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公开(公告)号：US5110696A
公开(公告)日：1992-05-05
申请号：US733224
申请日：1991-07-22
IPC分类号： C23C14/08 , H01M4/131 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M10/05 , H01M10/36
摘要： A Thin film electrode for a rechargeable (secondary) battery is prepared by electron beam deposition of LiMn.sub.2 O.sub.4, LiCoO.sub.2, or LiNiO.sub.2 on a smooth, amorphous substrate surface and in situ annealing of the deposited lithium composition at a temperature below about 500.degree. C. The amorphous nature of the substrate surface prevents epitaxial growth or ordered orientation of the minute composition crystallites thus formed. The finely granular structure of the resulting electrode thin film presents abundant surface area that enables a 4V battery to provide current densities in the range of 500 microamps/cm.sup.2. The low annealing temperature enables formation of the electrode structure and subsequent battery assembly directly upon semiconductor devices and integrated circuitry.
摘要翻译： 通过在光滑的非晶基材表面上电子束沉积LiMn 2 O 4，LiCoO 2或LiNiO 2并在低于约500℃的温度对沉积的锂组合物进行原位退火，制备用于可再充电（二次）电池的薄膜电极。 衬底表面的无定形特性防止由此形成的微小组合物微晶的外延生长或有序取向。 所得电极薄膜的细颗粒结构具有丰富的表面积，使4V电池能够提供500微安/ cm2范围内的电流密度。 低退火温度能够直接在半导体器件和集成电路上形成电极结构和随后的电池组件。
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2.发明授权Method for preparation of LiCoO.sub.2 intercalation compound for use in secondary lithium batteries 失效用于二次锂电池的LiCoO2插层化合物的制备方法
公开(公告)号：US5211933A
公开(公告)日：1993-05-18
申请号：US876880
申请日：1992-04-30
CPC分类号： H01M4/485 , C01G45/1242 , C01G51/42 , H01M4/131 , H01M4/505 , H01M4/525 , C01P2002/32 , C01P2006/40
摘要： Methods are described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 and layered LiCoO.sub.2 phases which are intercalable compounds of interest for use in lithium secondary batteries. These phases can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.
摘要翻译： 描述了用于锂二次电池的尖晶石LiMn 2 O 4和层状LiCoO 2相的低温制备方法，这些相是可感兴趣的化合物。 这些相可以使用乙酸酯前体在小于400℃的温度下以体积或厚膜形式制备。
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公开(公告)号：US5470357A
公开(公告)日：1995-11-28
申请号：US428970
申请日：1995-04-26
CPC分类号： C08J9/28 , H01M10/0431 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M2/1653 , H01M6/181 , H01M6/32 , H01M6/46 , C08J2327/16 , H01M2300/0085 , H01M6/30 , H01M6/42 , Y02P70/54 , Y10T29/49108 , Y10T29/49115
摘要： Li-ion rechargeable battery cell electrode and electrolyte/separator elements formulated as layers of plasticized polymeric matrix compositions are laminated with electrically conductive collector elements to form a unitary battery cell structure. Adhesion between the electrode and collector elements is enhanced by pretreatment of the collector elements in which a 0.25% to 3.0% solution of a polymeric material compatible with said matrix polymer is applied to a collector foil or grid and dried to form a coated film, and the resulting coated collector element is heated within the range of about 250.degree. to 450.degree. C. for about 5 to 60 seconds.
