公开(公告)号：US6015768A

公开(公告)日：2000-01-18

申请号：US64139

申请日：1998-04-22

申请人： Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Meeta Sharma ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Prabhat Kumar Saxena ,  Swaminathan Sivaram

发明人： Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Meeta Sharma ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Prabhat Kumar Saxena ,  Swaminathan Sivaram

IPC分类号： B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  C08F4/646 ,  C08F210/16 ,  B01J31/00 ,  B01J23/00 ,  B01J23/58 ,  B01J27/135

CPC分类号： B01J31/143 ,  B01J31/0211 ,  B01J31/0212 ,  C08F210/16

摘要： A process for the preparation of heterogeneous zirconium based catalyst for polymerization of alpha-olefins to super high molecular weight poly (alpha-olefins). The process comprises in mixing zirconium alcholate or phenolate with anhydrous magnesium chloride in the presence of a solvent. The mixture is heated, then cooled and an organoaluminum compound is added. Optionally, an electron donor compound is added and heated to obtain a black slurry, which is cooled and then washed with a hydrocarbon diluent.

摘要翻译： 制备用于将α-烯烃聚合成超高分子量聚（α-烯烃）的非均相锆基催化剂的方法。 该方法包括在溶剂存在下将烷基铝酸盐或酚盐与无水氯化镁混合。 将混合物加热，然后冷却，并加入有机铝化合物。 任选地，加入电子给体化合物并加热，得到黑色浆料，将其冷却，然后用烃稀释剂洗涤。

公开(公告)号：US6096678A

公开(公告)日：2000-08-01

申请号：US64138

申请日：1998-04-22

申请人： Sabyasachi Sinha Ray ,  Rakesh Sarin ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Swaminathan Sivaram ,  Thekke Pangil Mohandas ,  Dattatraya Haribhau Gholap ,  Mallinamadugu Jogimarappa Gari Yanjarappa

发明人： Sabyasachi Sinha Ray ,  Rakesh Sarin ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Swaminathan Sivaram ,  Thekke Pangil Mohandas ,  Dattatraya Haribhau Gholap ,  Mallinamadugu Jogimarappa Gari Yanjarappa

IPC分类号： B01J27/125 ,  B01J31/14 ,  B01J31/00 ,  C07C2/02 ,  C07C2/24

CPC分类号： B01J27/125 ,  B01J31/143 ,  B01J2231/20

摘要： A process for the preparation of an inert oxide supported metal halide organo aluminium compound catalyst. The catalyst is obtained by reacting an activated support having surface hydroxyl groups with aluminium chloride selected from aluminium chloride solution and aluminium chloride vapors. A solution of an aluminium alkyl is added to the reacted support. The solvent is removed and the reacted support is dried.

摘要翻译： 一种制备惰性氧化物负载金属卤化物有机铝化合物催化剂的方法。 该催化剂通过使具有表面羟基的活性载体与选自氯化铝溶液和氯化铝蒸汽的氯化铝反应而获得。 向反应的载体中加入烷基铝溶液。 除去溶剂并干燥反应的载体。

公开(公告)号：US6002060A

公开(公告)日：1999-12-14

申请号：US64177

申请日：1998-04-22

申请人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Swaminathan Sivaram ,  Thekke Pangil Mohandas ,  Dattatraya Haribhau Gholap ,  Mallinamadugu Jogimarappa Gari Yanjarappa

发明人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar ,  Swaminathan Sivaram ,  Thekke Pangil Mohandas ,  Dattatraya Haribhau Gholap ,  Mallinamadugu Jogimarappa Gari Yanjarappa

IPC分类号： C07C2/30 ,  C07C2/02

CPC分类号： C07C2/30 ,  C07C2527/126 ,  C07C2531/14 ,  C07C2531/26

摘要： A process for the oligomerization and co-oligomerization of alpha olefins by subjecting olefins to the step of oligomerization in the presence of a supported aluminum chloride catalyst and an organoaluminum compound as a promoter. The catalyst is separated and the reaction product is subjected to the step of fractional distillation for removal of the solvent. The oligomers are further fractionated to obtain poly alpha olefins.

