Production of ethylbenzene
    1.
    发明授权
    Production of ethylbenzene 失效
    生产乙苯

    公开(公告)号:US5334795A

    公开(公告)日:1994-08-02

    申请号:US967954

    申请日:1992-10-27

    CPC classification number: C07C2/66 C07C2529/70

    Abstract: Ethylbenzene is produced by the alkylation of benzene with ethylene in the presence of an alkylation catalyst having a particular structure defined by its X-ray diffraction pattern. A preferred catalyst is the zeolite MCM-22. The process is typically carried out at a temperature of 300.degree. to 1000.degree. F. but the catalyst provides sufficient activity for the reaction to be carried out at temperatures below 700.degree. F. Liquid phase operation is preferred, giving a lower yield of polyethylated products. The use of the selected catalyst also results in a reduction of the xylene impurity level to values below 500 ppm in the product.

    Abstract translation: 在具有由其X射线衍射图形定义的特定结构的烷基化催化剂存在下,通过苯与乙烯的烷基化生产乙苯。 优选的催化剂是沸石MCM-22。 该方法通常在300至1000°F的温度下进行,但催化剂提供足够的活性以使反应在低于700°F的温度下进行。液相操作是优选的,从而降低聚乙烯化产物的产率 。 使用所选择的催化剂还导致二甲苯杂质水平降低到产品中低于500ppm的值。

    Crystalline layered material MCM-20 and process for its preparation
    5.
    发明授权
    Crystalline layered material MCM-20 and process for its preparation 失效
    结晶层状材料MCM-20及其制备方法

    公开(公告)号:US4791088A

    公开(公告)日:1988-12-13

    申请号:US939265

    申请日:1986-12-09

    CPC classification number: B01J29/049 C01B33/20 C01B33/28

    Abstract: Layered silicate materials of high thermal stability and surface area which contain interspathic oxides such as silica as prepared by treating a layered silicate, with organic cation, to spread the layers apart. A compound such as tetraethylorthosilicate, capable of forming said oxide, is thereafter introduced between the layers. The resulting product is treated to form the oxide, e.g. by hydrolysis, to produce the layered silicate material. The resulting product may be employed as a catalyst material in the conversion of hydrocarbons.

    Abstract translation: 具有高热稳定性和表面积的层状硅酸盐材料,其含有通过用有机阳离子处理层状硅酸盐制备的层间氧化物如二氧化硅,以将层分开。 然后在层之间引入能够形成所述氧化物的化合物如原硅酸四乙酯。 将所得产物处理形成氧化物,例如。 通过水解制备层状硅酸盐材料。 所得产物可用作烃转化中的催化剂材料。

    Selective oxidative coupling
    6.
    发明授权
    Selective oxidative coupling 失效
    选择性氧化偶联

    公开(公告)号:US4914252A

    公开(公告)日:1990-04-03

    申请号:US298240

    申请日:1989-01-12

    CPC classification number: C07C2/84 C07C2521/06 C07C2521/08

    Abstract: A method is provided for converting feedstock comprising paraffins by selective oxidative coupling to product comprising higher hydrocarbons including dimers of said feedstock paraffins which comprises contacting said feedstock with a catalyst composition comprising a thermally stable layered metal chalcogenide having adjacent layers separated by chalcogenide pillars, and an alkali metal.

    Abstract translation: 提供了一种通过选择性氧化偶合将包含链烷烃的原料转化成包含高级烃的产物,所述产物包括所述原料链烷烃的二聚体,其包括使所述原料与催化剂组合物接触,所述催化剂组合物包含具有由硫属化物柱分隔的相邻层的热稳定的层状金属硫族化物, 碱金属。

    Wax hydroisomerization process
    9.
    发明授权
    Wax hydroisomerization process 失效
    蜡加氢异构化工艺

    公开(公告)号:US4995962A

    公开(公告)日:1991-02-26

    申请号:US459154

    申请日:1989-12-29

    CPC classification number: B01J29/049 C10G45/64

    Abstract: There is provided a process for hydroisomerizing petroleum or synthetic paraffin wax with a particular catalyst. The catalyst comprises a hydrogenating component and a layered titanate containing an interspathic polymeric oxide such as silica. The hydrogenating component may be a Group VIII metal such as Pt.

    Abstract translation: 提供了用特定催化剂加氢异构化石油或合成石蜡的方法。 催化剂包含氢化组分和含有间接聚合氧化物如二氧化硅的层状钛酸盐。 氢化组分可以是诸如Pt的VIII族金属。

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