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公开(公告)号：US06794549B2
公开(公告)日：2004-09-21
申请号：US10360192
申请日：2003-02-06
IPC分类号： C07C20500
CPC分类号： C07C201/08 , C07C205/12
摘要： The present invention relates to a continuous adiabatic process for preparing nitrochlorobenzene in the presence of phosphoric acid. The waste acid produced during the practice of the process is reconcentrated and recycled into the nitration reaction.
摘要翻译： 本发明涉及在磷酸存在下制备硝基氯苯的连续绝热方法。 在该过程的实践过程中产生的废酸被再浓缩并再循环到硝化反应中。
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2.发明授权Continuous isothermal process for preparing mononitrotoluenes in the presence of phosphoric acid 失效在磷酸存在下制备单硝基甲苯的连续等温方法公开(公告)号：US06768032B2
公开(公告)日：2004-07-27
申请号：US10114288
申请日：2002-04-02
IPC分类号： C07C20500
CPC分类号： C07C201/08 , C07C205/06
摘要： The present invention relates to a continuous isothermal process for preparing mononitrotoluenes in the presence of a mixed acid component comprising mixtures of sulfuric acid and phosphoric acid with concentration of the resultant waste acid and recycling of the concentrated waste acid to the process.
摘要翻译： 本发明涉及在包含硫酸和磷酸的混合物的混合酸组分存在下制备单硝基甲苯的连续等温方法，浓缩所得废酸并将浓缩的废酸再循环到该方法中。
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公开(公告)号：US20060229468A1
公开(公告)日：2006-10-12
申请号：US11392009
申请日：2006-03-29
申请人： Bjorn Schlummer , Florian Rampf , Paul Naab , Guido Giffels , Matthias Gotta
发明人： Bjorn Schlummer , Florian Rampf , Paul Naab , Guido Giffels , Matthias Gotta
IPC分类号： C07C309/00
CPC分类号： C07C303/22 , C07C303/00 , C07C309/00
摘要： The present invention relates to a process for preparing optionally substituted arylsulphonic anhydrides of the general formula (I)
摘要翻译： 本发明涉及制备通式（I）的任选取代的芳基磺酸酐的方法，
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4.发明申请Method for Allylating and Vinylating Aryl, Heteroaryl, Alkyl, and Alkene Halogenides Using Transition Metal Catalysis 有权使用过渡金属催化烯化和乙酰化芳基，杂芳基，烷基和烯烃卤化物的方法公开(公告)号：US20130184485A1
公开(公告)日：2013-07-18
申请号：US13577278
申请日：2011-02-01
申请人： Matthias Gotta , Bernd Wilhelm Lehnemann , Waldemar Maximilian Czaplik , Matthias Mayer , Axel Jacobi Von Wangelin
发明人： Matthias Gotta , Bernd Wilhelm Lehnemann , Waldemar Maximilian Czaplik , Matthias Mayer , Axel Jacobi Von Wangelin
IPC分类号： C07C253/04 , C07C1/30 , C07C17/26 , C07C209/74 , C07C41/24
CPC分类号： C07C253/04 , C07B37/04 , C07B49/00 , C07C1/30 , C07C1/326 , C07C17/26 , C07C17/2632 , C07C41/24 , C07C41/30 , C07C67/343 , C07C209/68 , C07C209/74 , C07C253/30 , C07C2527/128 , C07C2531/22 , C07C2603/26 , C07C11/02 , C07C15/44 , C07C43/2055 , C07C43/205 , C07C69/612 , C07C25/24 , C07C211/48 , C07C255/50
摘要： What is described is a process for preparing organic compounds of the general formula (I) R—R′ (I) by converting a corresponding compound of the general formula (II) R—X (II) in which X is fluorine, chlorine, bromine or iodine to an organomagnesium compound of the general formula (III) [M+]n[RmMgXkY1] (III) wherein compounds of the formula (III) are reacted with a compound of the general formula (IV) characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic amounts of an iron compound, based on the compound of the general formula (II), and optionally in the presence of b) a nitrogen-, oxygen- and/or phosphorus-containing additive in a catalytic or stoichiometric amount, based on the compound of the general formula (II).