摘要翻译： 配制为增塑聚合物基质组合物层的锂离子可再充电电池单元电极和电解质/隔离元件与导电收集器元件层叠以形成单一电池单元结构。 通过预处理收集器元件来增强电极和收集器元件之间的粘附，其中将与所述基质聚合物相容的聚合物材料的0.25％至3.0％的溶液施加到收集器箔或网格上并干燥以形成涂膜， 将所得的涂覆的集电体元件在约250℃至450℃的范围内加热约5至60秒。
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4.发明授权Method for preparation of LiMn.sub.2 O.sub.4 intercalation compounds and use thereof in secondary lithium batteries 失效LiMn2O4插层化合物的制备方法及其在二次锂电池中的应用
公开(公告)号：US5135732A
公开(公告)日：1992-08-04
申请号：US690080
申请日：1991-04-23
IPC分类号： C01G45/12 , C01G45/00 , C01G51/00 , H01M4/131 , H01M4/1391 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525
CPC分类号： H01M4/505 , C01G45/1242 , C01G51/42 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M4/525 , C01P2006/40
摘要： Method is described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 phase which is an intercalable compound of interest for use in lithium secondary batteries. This phase can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.
摘要翻译： 描述了用于锂二次电池的尖晶石LiMn 2 O 4相的低温制备方法，该尖晶石LiMn 2 O 4相是可用的化合物。 该相可以使用乙酸酯前体在小于400℃的温度下以体积或厚膜形式制备。
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公开(公告)号：US09293767B2
公开(公告)日：2016-03-22
申请号：US13124723
申请日：2009-10-23
申请人： Jean-Marie Tarascon , Nadir Recham , Michel Armand
发明人： Jean-Marie Tarascon , Nadir Recham , Michel Armand
IPC分类号： H01M4/48 , H01M4/58 , C01B25/26 , C01B25/37 , C01B25/45 , C01B25/455 , C01B33/20 , C01G1/10 , C01G49/00 , C01G51/00 , C01G53/00 , H01M10/052
CPC分类号： H01M4/5825 , C01B25/26 , C01B25/37 , C01B25/45 , C01B25/455 , C01B33/20 , C01G1/10 , C01G49/009 , C01G51/006 , C01G53/006 , C01P2002/54 , C01P2002/72 , C01P2002/77 , C01P2002/88 , C01P2004/04 , C01P2006/40 , H01M4/582 , H01M10/052 , Y10T428/2982
摘要： A material is made up of particles of an optionally-doped fluorosulphate. The fluorosulphate has a distorted Tavorite type structure of formula (A1−aA′a)x(Z1−bZ′b)z(SO4)sFf (I) where A=Li or Na, A′ 0 a hole or at least one doping element, Z=at least one element selected from Fe, Co and Ni, Z′=a hole or at least one doping element, the indices a, b, x, z, s, and f are selected to assure the electroneutrality of the compound and a≧0, b≧0, x≧0, z>0, s>0, f>0, the respective quantities a and b of dopant A and Z′ being such that the Tavorite type structure is preserved. The material is obtained from the precursors thereof by an ionothermal route or ceramic route in a closed reactor. The material is of particular use as an active electrode material.
摘要翻译： 材料由任选掺杂的氟代硫酸盐的颗粒组成。 氟代硫酸盐具有式（A1-aA'a）x（Z1-bZ'b）z（SO4）sFf（I）变形的Tavorite型结构，其中A = Li或Na，A'0为空穴或至少一种掺杂 元素Z =选自Fe，Co和Ni中的至少一种元素，Z'=空穴或至少一种掺杂元素，选择指数a，b，x，z，s和f以确保电中性 化合物和a≥0，b≥0，x≥0，z> 0，s> 0，f> 0，掺杂剂A和Z'的各自的量a和b使得保留了Tavorite型结构。 该材料通过在封闭反应器中的离子热路径或陶瓷路线从其前体获得。 该材料特别用作活性电极材料。
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6.发明申请METHOD FOR PREPARING A SOLID-STATE BATTERY BY SINTERING UNDER PULSATING CURRENT 有权通过在脉冲电流下烧结制备固态电池的方法公开(公告)号：US20130189562A1
公开(公告)日：2013-07-25
申请号：US13578415
申请日：2011-02-17
申请人： Michael Dolle , Patrick Rozier , Gaelle Delaizir , Jean-Marie Tarascon , Virginie Viallet , Mathieu Morcrette , Vincent Seznec , Renaud Bouchet , Abdelmaula Aboulaich , Laurence Tortet
发明人： Michael Dolle , Patrick Rozier , Gaelle Delaizir , Jean-Marie Tarascon , Virginie Viallet , Mathieu Morcrette , Vincent Seznec , Renaud Bouchet , Abdelmaula Aboulaich , Laurence Tortet
CPC分类号： H01M2/0207 , H01M2/204 , H01M4/02 , H01M4/0471 , H01M4/139 , H01M4/5825 , H01M10/0525 , H01M10/0562 , H01M10/058 , H01M2004/021 , H01M2300/0071 , Y02E60/122 , Y10T29/49115
摘要： The present invention relates to a method for preparing a completely solid Li-ion battery having a solid state body wherein the battery is assembled in a single step by stacking at least one layer of a powder mix including a positive electrode active material and a solid electrolyte, at least one intermediate layer of a solid electrolyte and at least one layer of a powder mix including a negative electrode active material and a solid electrolyte, and simultaneous sintering of the three layers at a pressure of at least 20 MPa, under pulsating current. The invention also relates to the Li-ion battery obtained by such a method.
