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    TUBULAR COMPRESSIVE ORTHOSIS
    1.
    发明申请
    TUBULAR COMPRESSIVE ORTHOSIS 有权
    管状压缩性手术

    公开(公告)号：US20130053744A1

    公开(公告)日：2013-02-28

    申请号：US13578950

    申请日：2011-02-09

    申请人： Reynald Convert ,  Marie Gerard ,  Alain Cotte

    发明人： Reynald Convert ,  Marie Gerard ,  Alain Cotte

    IPC分类号： A61F5/00

    CPC分类号： A61F13/08 ,  A41B11/00 ,  A41B11/02 ,  A41B11/04 ,  A41B11/12 ,  A41B11/121 ,  A61F13/06 ,  A61F13/061 ,  A61F13/069 ,  D04B1/18 ,  D04B1/265 ,  D10B2509/028

    摘要： The invention relates to a tubular compressive orthosis having an upper edge defining a first knitted compression zone, and comprising, close to said upper edge, at least one grip element facilitating the process of putting on the orthosis. Characteristically, the grip element is a second knitted gripping zone arranged beneath the upper edge and having a mesh density higher than the mesh density of the first compression zone.

    摘要翻译： 本发明涉及一种管状压缩矫正装置，其具有限定第一编织压缩区的上边缘，并且包括靠近所述上边缘的至少一个抓握元件，其有助于穿过矫正器的过程。 特征在于，抓持元件是布置在上边缘下方并具有高于第一压缩区的网格密度的网格密度的第二编织夹持区域。

    Process for catalytically preparing aromatic or heteroaromatic nitriles
    4.
    发明申请
    Process for catalytically preparing aromatic or heteroaromatic nitriles 有权
    用于催化制备芳族或杂芳族腈的方法

    公开(公告)号：US20080194829A1

    公开(公告)日：2008-08-14

    申请号：US11986398

    申请日：2007-11-21

    申请人： Nikolaus Muller ,  Wolfgang Magerlein ,  Alain Cotte ,  Matthias Beller ,  Thomas Schareina ,  Alexander Zapf

    发明人： Nikolaus Muller ,  Wolfgang Magerlein ,  Alain Cotte ,  Matthias Beller ,  Thomas Schareina ,  Alexander Zapf

    IPC分类号： C07D211/04 ,  C07C255/49

    CPC分类号： C07B37/04 ,  C07C1/26 ,  C07C17/10 ,  C07C2529/40 ,  C07D213/61 ,  C07C9/00 ,  C07C19/075

    摘要： A process is described for catalytically preparing optionally substituted aromatic or heteroaromatic nitrites of the general formula (I) Ar—CN   (I) by reacting the corresponding aryl halides of the general formula (II) Ar—X   (II) in which X is chlorine, bromine, iodine, triflate, nonaflate, mesylate or tosylate and Ar is an optionally substituted aromatic or heteroaromatic radical, characterized in that the reaction is performed in the presence of a palladium compound, a phosphine of the general formula (III) or (IV) where R is an alkyl radical and R′, R″ and R′″ are each an alkyl radical or an aryl radical or heteroaryl radical and A is an alkylene or arylene radical, and potassium hexacyanoferrate(II) or potassium hexacyanoferrate(III), optionally in a solvent and optionally with addition of a base.

    摘要翻译： 描述了用于催化制备通式（I）的任选取代的芳香族或杂芳族亚硝酸盐的方法，该方法包括通式（I）的化合物。 通过使通式（II）的相应的芳基卤反应<？in-line-formula description =“In-Line Formulas”end =“in-line-formula description =”In-line Formulas“end =”tail“ “铅”→Ar-X（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X为氯，溴，碘，三氟甲磺酸酯，壬酸酯，甲磺酸酯或甲苯磺酸酯 并且Ar是任选取代的芳族或杂芳族基团，其特征在于反应在钯化合物，通式（III）或（IV）的膦的存在下进行，其中R是烷基，R'，R “和”R“分别是烷基或芳基或杂芳基，A是亚烷基或亚芳基，六氰基铁酸钾（II）或六氰基铁酸钾（III），选择性 在溶剂中并任选加入碱。