摘要翻译： 描述的是通过将相应的通式（II）RX（II）的化合物（其中X是氟，氯，溴或溴）或其盐，其中R 1，R 2， 碘与通式（III）的化合物（III）反应的通式（III）的有机镁化合物[M +] n [RmMgXkY1]（III）其中式（III）化合物与通式（IV）的化合物反应，其特征在于（III ）与（IV）化合物在（a）催化量的铁化合物（基于通式（II）的化合物）存在下进行，任选在b）氮，氧和/或磷 基于通式（II）的化合物，催化剂或化学计量的添加剂。
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5.发明申请PROCESS FOR PREPARING ORGANIC COMPOUNDS BY A TRANSITION METAL-CATALYSED CROSS-COUPLING REACTION OF AN ARYL-X, HETEROARYL-X, CYCLOALKENYL-X OR ALKENYL-X COMPOUND WITH AN ALKYL, ALKENYL, CYCLOALKYL OR CYCLOALKENYL HALIDE 审中-公开通过亚苄基，亚苄基，环烷基或环烷基卤化物的ARYL-X，HETEROARYL-X，CYCLOALKENYL-X或ALKENYL-X化合物的过渡金属催化交联偶联反应制备有机化合物的方法公开(公告)号：US20120046471A1
公开(公告)日：2012-02-23
申请号：US13232028
申请日：2011-09-14
IPC分类号： C07D213/16 , C07C1/26 , C07C209/68 , C07C67/343 , C07C41/30
CPC分类号： C07C1/326 , C07B37/04 , C07C2523/745 , C07C2523/75
摘要： This invention relates to a process for preparing functionalized aryl, heteroaryl, cycloalkenyl, or alkenyl compounds, by a transition-metal-catalyzed cross-coupling reaction of a substituted or unsubstituted aryl-X, heteroaryl-X, cycloalkenyl-X or alkenyl-X compound with an alkyl, alkenyl, cycloalkyl or cycloalkenyl halide, where X is a halide, diazonium, tosylate (p-toluenesulphonate), mesylate (methanesulphonate) or triflate (trifluoromethanesulphonate) leaving group.
摘要翻译： 本发明涉及通过取代或未取代的芳基-X，杂芳基-X，环烯基-X或链烯基-X的过渡金属催化交叉偶联反应制备官能化芳基，杂芳基，环烯基或烯基化合物的方法 与烷基，烯基，环烷基或环烯基卤化物的化合物，其中X是卤化物，重氮，甲苯磺酸酯（对甲苯磺酸酯），甲磺酸酯（甲磺酸酯）或三氟甲磺酸酯（三氟甲磺酸酯）离去基团。
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6.发明授权Method for allylating and vinylating aryl, heteroaryl, alkyl, and alkene halogenides using transition metal catalysis 有权使用过渡金属催化烯化和烯化芳基，杂芳基，烷基和烯烃卤化物的方法公开(公告)号：US09309188B2
公开(公告)日：2016-04-12
申请号：US13577278
申请日：2011-02-01
申请人： Matthias Gotta , Bernd Wilhelm Lehnemann , Waldemar Maximilian Czaplik , Matthias Mayer , Axel Jacobi Von Wangelin
发明人： Matthias Gotta , Bernd Wilhelm Lehnemann , Waldemar Maximilian Czaplik , Matthias Mayer , Axel Jacobi Von Wangelin
IPC分类号： C07B37/04 , C07B49/00 , C07C1/32 , C07C15/44 , C07C43/205 , C07C253/04 , C07C17/263 , C07C41/30 , C07C67/343 , C07C209/68 , C07C253/30 , C07C1/30 , C07C17/26 , C07C41/24 , C07C209/74
CPC分类号： C07C253/04 , C07B37/04 , C07B49/00 , C07C1/30 , C07C1/326 , C07C17/26 , C07C17/2632 , C07C41/24 , C07C41/30 , C07C67/343 , C07C209/68 , C07C209/74 , C07C253/30 , C07C2527/128 , C07C2531/22 , C07C2603/26 , C07C11/02 , C07C15/44 , C07C43/2055 , C07C43/205 , C07C69/612 , C07C25/24 , C07C211/48 , C07C255/50
摘要： What is described is a process for preparing organic compounds of the general formula (I) R—R′ (I) by converting a corresponding compound of the general formula (II) R—X (II) in which X is fluorine, chlorine, bromine or iodine to an organomagnesium compound of the general formula (III) [M+]n[RmMgXkY1] (III) wherein compounds of the formula (III) are reacted with a compound of the general formula (IV) characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic amounts of an iron compound, based on the compound of the general formula (II), and optionally in the presence of b) a nitrogen-, oxygen- and/or phosphorus-containing additive in a catalytic or stoichiometric amount, based on the compound of the general formula (II).
