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公开(公告)号：US09175201B2
公开(公告)日：2015-11-03
申请号：US13419071
申请日：2012-03-13
IPC分类号： C09K5/04 , C10M171/00
CPC分类号： C09K5/044 , C09K5/045 , C09K2205/122 , C09K2205/126 , C10M171/008 , C10M2205/026 , C10M2205/08 , C10M2207/023 , C10M2207/026 , C10M2207/042 , C10M2209/1033 , C10M2211/022 , C10M2223/049 , C10N2220/302
摘要： Disclosed are compositions comprising at least one iodocarbon compound and preferably at least one stabilization agent. These compositions are generally useful as refrigerants for heating and cooling, as blowing agents, as aerosol propellants, as solvent composition, and as fire extinguishing and suppressing agents.
摘要翻译： 公开了包含至少一种碘化碳化合物和优选至少一种稳定剂的组合物。 这些组合物通常可用作加热和冷却的制冷剂，作为发泡剂，作为气溶胶推进剂，作为溶剂组合物，以及灭火和抑制剂。
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公开(公告)号：US20080157022A1
公开(公告)日：2008-07-03
申请号：US11795779
申请日：2005-12-21
CPC分类号： C09K5/045 , C09K2205/122 , C09K2205/126
摘要： Disclosed are compositions comprising at least one iodocarbon compound and preferably at least one stabilization agent comprising a diene-based compound. These compositions are generally useful as refrigerants for heating and cooling, as blowing agents, as aerosol propellants, as solvent composition, and as fire extinguishing and suppressing agents.
摘要翻译： 公开了包含至少一种碘化碳化合物和优选至少一种包含二烯类化合物的稳定剂的组合物。 这些组合物通常可用作加热和冷却的制冷剂，作为发泡剂，作为气溶胶推进剂，作为溶剂组合物，以及灭火和抑制剂。
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公开(公告)号：US07531701B2
公开(公告)日：2009-05-12
申请号：US11900081
申请日：2007-09-10
摘要： A process for the preparation of an allyloxytrifluoropropene derivative of the formula CF3CH═CR1(OCH2CR═CH2) wherein R1 is hydrogen, fluoro, or an allyloxy group represented by the formula —OCH2CR═CH2 wherein R is hydrogen or methyl including contacting (I) a compound represented by the formula CF3CH═CR2R3 wherein R2 is selected from the group consisting of hydrogen, chloro, and fluoro and wherein R3 is chloro or fluoro; and (ii) an allyl alcohol derivative of the formula HOCH2CR═CH2 wherein R is selected from the group consisting of: hydrogen and methyl; wherein the contacting is carried out in the presence of a base and optionally a solvent at a temperature and length of time sufficient to produce the allyloxytrifluoropropene derivative. A process for the preparation of polymers of the allyloxytrifluoropropene derivatives is also provided.
摘要翻译： 制备式CF 3 CH-CR 1（OCH 2 CR-CH 2）的烯丙氧基三氟丙烯衍生物的方法，其中R 1是氢，氟或由式-OCH 2 CR-CH 2表示的烯丙氧基，其中R是氢或甲基，包括与（I） 由式CF 3 CH-CR 2 R 3表示的化合物，其中R 2选自氢，氯和氟，并且其中R 3是氯或氟; 和（ii）式HOCH 2 CR-CH 2的烯丙醇衍生物，其中R选自：氢和甲基; 其中所述接触在碱和任选的溶剂的存在下，在足以产生烯丙氧基三氟丙烯衍生物的温度和时间长度下进行。 还提供了制备烯丙氧基三氟丙烯衍生物的聚合物的方法。
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公开(公告)号：US08383867B2
公开(公告)日：2013-02-26
申请号：US11592476
申请日：2006-11-03
CPC分类号： C07C17/278 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/10
摘要： Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, F, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a Cl addition agent under conditions effective to produce a compound of formula (I).