摘要翻译： 本发明涉及一种制备具有固态体的完全固体锂离子电池的方法，其中通过将至少一层包含正极活性材料和固体电解质的粉末混合物堆叠在一个步骤中组装电池 ，固体电解质的至少一个中间层和至少一层包含负极活性材料和固体电解质的粉末混合物，并且在脉动电流下以至少20MPa的压力同时烧结三层。 本发明还涉及通过这种方法获得的锂离子电池。
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公开(公告)号：US08062791B1
公开(公告)日：2011-11-22
申请号：US12157443
申请日：2008-06-10
CPC分类号： H01M4/54 , H01M4/34 , H01M4/485 , H01M10/052 , H01M10/32
摘要： A battery cathode comprises an electrode of silver, molybdenum, oxygen, fluorine and chlorine and having a higher discharge capacity expressed as milliampere hour per gram of material (mAh/g) available from silver reduction at a potential above 3V as compared to that of SVO material versus lithium. The battery cathode compound can be represented by Ag6 Mo2O7F3Cl. The cathode is devoted for primary lithium batteries application and most notably can be used in a medical battery, such as a defibrillator battery [e.g. implantable cardioverter defibrillator (ICD) battery] having a lithium metal anode.
摘要翻译： 电池阴极包括银，钼，氧，氟和氯的电极，并且具有更高的放电容量，表示为每毫升材料（mAh / g）表示的毫安小时，其电位高于3V时的银还原，与SVO相比 材料与锂。 电池阴极化合物可以由Ag6 Mo2O7F3Cl表示。 阴极用于一次锂电池应用，并且最显着地可用于医疗电池，例如除颤器电池[例如， 具有锂金属阳极的植入式心律转复除颤器（ICD）电池]。
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8.发明授权公开(公告)号：US07736813B2
公开(公告)日：2010-06-15
申请号：US11793865
申请日：2005-12-19
CPC分类号： G02F1/1533 , G02F1/1506
摘要： The invention concerns an electrochromic cell with emission controlled by electrodeposition under the action of a control voltage. The cell comprises the following flexible elements, superimposed and respectively in intimate contact: a first electrode (11) intended to be connected to a first potential of the control voltage, a first porous layer (12), formed of a mixture of PVDF-HFP, PEO and an activated carbon powder, a porous separator (13), formed of a mixture of PVDF-HFP and PEO, a second electrode (14) formed of a grid and connected to a second potential of the control voltage, a second porous layer (15), formed of a mixture of PVDF-HFP, PEO and carbon powder, an aqueous electrolytic solution containing a copper salt being contained in the first flexible layer (12), in the separator (13) and in the second flexible layer (15).
