摘要:
A catalyst composition for use in oligomerization of olefins contained in refinery distillate streams including paraffins, naphthenes, and aromatics therein, the catalyst consisting of a first constituent which is at least one aluminum halide; and a second constituent which is at least one alkoxide of a transition metal of Group IVB of the Periodic Table and which has a general formula:M(OR).sub.4,where M is selected from the group consisting of metals of Group IVB of the Periodic Table and R is one of (a) an alkyl group having from 1-12 carbon atoms or (b) an alkylaryl group having an alkyl chain having from 1-12 carbon atoms.
摘要:
A process for the preparation of an inert oxide supported metal halide organo aluminium compound catalyst. The catalyst is obtained by reacting an activated support having surface hydroxyl groups with aluminium chloride selected from aluminium chloride solution and aluminium chloride vapors. A solution of an aluminium alkyl is added to the reacted support. The solvent is removed and the reacted support is dried.
摘要:
This invention relates to a catalyst composition capable of effecting selective oligomerisation of olefins contained in cracked refinery distillate streams, comprising of olefins, aromatics, paraffins and cycloparaffins. The catalyst composition gives very high conversion of olefins to poly olefins, which after distillation and stabilization by hydrogenation affords lubricating oil base stocks. The catalyst composition comprises of an aluminum halide and a transition metal alkoxide belonging to group IVB.
摘要:
A process for the oligomerization and co-oligomerization of alpha olefins by subjecting olefins to the step of oligomerization in the presence of a supported aluminum chloride catalyst and an organoaluminum compound as a promoter. The catalyst is separated and the reaction product is subjected to the step of fractional distillation for removal of the solvent. The oligomers are further fractionated to obtain poly alpha olefins.
摘要:
A process for the preparation of oligomers which are used in synthetic lubricant base stocks. The oligomers are prepared by contacting a mixture of linear olefins and n-paraffins contained in cracked refinery streams having 6 to 24 carbon atoms with activated Y-zeolites. The oligomers and unreacted monomers are subjected to the step of hydrogenation and the lower saturated paraffins are separated therefrom to produce synthetic lubricant base stock.
摘要:
A process for the preparation of heterogeneous zirconium based catalyst for polymerization of alpha-olefins to super high molecular weight poly (alpha-olefins). The process comprises in mixing zirconium alcholate or phenolate with anhydrous magnesium chloride in the presence of a solvent. The mixture is heated, then cooled and an organoaluminum compound is added. Optionally, an electron donor compound is added and heated to obtain a black slurry, which is cooled and then washed with a hydrocarbon diluent.
摘要:
The present invention provides a process for the upgradation of petroleum residue into useful fractions by subjecting petroleum residue in the presence of a solvent and ferrous sulphate catalyst to a pressure in the range of 10 atm. to 120 atm., temperature in the range of 380-420° C., for a period in the range of 0-120 minutes, in a reactor vessel, in an inert atmosphere. The charge is then cooled to room temperature and the product gas released through scrubbers. The residue is re-heated, if required, for free flow of liquid product. The resulting liquid product is distilled to obtain useful fractions.
摘要:
The present invention relates to a process for enhancing the yield of molecular sieve zeolite during the synthesis from a sodium aluminosilicate reaction mixture, said process comprising the step of adding at an intermediate stage of crystallization a source of aluminum to the sodium aluminosilicate reaction mixture and allowing the mixture to crystallize.
摘要:
A process for preparing bi-functional catalyst for Fluid Catalytic Cracking (FCC), that comprises molecular sieves, modified clay and semi-basic alumina and the catalyst for highly effective cracking of high boiling petroleum feedstock to provide simultaneously, enhanced yields of Liquefied Petroleum Gas (LPG) and reduction of undesirable bottoms.
摘要:
A fluidized catalytic cracking process for catalytically cracking a feed to lighter products includes introducing a heated catalyst and the feed into a bottom riser of a fluidized catalytic cracking apparatus and allowing the heated catalyst and the feed to preaccelerate upwardly within the bottom riser as a mixture; flowing the mixture upwardly from the bottom riser through a plurality of microriser tubes disposed within a regenerator under conditions effective to cause a cracking reaction of the hydrocarbons and result in a mixture including coked catalyst and hydrocarbon vapors; passing the mixture from the microriser tubes through a catalyst separator for separating the coked catalyst from the hydrocarbon vapors; collecting coked catalyst in a stripper for stripping out hydrocarbon vapors carried along with the coked catalyst and introducing the coked catalyst collected into a regenerator; simultaneous with flowing the mixture, combusting the coked catalyst within the regenerator under conditions effective to cause regeneration of the catalyst so that hot regenerated catalyst is produced and heat transferred to the microriser tubes; introducing the hot regenerated catalyst from the regenerator into the bottom riser for facilitating continuous operation; and directing hydrocarbon vapors from the catalyst separator and from the stripper to a fractionator for separation of products.