摘要翻译： 公开了一种制备氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：CF 3 CF n CH m X a-m（I）转化为至少一种式（II）CF 3 CZCHZ（II）化合物。 其中每个X独立地为Cl，F，I或Br; 每个Z独立地为H或F; n为1或2; m为1,2或3，条件是当n为1时，m为1或2; a为2或3，a-m≥0。 某些实施方案包括在有效产生式（I）化合物的条件下，将氟化C 2烯烃如四氟乙烯与Cl加成剂反应的步骤。
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5.发明申请Chloro- And Bromo-Fluoro Olefin Compounds Useful As Organic Rankine Cycle Working Fluids 有权氯和氟氟烯烃化合物可用作有机兰金循环工作液公开(公告)号：US20100139274A1
公开(公告)日：2010-06-10
申请号：US12630647
申请日：2009-12-03
CPC分类号： C09K5/048 , C07B2200/09 , C07C21/18 , C09K5/045 , C09K2205/126 , F01K25/06 , F01K25/08
摘要： Aspects of the present invention are directed to working fluids and their use in processes wherein the working fluids comprise compounds having the structure of formula (I): wherein R1, R2, R3, and R4 are each independently selected from the group consisting of: H, F, Cl, Br, and C1-C6 alkyl, at least C6 aryl, at least C3 cycloalkyl, and C6-C15 alkylaryl optionally substituted with at least one F, Cl, or Br, wherein formula (I) contains at least one F and at least one Cl or Br, provided that if any R is Br, then the compound does not have hydrogen. The working fluids are useful in Rankine cycle systems for efficiently converting waste heat generated from industrial processes, such as electric power generation from fuel cells, into mechanical energy or further to electric power. The working fluids of the invention are also useful in equipment employing other thermal energy conversion processes and cycles.
摘要翻译： 本发明的方面涉及工作流体及其在工作流体中的用途，其中工作流体包含具有式（I）结构的化合物：其中R 1，R 2，R 3和R 4各自独立地选自：H ，F，Cl，Br和C 1 -C 6烷基，至少C 6芳基，至少C 3环烷基和任选被至少一个F，Cl或Br取代的C 6 -C 15烷基芳基，其中式（I）含有至少一个 F和至少一个Cl或Br，条件是如果任何R是Br，则化合物不具有氢。 工作流体在兰金循环系统中有用，可有效地将工业过程产生的废热（如燃料电池的发电）转化为机械能或进一步电力。 本发明的工作流体也可用于采用其它热能转换过程和循环的设备中。
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6.发明授权Chloro- and bromo-fluoro olefin compounds useful as organic rankine cycle working fluids 有权氯代和溴代氟代烯烃化合物可用作有机有机酸循环工作液公开(公告)号：US08820079B2
公开(公告)日：2014-09-02
申请号：US12630647
申请日：2009-12-03
CPC分类号： C09K5/048 , C07B2200/09 , C07C21/18 , C09K5/045 , C09K2205/126 , F01K25/06 , F01K25/08
摘要： Aspects of the present invention are directed to working fluids and their use in processes wherein the working fluids comprise compounds having the structure of formula (I): wherein R1, R2, R3, and R4 are each independently selected from the group consisting of: H, F, Cl, Br, and C1-C6 alkyl, at least C6 aryl, at least C3 cycloalkyl, and C6-C15 alkylaryl optionally substituted with at least one F, Cl, or Br, wherein formula (I) contains at least one F and at least one Cl or Br, provided that if any R is Br, then the compound does not have hydrogen. The working fluids are useful in Rankine cycle systems for efficiently converting waste heat generated from industrial processes, such as electric power generation from fuel cells, into mechanical energy or further to electric power. The working fluids of the invention are also useful in equipment employing other thermal energy conversion processes and cycles.