    PROCESS FOR PREPARING AZOMETHINES FROM ALPHA-OXOCARBOXYLATES, AMINES AND ARYL BROMIDES
    7.
    发明申请
    PROCESS FOR PREPARING AZOMETHINES FROM ALPHA-OXOCARBOXYLATES, AMINES AND ARYL BROMIDES 审中-公开
    从α-羟基甲酸酯，氨基酸和芳香族氨基酸制备氨基甲酸酯的方法

    公开(公告)号：US20140100371A1

    公开(公告)日：2014-04-10

    申请号：US13885059

    申请日：2011-11-18

    申请人： Alain Cotte ,  Matthias Cotta ,  Felix Rudolph ,  Bingrui Song ,  Lukas Goossen

    发明人： Alain Cotte ,  Matthias Cotta ,  Felix Rudolph ,  Bingrui Song ,  Lukas Goossen

    IPC分类号： C07D333/22 ,  C07C253/00 ,  C07D307/52 ,  C07C45/42 ,  C07C249/02 ,  C07D213/53

    CPC分类号： C07C253/00 ,  C07C45/42 ,  C07C249/02 ,  C07C253/30 ,  C07C319/20 ,  C07C2601/14 ,  C07C2603/26 ,  C07D213/53 ,  C07D307/52 ,  C07D333/22 ,  C07C251/18 ,  C07C251/24 ,  C07C255/61 ,  C07C323/45

    摘要： A process for preparing azomethines of the general formula (V) where R is an optionally substituted carbocyclic aromatic radical having 6 to 24 carbon atoms or an optionally substituted alkyl radical or an optionally substituted heteroaromatic radical having 5 to 24 carbon atoms, and R1 is an optionally substituted carbocyclic aromatic radical having 6 to 24 carbon atoms or an optionally substituted heteroaromatic radical having 5 to 24 carbon atoms, R2 is hydrogen or an optionally substituted carbocyclic aromatic radical having 6 to 24 carbon atoms or an optionally substituted alkyl radical or an optionally substituted cycloalkyl radical N or an optionally substituted heteroaromatic radical having 5 to 24 carbon atoms by reacting alpha-oxo carboxylates of the general formula (I) where n is a number in the range from 1 to 6, M(n+) is a cation, with aryl bromides of the general formula (IV) and amines of the general formula (II) via the alpha-iminocarboxylate intermediate of the general formula (III), in the presence of two transition metals or compounds thereof as catalyst, is described.

    摘要翻译： 一种制备通式（Ⅴ）的偶氮甲碱的方法，其中R是具有6至24个碳原子的任选取代的碳环芳族基团或任选取代的烷基或任选取代的具有5至24个碳原子的杂芳族基团，R 1是 具有6至24个碳原子的任选取代的碳环芳族基团或具有5至24个碳原子的任选取代的杂芳族基团，R 2是氢或任选取代的具有6至24个碳原子的碳环芳族基团或任选取代的烷基或任选取代的 环烷基N或具有5至24个碳原子的任选取代的杂芳族基团，其中通式（I）的α-氧代羧酸盐，其中n是1至6的数，M（n +）是阳离子，与 通式（Ⅳ）的芳基溴和通式（Ⅱ）的胺通过一般的α-亚氨基羧酸酯中间体 式（III）在两种过渡金属或其化合物作为催化剂的存在下进行了描述。

    PROCESS FOR PREPARING KETONES FROM ALPHA-OXO CARBOXYLATES AND ARYL BROMIDES
    9.
    发明申请
    PROCESS FOR PREPARING KETONES FROM ALPHA-OXO CARBOXYLATES AND ARYL BROMIDES 有权
    从α-氧代羧酸酯和芳香族羧酸制备克ON酮的方法

    公开(公告)号：US20090221832A1

    公开(公告)日：2009-09-03

    申请号：US12388779

    申请日：2009-02-19

    申请人： Alain Cotte ,  Matthias Gotta ,  Lukas Goossen ,  Felix Rudolphi ,  Christoph Oppel ,  Nuria Rodriguez Garrido

    发明人： Alain Cotte ,  Matthias Gotta ,  Lukas Goossen ,  Felix Rudolphi ,  Christoph Oppel ,  Nuria Rodriguez Garrido

    IPC分类号： C07D213/50 ,  C07C45/61 ,  C07D333/22

    CPC分类号： C07C45/68 ,  C07C221/00 ,  C07C253/30 ,  C07D213/50 ,  C07D307/46 ,  C07D333/22 ,  C07C49/782 ,  C07C49/788 ,  C07C49/76 ,  C07C49/813 ,  C07C49/84 ,  C07C225/22 ,  C07C255/56