摘要翻译： 一种通过在负载氯化铝催化剂和有机铝化合物作为助催化剂的存在下使烯烃进行低聚步骤来使α-烯烃低聚和共低聚的方法。 分离催化剂，反应产物进行分馏步骤以除去溶剂。 将低聚物进一步分馏以获得聚α烯烃。

公开(公告)号：US5922636A

公开(公告)日：1999-07-13

申请号：US972951

申请日：1997-11-19

申请人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

发明人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

IPC分类号： B01J27/125 ,  C07C2/26 ,  B01J31/02 ,  B01J31/12 ,  B01J31/26

CPC分类号： B01J31/0212 ,  B01J27/125 ,  C07C2/26 ,  B01J2231/20 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/26

摘要： A catalyst composition for use in oligomerization of olefins contained in refinery distillate streams including paraffins, naphthenes, and aromatics therein, the catalyst consisting of a first constituent which is at least one aluminum halide; and a second constituent which is at least one alkoxide of a transition metal of Group IVB of the Periodic Table and which has a general formula:M(OR).sub.4,where M is selected from the group consisting of metals of Group IVB of the Periodic Table and R is one of (a) an alkyl group having from 1-12 carbon atoms or (b) an alkylaryl group having an alkyl chain having from 1-12 carbon atoms.

摘要翻译： 一种催化剂组合物，用于在包含石油馏出物流中的烯烃的低聚反应中，其中包括烷烃，环烷烃和芳烃，所述催化剂由至少一种卤化铝的第一组分组成; 和第二组分，其为元素周期表IVB族过渡金属的至少一种醇盐，其具有通式M（OR）4，其中M选自周期表IVB族的金属 表和R是（a）具有1-12个碳原子的烷基或（b）具有1-12个碳原子的烷基链的烷基芳基之一。

公开(公告)号：US06184429B2

公开(公告)日：2001-02-06

申请号：US09354844

申请日：1999-07-16

申请人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

发明人： Rakesh Sarin ,  Sabyasachi Sinha Ray ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

IPC分类号： C07C202

CPC分类号： B01J31/0212 ,  B01J27/125 ,  B01J2231/20 ,  C07C2/26 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/26

摘要： This invention relates to a catalyst composition capable of effecting selective oligomerisation of olefins contained in cracked refinery distillate streams, comprising of olefins, aromatics, paraffins and cycloparaffins. The catalyst composition gives very high conversion of olefins to poly olefins, which after distillation and stabilization by hydrogenation affords lubricating oil base stocks. The catalyst composition comprises of an aluminum halide and a transition metal alkoxide belonging to group IVB.

摘要翻译： 本发明涉及一种催化剂组合物，其能够对包含在烯烃，芳族化合物，链烷烃和环烷烃的裂化炼油馏出物流中的烯烃进行选择性低聚。 催化剂组合物提供非常高的烯烃转化为聚烯烃，其在蒸馏和通过氢化稳定化后提供润滑油基础油。 催化剂组合物包含属于IVB族的卤化铝和过渡金属醇盐。

公开(公告)号：US5714661A

公开(公告)日：1998-02-03

申请号：US655925

申请日：1996-05-31

申请人： Deepak Kumar Tuli ,  Sabyasachi Sinha Ray ,  Rakesh Sarin ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

发明人： Deepak Kumar Tuli ,  Sabyasachi Sinha Ray ,  Rakesh Sarin ,  Madan Mohan Rai ,  Sobhan Ghosh ,  Akhilesh Kumar Bhatnagar

IPC分类号： B01J29/08 ,  C07C2/12 ,  C07C11/02 ,  C10G50/02 ,  C07C2/10 ,  C07C2/74

CPC分类号： C10G50/02 ,  B01J29/084 ,  C07C11/02 ,  C07C2/12 ,  B01J2229/16 ,  C07C2529/08

摘要： A process for the preparation of oligomers which are used in synthetic lubricant base stocks. The oligomers are prepared by contacting a mixture of linear olefins and n-paraffins contained in cracked refinery streams having 6 to 24 carbon atoms with activated Y-zeolites. The oligomers and unreacted monomers are subjected to the step of hydrogenation and the lower saturated paraffins are separated therefrom to produce synthetic lubricant base stock.

