公开(公告)号：US5922636A

公开(公告)日：1999-07-13

申请号：US972951

申请日：1997-11-19

申请人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

发明人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

IPC分类号： B01J27/125 ,  C07C2/26 ,  B01J31/02 ,  B01J31/12 ,  B01J31/26

CPC分类号： B01J31/0212 ,  B01J27/125 ,  C07C2/26 ,  B01J2231/20 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/26

摘要： A catalyst composition for use in oligomerization of olefins contained in refinery distillate streams including paraffins, naphthenes, and aromatics therein, the catalyst consisting of a first constituent which is at least one aluminum halide; and a second constituent which is at least one alkoxide of a transition metal of Group IVB of the Periodic Table and which has a general formula:M(OR).sub.4,where M is selected from the group consisting of metals of Group IVB of the Periodic Table and R is one of (a) an alkyl group having from 1-12 carbon atoms or (b) an alkylaryl group having an alkyl chain having from 1-12 carbon atoms.

摘要翻译： 一种催化剂组合物，用于在包含石油馏出物流中的烯烃的低聚反应中，其中包括烷烃，环烷烃和芳烃，所述催化剂由至少一种卤化铝的第一组分组成; 和第二组分，其为元素周期表IVB族过渡金属的至少一种醇盐，其具有通式M（OR）4，其中M选自周期表IVB族的金属 表和R是（a）具有1-12个碳原子的烷基或（b）具有1-12个碳原子的烷基链的烷基芳基之一。

公开(公告)号：US6096678A

公开(公告)日：2000-08-01

申请号：US64138

申请日：1998-04-22

申请人： Sabyasachi Sinha Ray ,  Rakesh Sarin ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Swaminathan Sivaram ,  Thekke Pangil Mohandas ,  Dattatraya Haribhau Gholap ,  Mallinamadugu Jogimarappa Gari Yanjarappa

发明人： Sabyasachi Sinha Ray ,  Rakesh Sarin ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Swaminathan Sivaram ,  Thekke Pangil Mohandas ,  Dattatraya Haribhau Gholap ,  Mallinamadugu Jogimarappa Gari Yanjarappa

IPC分类号： B01J27/125 ,  B01J31/14 ,  B01J31/00 ,  C07C2/02 ,  C07C2/24

CPC分类号： B01J27/125 ,  B01J31/143 ,  B01J2231/20

摘要： A process for the preparation of an inert oxide supported metal halide organo aluminium compound catalyst. The catalyst is obtained by reacting an activated support having surface hydroxyl groups with aluminium chloride selected from aluminium chloride solution and aluminium chloride vapors. A solution of an aluminium alkyl is added to the reacted support. The solvent is removed and the reacted support is dried.

摘要翻译： 一种制备惰性氧化物负载金属卤化物有机铝化合物催化剂的方法。 该催化剂通过使具有表面羟基的活性载体与选自氯化铝溶液和氯化铝蒸汽的氯化铝反应而获得。 向反应的载体中加入烷基铝溶液。 除去溶剂并干燥反应的载体。

公开(公告)号：US06184429B2

公开(公告)日：2001-02-06

申请号：US09354844

申请日：1999-07-16

申请人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

发明人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

IPC分类号： C07C202

CPC分类号： B01J31/0212 ,  B01J27/125 ,  B01J2231/20 ,  C07C2/26 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/26

摘要： This invention relates to a catalyst composition capable of effecting selective oligomerisation of olefins contained in cracked refinery distillate streams, comprising of olefins, aromatics, paraffins and cycloparaffins. The catalyst composition gives very high conversion of olefins to poly olefins, which after distillation and stabilization by hydrogenation affords lubricating oil base stocks. The catalyst composition comprises of an aluminum halide and a transition metal alkoxide belonging to group IVB.