摘要翻译： 本发明的方面涉及工作流体及其在工作流体中的用途，其中工作流体包含具有式（I）结构的化合物：其中R 1，R 2，R 3和R 4各自独立地选自：H ，F，Cl，Br和C 1 -C 6烷基，至少C 6芳基，至少C 3环烷基和任选被至少一个F，Cl或Br取代的C 6 -C 15烷基芳基，其中式（I）含有至少一个 F和至少一个Cl或Br，条件是如果任何R是Br，则化合物不具有氢。 工作流体在兰金循环系统中有用，可有效地将工业过程产生的废热（如燃料电池的发电）转化为机械能或进一步电力。 本发明的工作流体也可用于采用其它热能转换过程和循环的设备中。
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公开(公告)号：US07880040B2
公开(公告)日：2011-02-01
申请号：US11592442
申请日：2006-11-03
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Rajiv R. Singh , Haiyou Wang , Robert C. Johnson , Rajesh K. Dubey
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Rajiv R. Singh , Haiyou Wang , Robert C. Johnson , Rajesh K. Dubey
IPC分类号： C07C19/08
摘要： Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a C1 addition agent under conditions effective to produce a compound of formula (I).
摘要翻译： 公开了一种制备氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：CF 3 CF n CH m X a-m（I）转化为至少一种式（II）CF 3 CZCHZ（II）化合物。 其中每个X独立地为Cl，I或Br; 每个Z独立地为H或F; n为1或2; m为1,2或3，条件是当n为1时，m为1或2; a为2或3，a-m≥0。 某些实施方案包括在有效产生式（I）化合物的条件下使氟化C 2烯烃如四氟乙烯与C1加成剂反应的步骤。
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公开(公告)号：US08901360B2
公开(公告)日：2014-12-02
申请号：US13110979
申请日：2011-05-19
IPC分类号： C07C21/18 , C07C17/278 , C07C17/04 , C07C17/20 , C07C17/23 , C07C17/25 , C07C17/354
CPC分类号： C07C17/278 , C07C17/04 , C07C17/206 , C07C17/23 , C07C17/25 , C07C17/354 , C07C19/10 , C07C21/22 , C07C21/18
摘要： Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluorobutene comprising the steps of (a) reacting CCl4 with a compound having the formula CF3CX═CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF3CXClCXHCCl3; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF3CXHCXHCF3; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF3C≡CCF3; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula:
摘要翻译： 公开了一种制备顺式-1,1,1,4,4,4-六氟丁烯的方法，包括以下步骤：（a）使CCl4与具有式CF 3 C X = C X H的化合物反应，其中每个X独立地为卤素或氢， 形成式CF3CXClCXHCCl3的化合物; （b）氟化步骤（a）中形成的化合物以形成具有式CF 3 C XHCXHCF 3的化合物; （c）通过选自脱卤化氢，脱卤和两种反应的反应转化步骤（b）中形成的化合物，以形成具有式CF 3C≡CCF3的化合物; 和（d）用氢气将步骤（c）中形成的化合物催化还原以形成具有下式的化合物：
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公开(公告)号：US20100210883A1
公开(公告)日：2010-08-19
申请号：US12702135
申请日：2010-02-08
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Rajesh K. Dubey , Jing Ji Ma
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Rajesh K. Dubey , Jing Ji Ma
IPC分类号： C07C17/23 , C07C17/357
CPC分类号： C07C17/04 , C07C17/00 , C07C17/06 , C07C17/206 , C07C17/25 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18 , C07C19/08 , C07C19/10
摘要： Disclosed are methods for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CHXCH2X (I) to at least one compound of formula (II) CF3CZCHZ (II). where X is independently Cl, Br, I or F, and Z independently is H or F. In certain preferred embodiments, each Z is different.
摘要翻译： 公开了生产氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：CF 3 CHXCH 2 X（I）转化为至少一种式（II）CF 3 CZCHZ（II）化合物。 其中X独立地为Cl，Br，I或F，Z独立地为H或F.在某些优选实施方案中，每个Z不同。
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公开(公告)号：US20080242901A1
公开(公告)日：2008-10-02
申请号：US12134629
申请日：2008-06-06
IPC分类号： C07C17/00
CPC分类号： B01J27/125 , B01J27/10 , B01J27/12 , C07C17/00 , C07C17/278 , C07C21/18 , C07C19/08
摘要： A method for preparing fluorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at least one product having at least 3 carbon atoms.
摘要翻译： 一种制备氟化有机化合物的方法，其中至少一种氟化烯烃在气相和路易斯酸催化剂存在下与甲基氟反应形成至少一种具有至少3个碳原子的产物。
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