摘要翻译： 描述的是通过将相应的通式（II）化合物R-X（II）转化为其中X为氟，氯，氯， 溴或碘与通式（III）的有机镁化合物[M +] n [RmMgXkY1]（III）反应，其中式（III）化合物与通式（IV）的化合物反应，其特征在于： （III）与（IV）的化合物在a）催化量的铁化合物存在下进行，基于通式（II）的化合物，并且任选在b）氮，氧和/ 或基于通式（II）的化合物的催化或化学计量的含磷添加剂。
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公开(公告)号：US08304550B2
公开(公告)日：2012-11-06
申请号：US12275316
申请日：2008-11-21
申请人： Alain Cotte , Nikolaus Muller , Matthias Gotta , Matthias Beller , Thomas Schareina , Alexander Zapf
发明人： Alain Cotte , Nikolaus Muller , Matthias Gotta , Matthias Beller , Thomas Schareina , Alexander Zapf
IPC分类号： C07D213/63 , C07C209/00 , C07C41/01 , B01J31/18
CPC分类号： C07C41/16 , C07C201/12 , C07C213/00 , C07C231/12 , C07D213/643 , C07C217/90 , C07C233/25 , C07C205/38 , C07C43/275 , C07C43/263 , C07C43/257
摘要： Described is a process for preparing diaryl ethers of the formula (I) Ar—O—Ar′ (I) In which Ar is an aryl or substituted aryl group and Ar′ is an aryl, substituted aryl, heteroaryl or substituted heteroaryl group,by reacting an aryl of formula (II) or a aryloxy salt of formula (III) Ar—OH (II) Ar—OR (III) In which Ar has the same meaning as in formula (I) and R is an alkali metal,with an aryl or heteroaryl bromide of formula (IV) Ar′—Br (IV) In which Ar′ has the same meaning as in formula (I),characterized in that the reaction is carried out in the presence of a copper(I)salt and a 1-substituted imidazole as catalyst system.
摘要翻译： 描述了制备式（I）Ar-O-Ar'（I）的二芳基醚的方法，其中Ar是芳基或取代的芳基，Ar'是芳基，取代的芳基，杂芳基或取代的杂芳基，由 使式（II）的芳基或式（III）的芳氧基盐Ar-OH（II）Ar-OR（III）反应其中Ar具有与式（I）中相同的含义，R是碱金属，与 式（Ⅳ）的芳基或杂芳基溴Ar'-Br（Ⅳ）其中Ar'具有与式（I）中相同的含义，其特征在于该反应在铜（I）盐 和1-取代的咪唑作为催化剂体系。
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8.发明授权公开(公告)号：US08022255B2
公开(公告)日：2011-09-20
申请号：US12388779
申请日：2009-02-19
申请人： Alain Cotte , Matthias Gotta , Lukas Goossen , Felix Rudolphi , Christoph Oppel , Nuria Rodriguez Garrido
发明人： Alain Cotte , Matthias Gotta , Lukas Goossen , Felix Rudolphi , Christoph Oppel , Nuria Rodriguez Garrido
CPC分类号： C07C45/68 , C07C221/00 , C07C253/30 , C07D213/50 , C07D307/46 , C07D333/22 , C07C49/782 , C07C49/788 , C07C49/76 , C07C49/813 , C07C49/84 , C07C225/22 , C07C255/56
摘要： A process for preparing ketones of the general formula (III) where R is an optionally substituted carbocyclic aromatic radical having 6 to 24 carbon atoms or an optionally substituted alkyl radical or an optionally substituted heteroaromatic radical having 5 to 24 carbon atoms, and R1 is an optionally substituted carbocyclic aromatic radical having 6 to 24 carbon atoms or an optionally substituted heteroaromatic radical having 5 to 24 carbon atoms, by reacting alpha-oxo carboxylates of the general formula (I) wherein n and m is a number in the range from 1 to 6, M(m+) is a cation, and R has the meaning indicated for formula (III), with aryl bromides of the general formula (II) R1—Br (II) where R1 has the meaning indicated for formula (III), in the presence of two transition metals or compounds thereof as catalyst, is described.