摘要翻译： 本发明涉及在控制电压的作用下通过电沉积控制发射的电致变色电池。 电池包括叠加并分别紧密接触的以下柔性元件：旨在连接到控制电压的第一电位的第一电极（11），由PVDF-HFP的混合物形成的第一多孔层（12） ，PEO和活性炭粉末，由PVDF-HFP和PEO的混合物形成的多孔分离器（13），由栅格形成并连接到控制电压的第二电位的第二电极（14），第二多孔 由PVDF-HFP，PEO和碳粉末的混合物形成的层（15），包含在第一柔性层（12）中的铜盐的水性电解液，隔板（13）和第二柔性层 （15）。
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公开(公告)号：US06187061B1
公开(公告)日：2001-02-13
申请号：US09315434
申请日：1999-05-20
IPC分类号： H01G900
CPC分类号： H01G9/155 , H01G4/30 , H01G11/72 , H01M6/181 , H01M10/4264 , H01M16/00 , Y02E60/13 , Y10T29/417
摘要： Supercapacitor cell electrode and separator elements formulated as membranes of plasticized polymers matrix compositions are laminated with electrically conductive current collector elements to form flexible, unitary supercapacitor structures. The matrix plasticizer component is extracted from the laminate with polymer-inert solvent and replaced with electrolyte solution to activate the supercapacitor. Various arrangements of cell structure elements provide parallel and series cell structures which yield improved specific energy capacity and increased voltage output for utilization demands. The supercapacitor elements may also be laminated with similar polymeric rechargeable battery cell structures to provide hybrid devices capable of delivering both high energy and high power as needed in electronic systems.
摘要翻译： 配制为增塑聚合物基体组合物的膜的超级电容器电极和隔离元件与导电集电器元件层叠以形成柔性的单一超级电容器结构。 用聚合物惰性溶剂从层压体中提取基质增塑剂组分，并用电解质溶液代替以激活超级电容器。 电池结构元件的各种布置提供并联和串联电池结构，其产生改进的比能量容量和增加的电压输出用于利用需求。 超级电容器元件也可以与类似的聚合物可再充电电池单元结构层压，以提供能够在电子系统中根据需要传送高能量和高功率的混合设备。
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公开(公告)号：US5635138A
公开(公告)日：1997-06-03
申请号：US373830
申请日：1995-01-17
CPC分类号： G01N23/20008 , H01M10/48 , H01M6/181
摘要： An apparatus and method for monitoring structural changes of an electrode in a rechargeable battery include an in situ x-ray study electrochemical cell holder (30) comprising top and bottom cell holder members (32, 34) including at least one beryllium window element (36) for transmission of diffractometer x-radiation. A rechargeable battery cell (43) mounted within the x-ray cell holder enclosure comprises an electrolyte/separator element (68) interposed between positive and negative electrodes (64, 66). A current collector element (70) formed of an electrically-conductive open-mesh grid is disposed between the positive electrode and the separator to enable ion-conducting contact of the electrode and separator while maintaining electrical continuity between the electrode and an external x-ray cell holder terminal (54). As a result of this arrangement, the positive electrode need not contact the window element to establish an electrical battery circuit, but may be sufficiently spaced from the window to avoid electrolytic corrosion of the beryllium element. The in situ x-ray electrochemical cell holder and battery cell structure allow for continuous monitoring of the structural changes in electrode materials during charge/discharge cycling.
摘要翻译： 用于监测可再充电电池中的电极的结构变化的装置和方法包括原位x射线研究电化学电池座（30），其包括顶部和底部电池保持器构件（32,34），其包括至少一个铍窗口元件（36） ）用于传播衍射仪x辐射。 安装在x射线电池保持器外壳内的可再充电电池单元（43）包括插在正极和负极（64,66）之间的电解质/分离元件（68）。 由导电开口网格形成的集电器元件（70）设置在正电极和隔板之间，以使电极和隔板之间能够进行离子导电接触，同时保持电极与外部x射线之间的电连续性 电池座端子（54）。 作为这种布置的结果，正极不需要接触窗口元件以建立电池电路，而是可以与窗口充分间隔开以避免铍元件的电解腐蚀。 原位X射线电化学电池座和电池单元结构允许连续监测充电/放电循环期间电极材料的结构变化。
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