    摘要： A process for preparing ketones of the general formula (III) where R is an optionally substituted carbocyclic aromatic radical having 6 to 24 carbon atoms or an optionally substituted alkyl radical or an optionally substituted heteroaromatic radical having 5 to 24 carbon atoms, and R1 is an optionally substituted carbocyclic aromatic radical having 6 to 24 carbon atoms or an optionally substituted heteroaromatic radical having 5 to 24 carbon atoms, by reacting alpha-oxo carboxylates of the general formula (I) whereinn and m is a number in the range from 1 to 6,M(m+) is a cation, andR has the meaning indicated for formula (III),with aryl bromides of the general formula (II) R1—Br   (II) whereR1 has the meaning indicated for formula (III),in the presence of two transition metals or compounds thereof as catalyst, is described.

    摘要翻译： 一种制备通式（III）的酮的方法，其中R是具有6至24个碳原子的任选取代的碳环芳族基团或任选取代的烷基或任选取代的具有5至24个碳原子的杂芳族基团，R 1是 任选取代的碳原子数为6〜24的碳环芳基或具有5〜24个碳原子的任意取代的杂芳族基，通式（I）的α-氧代羧酸盐反应，其中n和m为1〜 6，M（m +）为阳离子，R为式（III）所示的含义，通式（II）的芳基溴<？in-line-formula description =“In-Line Formulas”end =“ 引线“→R1-Br（II）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中R1具有式（III）所示的含义， 金属或其化合物作为催化剂。

    PROCESS FOR THE CATALYTIC SYNTHESIS OF DIARYL ETHERS
    10.
    发明申请
    PROCESS FOR THE CATALYTIC SYNTHESIS OF DIARYL ETHERS 有权
    二元醇的催化合成方法

    公开(公告)号：US20090143594A1

    公开(公告)日：2009-06-04

    申请号：US12275316

    申请日：2008-11-21

    申请人： Alain Cotte ,  Nikolaus Muller ,  Matthias Gotta ,  Matthias Beller ,  Thomas Schareina ,  Alexander Zapf

    发明人： Alain Cotte ,  Nikolaus Muller ,  Matthias Gotta ,  Matthias Beller ,  Thomas Schareina ,  Alexander Zapf

    IPC分类号： C07C41/01 ,  C07C209/00 ,  C07D213/63 ,  B01J31/18

    CPC分类号： C07C41/16 ,  C07C201/12 ,  C07C213/00 ,  C07C231/12 ,  C07D213/643 ,  C07C217/90 ,  C07C233/25 ,  C07C205/38 ,  C07C43/275 ,  C07C43/263 ,  C07C43/257

    摘要： Described is a process for preparing diaryl ethers of the formula (I) Ar—O—Ar′  (I) In which Ar is an aryl or substituted aryl group and Ar′ is an aryl, substituted aryl, heteroaryl or substituted heteroaryl group, by reacting an aryl of formula (II) or a aryloxy salt of formula (III) Ar—OH   (II) Ar—OR   (III) In which Ar has the same meaning as in formula (I) and R is an alkali metal, with an aryl or heteroaryl bromide of formula (IV) Ar′—Br   (IV) In which Ar′ has the same meaning as in formula (I), characterized in that the reaction is carried out in the presence of a copper(I)salt and a 1-substituted imidazole as catalyst system.

    摘要翻译： 描述了制备式（I）的二芳基醚的方法<？in-line-formula description =“In-line Formulas”end =“lead”→Ar-O-Ar'（I） -formulae description =“In-line Formulas”end =“tail”？>其中Ar是芳基或取代的芳基，Ar'是芳基，取代的芳基，杂芳基或取代的杂芳基，通过使式 II）或式（III）的芳氧基盐<？in-line-formula description =“In-line Formulas”end =“lead”？> Ar-OH（II）<？in-line-formula description =“In “公式”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> Ar-OR（III）<？in-line-formula description =“In 其中Ar具有与式（I）中相同的含义并且R是碱金属，其中式（IV）的芳基或杂芳基溴<？在线配方说明书 =“在线公式”end =“lead”？> Ar'-Br（IV）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Ar' 意义如式（I）所示 其特征在于反应在铜（I）盐和1-取代的咪唑作为催化剂体系的存在下进行。