，苯基烷氧基，烷酰基氨基，苯甲酰氨基， 烷酰氧基或苯甲酰氧基，n为0,1,2,3,4或5，X为氧，R 5为氢，烷基，苯基烷基，氰基甲基，氨基乙基，羟基乙基，烷基羰基或苯甲酰基 R6为氢，烷基，苯基烷基或苯基，m为2-8，并且这些化合物的酸加成盐和水合物是有机材料的稳定剂，特别是用于塑料如聚乙烯，聚丙烯和聚酰胺的稳定剂。

公开(公告)号：US4904779A

公开(公告)日：1990-02-27

申请号：US299423

申请日：1989-01-23

申请人： Peter Neumann ,  Alexander Aumueller ,  Hubert Trauth

发明人： Peter Neumann ,  Alexander Aumueller ,  Hubert Trauth

IPC分类号： C07D487/22 ,  C08G63/685 ,  C08K5/34 ,  C08K5/3432 ,  C08K5/3435 ,  C08K5/3477 ,  C08L77/00 ,  C09K15/30

CPC分类号： C07D487/22 ,  C08K5/3477

摘要： Heterocyclic compounds of the formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently of the others hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 - or C.sub.6 -cycloalkyl orR.sup.1 and R.sup.2 and also R.sup.3 and R.sup.4 are each pairwise trimethylene or tetramethylene,A is a direct bond, C.sub.1 - C.sub.22 -alkylene, cycloalkylene, ##STR2## where m and o are each from 1 to 20 andR.sup.6 is C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, unsubstituted or substituted phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a group of the formula ##STR3## which may be bonded to A not only via the nitrogen but also via the carbon, and whereR.sup.7, R.sup.8, and R.sup.10 are each independently of the others C.sub.1 -C.sub.4 -alkyl orR.sup.7 and R.sup.8 and/or R.sup.9 and R.sup.10 are each pairwise tetramethylene or pentamethylene andR.sup.11 is hydrogen or C.sub.1 -C.sub.4 -alkyl,B is a direct bond, C.sub.1 -C.sub.22 - alkylene, C.sub.7 -C.sub.16 -phenylalkylene or carbonyl-, carboxamido- or carboxylato-interrupted C.sub.3 -C.sub.22 -alkylene andR.sup.5 is hydrogen, cyano, hydroxyl, ##STR4## R.sup.12 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.16 -phenylalkyl, unsubstituted or substituted phenyl or 5- or 6- membered heterocyclyl or, when n is 1, M--B--R.sup.5 is a group of the formula ##STR5## R.sup.13 is C.sub.1 -C.sub.4 -alkyl, R.sup.14 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sup.15 is C.sub.1 -C.sub.12 -alkyl, have very good stabilizing properties, no self-color, good compatibility with polymers, a low vapor pressure and stability to thermal decomposition.

摘要翻译： 式（I）的杂环化合物其中n为1至70的整数，R 1，R 2，R 3和R 4各自独立地为氢，C 1 -C 22 - 烷基或C 5 - 或C 6 - 环烷基或R 1和R 2，并且R 3和R 4各自为一对三亚甲基或四亚甲基，A为直接键，C 1 -C 22 - 亚烷基，亚环烷基，其中m和o各自为1〜20， R 6是C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 7 -C 18 - 苯基烷基，未取代或取代的苯基或C 2 -C 22 - 氰基烷基，M是可以与A键合的基团， 氮，但也经由碳，并且其中R 7，R 8和R 10各自独立地为C 1 -C 4 - 烷基或者R 7和R 8和/或R 9和R 10各自为成对四亚甲基或五亚甲基，R 11为氢或C 1 -C 4 - C 4 - 烷基，B是直接键，C 1 -C 22 - 亚烷基，C 7 -C 16 - 苯基亚烷基或羰基 - ，甲酰胺基或羧基 - 中断的C 3 -C 22亚烷基，R 5是氢，氰基，羟基， > + TR R12是氢，C1-C22-烷基，C5-C12-环烷基，C7-C16-苯基烷基，未取代或取代的苯基或5-或6-元杂环基，或当n是1时，MB-R5是 R 13是C + HD 1 -C 4烷基，R 14是氢，C 1 -C 4烷基或C 1 -C 4烷氧基，R 15是C 1 -C 12烷基，具有非常好的稳定性 ，无自色，与聚合物相容性好，蒸气压低，热分解稳定。

公开(公告)号：US4835273A

公开(公告)日：1989-05-30

申请号：US133625

申请日：1987-12-16

申请人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

发明人： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

IPC分类号： C07D487/22 ,  C07D519/00 ,  C08G69/26 ,  C08K5/34 ,  C08K5/3477 ,  C09D7/12 ,  C09K15/30

CPC分类号： C07D487/22 ,  C07D519/00 ,  C08K5/3477

摘要： Compounds useful for stabilizing organic material have the general formula (I) ##STR1## where the substituents are as defined in claim 1.

摘要翻译： 可用于稳定有机材料的化合物具有通式（I）其中取代基如权利要求1中所定义。