摘要翻译： 一种制备通式（III）的酮的方法，其中R是具有6至24个碳原子的任选取代的碳环芳族基团或任选取代的烷基或任选取代的具有5至24个碳原子的杂芳族基团，R 1是 任选取代的碳原子数为6〜24的碳环芳基或具有5〜24个碳原子的任意取代的杂芳基，通式（I）的α-氧代羧酸盐反应，其中n和m为1〜 6，M（m +）为阳离子，R为式（III）所示的含义，通式（II）的芳基溴R1-Br（Ⅱ）其中R1具有式（Ⅲ）所示的含义， 在两种过渡金属或其化合物作为催化剂的存在下进行了描述。
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公开(公告)号：US07329779B2
公开(公告)日：2008-02-12
申请号：US11392009
申请日：2006-03-29
申请人： Björn Schlummer , Florian Rampf , Paul Naab , Guido Giffels , Matthias Gotta
发明人： Björn Schlummer , Florian Rampf , Paul Naab , Guido Giffels , Matthias Gotta
IPC分类号： C07C303/00
CPC分类号： C07C303/22 , C07C303/00 , C07C309/00
摘要： The present invention relates to a process for preparing optionally substituted arylsulphonic anhydrides of the general formula (I)
摘要翻译： 本发明涉及制备通式（I）的任选取代的芳基磺酸酐的方法，
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10.发明授权Copper-catalysed process for the production of substituted or unsubstituted trifluormethylated aryl and heteroaryl compounds 有权用于制备取代或未取代的三氟甲基化芳基和杂芳基化合物的铜催化方法公开(公告)号：US08530666B2
公开(公告)日：2013-09-10
申请号：US13281646
申请日：2011-10-26
申请人： Alain Cotté , Matthias Gotta , Matthias Beller , Thomas Schareina , Alexander Zapf , Xiao-Feng Wu
发明人： Alain Cotté , Matthias Gotta , Matthias Beller , Thomas Schareina , Alexander Zapf , Xiao-Feng Wu
IPC分类号： C07D211/72 , C07C69/00 , C07C69/76 , C07C22/08 , C07C43/20
CPC分类号： C07C17/263 , C07C41/30 , C07C45/68 , C07C67/343 , C07C253/30 , C07D213/74 , C07D471/04 , C07C25/22 , C07C22/08 , C07C25/02 , C07C25/13 , C07C255/50 , C07C43/225 , C07C69/76 , C07C69/92 , C07C49/80
摘要： The present invention relates to a process for the production of trifluoromethylated unsubstituted or substituted aryl or heteroaryl compounds which comprises reacting an unsubstituted or substituted aryl or heteroaryl halide with a trifluoroacetate of formula (I) or (II), wherein R1 is hydrogen or a C1-C5 alkyl group and M an alkali metal or an ammonium ion, in the presence of and an anorganic halogenide salt or a trifluoroacetacid salt as activator compound and a catalytic combination of a copper salt with a monodentate, bidentate or tridentate aromatic or aliphatic amine or pyridine ligand.
摘要翻译： 本发明涉及生产三氟甲基化的未取代或取代的芳基或杂芳基化合物的方法，其包括使未取代或取代的芳基或杂芳基卤化物与式（I）或（II）的三氟乙酸盐反应，其中R 1是氢或C 1 -C 5烷基和M碱金属或铵离子，并且在有机卤化物盐或三氟乙酸盐的存在下作为活化剂化合物和铜盐与单齿，二齿或三齿芳族或脂族胺的催化组合，或 吡啶配体。
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