摘要:
The present invention relates to novel two tail-two head and two tail-one head surfactants. In one embodiment, the present invention comprises a novel composition of matter having the general formula: ##STR1## wherein R1 and R2 may be the same or different and are selected from liner or branched hydrocarbon chains with carbon numbers 8 and 22;R3 is H, SO.sup.-.sub.y M.sup.+, or --O (CH2CH2O).sub.n X;R4 is SO.sup.-.sub.y M.sup.+, or --O (CH2CH2O).sub.n X;M is H, Li, Na, K, Rb or Cs;n is an integer from 2 to 50;y is 3 or 4; and,X is H or SO.sup.-.sub.y M.sup.-.Preferably, in the above composition when R3 is other than H, R3.dbd.R4.
摘要:
In one embodiment, the present invention relates to novel two tail--two head and two tail--one head surfactants. In one embodiment, the present invention comprises a novel composition of matter having the general formula: ##STR1## wherein R1 and R2 may be the same or different and are selected from linear or branched hydrocarbon chains with from 6 to 22 carbon atoms;R3 is H, SO.sup.13.sub.y M.sup.+, or --O(CH2CH2O).sub.n X;R4 is SO.sup.--.sub.y M.sup.+, or --O(CH2CH2O).sub.n X;M is H, Li, Na, K, Rb or Cs;n is an integer from 2 to 50;y is 3 or 4; and,X is H or SO.sup.13.sub.y M.sup.+.Preferably, in the above composition when R3 is other than H, R3=R4.
摘要翻译:在一个实施方案中,本发明涉及新型的二尾二头和两个尾一头表面活性剂。 在一个实施方案中,本发明包括具有以下通式的物质的新组合物:其中R 1和R 2可以相同或不同,并且选自具有6至22个碳原子的直链或支链烃链; R3是H,SO13yM +或-O(CH2CH2O)nX; R4是SO-yM +,或-O(CH2CH2O)nX; M是H,Li,Na,K,Rb或Cs; n为2-50的整数; y为3或4; X为H或SO 13 y M +。 优选地,当上述组合物当R 3不是H时,R 3 = R 4。
摘要:
This invention relates to a hydroxyaromatic functionalized polyalpha-olefin comprising the product of the combination of: a) a polyalpha-olefin comprising one or more C3 to C20 linear alpha-olefins and having at least 10% vinylidene unsaturation, a viscosity index of 80 to 400, an Mn of 300 to about 20,000, and a pour point of 0° C. or less; and b) a hydroxyaromatic moiety; wherein the analine point of the functionalized polyalpha-olefin is at least 10° C. lower than the analine point of the polyalpha-olefin.
摘要:
In a process for oxidizing a hydrocarbon, the hydrocarbon is contacted with oxygen in the presence of an N-substituted cyclic imide and under conditions to oxidize the hydrocarbon to produce an oxidized hydrocarbon product and at least one decomposition product of the N-substituted cyclic imide. At least a portion of the at least one decomposition product is contacted with hydroxylamine or a salt thereof under conditions to convert the at least one decomposition product back to said imide.
摘要:
In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of formula (I) and the effluent is treated with an aqueous solution of a base to produce an aqueous phase comprising at least part of the unreacted imide catalyst of formula (I) and an organic phase comprising oxidized hydrocarbon product. The organic phase can then be recovered.
摘要:
Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicyclopentadiene copolymers. Such copolymers can be readily derivatized by hydrogenation and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics. Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described.
摘要:
The invention is related to a geminally disubstituted olefin-carbon monoxide-ethylene polymer. The invention is also related to a method for preparing geminally disubstituted olefin-carbon monoxide-ethylene polymers by reacting a geminally disubstituted olefin feed, a carbon monoxide feed and an ethylene feed under free radical polymerization conditions. The invention is further related to a geminally disubstituted olefin-carbon monoxide-ethylene-X polymer, where monomer X is a free radical polymerizable monomer. The invention is also directed to a method for preparing geminally disubstituted olefin-carbon monoxide-ethylene-X polymers by reacting a geminally disubstituted olefin feed, a carbon monoxide feed, an ethylene feed and a feed containing monomer X under free radical polymerization conditions. The polymers of the invention are useful as polyvinyl chloride plasticizers.
摘要:
The instant invention provides a late transition metal complex which can be used with an activating cocatalyst to produce polymers and copolymers. The invention also provides methods for polymerizing olefins, as well as copolymers having polar monomers incorporated therein. More specifically, the invention provides a composition having the formula LMXZn, wherein M is selected from the group consisting of Cu, Ag and Au; X is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, nitrate, sulfate, nitrile, hydroxide and any other moiety into which a monomer can insert; Z is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, carbon monoxide, nitrate, nitrile, hydroxide, sulfate, olefins, water, any other neutral coordinating ligand and any other moiety into which a monomer can insert; n equals 0, 1 or 2; and L is a multi-dentate nitrogen-containing ligand.
摘要:
A process for preparing polymeric amides is disclosed. The process comprises sequentially reacting a hydrocarbon polymer functionalized (e.g., via the Koch reaction) to contain acid, ester, thioacid and/or thioester groups with a heavy polyamine to form a partially derivatized product in which at least about 85% of the functional groups are converted to heavy (thio)amide groups, and then reacting the partially derivatized product with an excess of light amine to complete the derivatization by converting substantially all of the remaining functional groups to light (thio)amide groups. Products of the foregoing process are also disclosed, which products are useful as additives in fuels and in lubricants.