摘要翻译： 本发明涉及一种催化剂组合物，其能够对包含在烯烃，芳族化合物，链烷烃和环烷烃的裂化炼油馏出物流中的烯烃进行选择性低聚。 催化剂组合物提供非常高的烯烃转化为聚烯烃，其在蒸馏和通过氢化稳定化后提供润滑油基础油。 催化剂组合物包含属于IVB族的卤化铝和过渡金属醇盐。

公开(公告)号：US6002060A

公开(公告)日：1999-12-14

申请号：US64177

申请日：1998-04-22

申请人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Swaminathan Sivaram ,  Thekke Pangil Mohandas ,  Dattatraya Haribhau Gholap ,  Mallinamadugu Jogimarappa Gari Yanjarappa

发明人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Swaminathan Sivaram ,  Thekke Pangil Mohandas ,  Dattatraya Haribhau Gholap ,  Mallinamadugu Jogimarappa Gari Yanjarappa

IPC分类号： C07C2/30 ,  C07C2/02

CPC分类号： C07C2/30 ,  C07C2527/126 ,  C07C2531/14 ,  C07C2531/26

摘要： A process for the oligomerization and co-oligomerization of alpha olefins by subjecting olefins to the step of oligomerization in the presence of a supported aluminum chloride catalyst and an organoaluminum compound as a promoter. The catalyst is separated and the reaction product is subjected to the step of fractional distillation for removal of the solvent. The oligomers are further fractionated to obtain poly alpha olefins.

摘要翻译： 一种通过在负载氯化铝催化剂和有机铝化合物作为助催化剂的存在下使烯烃进行低聚步骤来使α-烯烃低聚和共低聚的方法。 分离催化剂，反应产物进行分馏步骤以除去溶剂。 将低聚物进一步分馏以获得聚α烯烃。

公开(公告)号：US5714661A

公开(公告)日：1998-02-03

申请号：US655925

申请日：1996-05-31

申请人： Deepak Kumar Tuli ,  Sabyasachi Sinha Ray ,  Rakesh Sarin ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

发明人： Deepak Kumar Tuli ,  Sabyasachi Sinha Ray ,  Rakesh Sarin ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

IPC分类号： B01J29/08 ,  C07C2/12 ,  C07C11/02 ,  C10G50/02 ,  C07C2/10 ,  C07C2/74

CPC分类号： C10G50/02 ,  B01J29/084 ,  C07C11/02 ,  C07C2/12 ,  B01J2229/16 ,  C07C2529/08

摘要： A process for the preparation of oligomers which are used in synthetic lubricant base stocks. The oligomers are prepared by contacting a mixture of linear olefins and n-paraffins contained in cracked refinery streams having 6 to 24 carbon atoms with activated Y-zeolites. The oligomers and unreacted monomers are subjected to the step of hydrogenation and the lower saturated paraffins are separated therefrom to produce synthetic lubricant base stock.

摘要翻译： 用于制备合成润滑剂基础油料中的低聚物的方法。 低聚物的制备方法是将具有6至24个碳原子的裂解精炼料流中所含的直链烯烃和正链烷烃的混合物与活化的Y-沸石接触。 将低聚物和未反应的单体进行氢化步骤，从其中分离出较低的饱和链烷烃以制备合成润滑剂基础油料。

公开(公告)号：US6015768A

公开(公告)日：2000-01-18

申请号：US64139

申请日：1998-04-22

申请人： Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Meeta Sharma ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Prabhat Kumar Saxena ,  Swaminathan Sivaram

发明人： Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Meeta Sharma ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Prabhat Kumar Saxena ,  Swaminathan Sivaram

IPC分类号： B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  C08F4/646 ,  C08F210/16 ,  B01J31/00 ,  B01J23/00 ,  B01J23/58 ,  B01J27/135

CPC分类号： B01J31/143 ,  B01J31/0211 ,  B01J31/0212 ,  C08F210/16

摘要： A process for the preparation of heterogeneous zirconium based catalyst for polymerization of alpha-olefins to super high molecular weight poly (alpha-olefins). The process comprises in mixing zirconium alcholate or phenolate with anhydrous magnesium chloride in the presence of a solvent. The mixture is heated, then cooled and an organoaluminum compound is added. Optionally, an electron donor compound is added and heated to obtain a black slurry, which is cooled and then washed with a hydrocarbon diluent.

摘要翻译： 制备用于将α-烯烃聚合成超高分子量聚（α-烯烃）的非均相锆基催化剂的方法。 该方法包括在溶剂存在下将烷基铝酸盐或酚盐与无水氯化镁混合。 将混合物加热，然后冷却，并加入有机铝化合物。 任选地，加入电子给体化合物并加热，得到黑色浆料，将其冷却，然后用烃稀释剂洗涤。