摘要翻译： 用于制备合成润滑剂基础油料中的低聚物的方法。 低聚物的制备方法是将具有6至24个碳原子的裂解精炼料流中所含的直链烯烃和正链烷烃的混合物与活化的Y-沸石接触。 将低聚物和未反应的单体进行氢化步骤，从其中分离出较低的饱和链烷烃以制备合成润滑剂基础油料。

公开(公告)号：US5916850A

公开(公告)日：1999-06-29

申请号：US965147

申请日：1997-11-06

申请人： Deepak Kumar Tuli ,  Rakesh Sarin ,  Madan Mohan Rai ,  Akhilesh Kumar Bhatnagar

发明人： Deepak Kumar Tuli ,  Rakesh Sarin ,  Madan Mohan Rai ,  Akhilesh Kumar Bhatnagar

IPC分类号： C07F9/18 ,  C10M137/10 ,  C10M137/08

CPC分类号： C10M137/105 ,  C07F9/18 ,  C10M2223/047

摘要： A process for the preparation of amino di(alkylaryl) phosphorodithioate for use as an additive in a lubricant composition so as to impart improved coefficient of friction, wear reduction, antioxidant and extreme pressure properties, including the steps of(a) reacting a starting material selected from the group consisting of distilled cashew nut shell liquid and distilled hydrogenated cashew nut shell liquid with phosphorus pentasulfide to obtain unpolymerized cashew nut shell liquid phosphorodithioic acid, the reacting being carried out at a temperature ranging from 40 to 80.degree. C. when the starting material is distilled cashew nut shell liquid and at a temperature ranging up to 140.degree. C. and above when the starting material is distilled hydrogenated cashew nut shell liquid; and(b) condensing the unpolymerized cashew nut shell liquid phosphorodithioic acid with at least one amine to obtain the amino di(alkylaryl) phosphorodithioate. A lubricant containing a major proportion of a material selected from the group consisting of an oil of lubricating viscosity and a grease; and remainder an additive including amino di(alkylaryl)phosphorodithioate prepared by the foregoing process.

摘要翻译： 一种制备用于润滑剂组合物中的添加剂的氨基二（烷基芳基）二硫代磷酸酯的方法，以提供改进的摩擦系数，磨损降低，抗氧化和极压性能，包括以下步骤：（a）使起始材料 选自蒸馏腰果壳液和蒸馏氢化腰果壳液与五硫化二磷组成的组，得到未聚合的腰果壳液体二硫代磷酸，反应在40〜80℃的温度下进行，当起始 材料为蒸馏后的腰果壳油，温度范围高达140℃以上时，原料为蒸馏氢化腰果壳液; 和（b）将未聚合的腰果壳液体二硫代磷酸与至少一种胺缩合以获得氨基二（烷基芳基）二硫代磷酸酯。 含有大部分选自润滑粘度油和油脂的材料的润滑剂的润滑剂; 并且其余为包括通过上述方法制备的氨基二（烷基芳基）二硫代磷酸酯的添加剂。

公开(公告)号：US5910468A

公开(公告)日：1999-06-08

申请号：US55213

申请日：1998-04-06

申请人： Khem Chand Dohhen ,  Harish Chander Bhatia ,  Krishan Kumar Swami ,  Rakesh Sarin ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Akhilesh Kumar Bhatnagar

发明人： Khem Chand Dohhen ,  Harish Chander Bhatia ,  Krishan Kumar Swami ,  Rakesh Sarin ,  Deepak Kumar Tuli ,  Madan Mohan Rai ,  Akhilesh Kumar Bhatnagar

IPC分类号： C10M159/22

CPC分类号： C10M159/22

摘要： A process for the preparation of sulphurized calcium phenate from cashew nut shell liquid (CNSL). Distilled or hydrogenated distilled CNSL is reacted with calcium salt and sulphur in the presence of promoters to obtain a reaction mixture. The reaction mixture is subjected to the step of carbonation to obtain basic sulfurized calcium phenate, which may be subjected to a further step of basefication to obtain overbased sulphurized calcium phenate. Such a calcium phenate is added to lubricating oil or grease as an additive.

摘要翻译： 一种从腰果壳液（CNSL）制备硫酸化酚钙的方法。 蒸馏或氢化蒸馏的CNSL与促进剂存在下的钙盐和硫反应，得到反应混合物。 将反应混合物进行碳酸化步骤以获得碱性硫化酚钙，其可以进一步进行碱化步骤以获得高碱性硫酸化酚钙。 将这种苯酚钙添加到润滑油或油脂中作为添加剂。

公开(公告)号：US07427303B2

公开(公告)日：2008-09-23

申请号：US10494385

申请日：2002-08-27

申请人： Rakesh Sarin ,  Deepak Kumar Tuli ,  Shanti Parkash ,  Krishan Kumar Swami ,  Rajiv Ranjan ,  Ram Prakash Verma ,  Niranjan Raghunath Raje ,  Akhilesh Kumar Bhatnagar

发明人： Rakesh Sarin ,  Deepak Kumar Tuli ,  Shanti Parkash ,  Krishan Kumar Swami ,  Rajiv Ranjan ,  Ram Prakash Verma ,  Niranjan Raghunath Raje ,  Akhilesh Kumar Bhatnagar

IPC分类号： C10L1/32

CPC分类号： C10L1/328 ,  C10L1/1852 ,  C10L1/191 ,  C10L1/1985 ,  C10L1/2225 ,  C10L1/231 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/2456

摘要： The present invention relates a surfactant composition for use as an emulsifier in water blended fuel mixture. The said composition includes ethoxylate of cashew nut shell liquid. In addition ethoxylate of cashew nut shell liquid, the said composition comprises a co-surfactant having a hydrophilic lipophilic balance in the range of 4 to 12 and a polymeric dispersant. The water blended fuel mixture using emulsifiers of the present invention, overcome some of the shortcomings of the previously known emulsions. The ethoxylate of cashew nut shell liquid is of the formula (I).

摘要翻译： 本发明涉及在水混合燃料混合物中用作乳化剂的表面活性剂组合物。 所述组合物包括腰果壳液体的乙氧基化物。 此外，腰果壳液体的乙氧基化物，所述组合物包含亲水亲油平衡在4至12范围内的助表面活性剂和聚合物分散剂。 使用本发明的乳化剂的水混合燃料混合物克服了先前已知的乳液的一些缺点。 腰果壳液的乙氧基化物为式（I）。

公开(公告)号：US5854182A

公开(公告)日：1998-12-29

申请号：US728052

申请日：1996-10-09

申请人： Krishan Kumar Swami ,  Anurag Ateet Gupta ,  Shanti Parkash ,  Madan Mohan Rai ,  Akhilesh Kumar Bhatnagar

发明人： Krishan Kumar Swami ,  Anurag Ateet Gupta ,  Shanti Parkash ,  Madan Mohan Rai ,  Akhilesh Kumar Bhatnagar

IPC分类号： C10M159/24

CPC分类号： C10M159/24

摘要： Magnesium borate overbased metallic detergent having magnesium borate uniformally dispersed in an extremely fine particle size is prepared by using magnesium alkoxide and boric acid. The process for preparation involves reacting neutral sulphonate of an alkaline earth metal with magnesium alkoxide and boric acid under anhydrous conditions in the presence of a dilution solvent followed by distillation to remove alcohol and part of dilution solvent therefrom. The borated mixture is then cooled, filtered to recover magnesium borated metal detergent. The magnesium borated metal detergent exhibited excellent cleaning and dispersing performance, very good hydrolytic and oxidation stability, good extreme pressure and antiwear properties. Such a detergent can advantageously be used in a hydrocarbon composition.

摘要翻译： 通过使用烷氧化镁和硼酸制备硼酸镁高碱性金属洗涤剂，其具有均匀分散在极细颗粒中的硼酸镁。 制备方法包括在无水条件下在稀释溶剂存在下使碱土金属的中性磺酸盐与烷氧基镁和硼酸反应，然后蒸馏以除去醇和部分稀释溶剂。 然后将硼酸化的混合物冷却，过滤以回收硼酸镁金属洗涤剂。 镁硼化金属洗涤剂表现出优异的清洗和分散性能，非常好的水解和氧化稳定性，极好的极压和抗磨性能。 这种洗涤剂可以有利地用于烃组合物中。